For the following complexes whether optical isomers are present have to be determined and the same have to be drawn. (a) cis - [ C o ( N H 3 ) 2 ( e n ) 2 ] 3 + (b) trans - [ I r C l 2 ( C 2 O 4 ) 2 ] 3 − Concept Introduction: Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism. A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other. In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Question

Want to see the full answer?

Answer 1

Question

Chapter 22, Problem 22.55QP

(a)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

(b)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

The quantum yield of the photochemical decay of HI is 2. Calculating the moles of HI per kJ of radiant energy can be decayed knowing that the energy absorbed per mole of photons is 490 kJ.

The quantum yield of the photochemical decay of HI is 2. Calculate the number of Einsteins absorbed per mole knowing that the energy absorbed per mole of photons is 490 kJ.

The quantum yield of the photochemical decay of HI is 2. How many moles of HI per kJ of radiant energy can be decayed knowing that the energy absorbed per mole of photons is 490 kJ.

Answer 2

Question

Chapter 22, Problem 22.55QP

(a)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

(b)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 22, Problem 22.55QP

(a)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

(b)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 22, Problem 22.55QP

(a)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

(b)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 22, Problem 22.55QP

(a)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

(b)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Answer 6

Chapter 22, Problem 22.55QP

(a)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Answer 7

Chapter 22, Problem 22.55QP

(a)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Answer 8

(b)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Answer 9

(b)

Interpretation Introduction

Interpretation:

For the following complexes whether optical isomers are present have to be determined and the same have to be drawn.

(a) cis - [Co(NH3)2(en)2]3+ (b) trans - [IrCl2(C2O4)2]3−

Concept Introduction:

Co-ordination compounds exhibit structural isomerism and stereoisomerism. Stereoisomerism deals with three dimensional spatial arrangements of atoms or groups of molecule. There are two types of stereoisomerism – Geometric isomerism and optical isomerism.

A cis isomer has two same ligands lying adjacent to each other whereas a trans isomer has two same ligands lying opposite to each other.

In optical isomerism the isomer that rotates the plane of the polarized light in clockwise direction is termed as d-isomer and the isomer rotates the plane of the polarized light in anti-clockwise direction is l-isomer. These isomers are called optical isomers and they are non-superimposable mirror images.

Answer 10

Expert Solution & Answer

Answer 11

Expert Solution & Answer

Answer 12

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 13

Ch. 22.3 - Another complex studied by Werner had a...Ch. 22.4 - Prob. 22.1E Ch. 22.4 - Prob. 22.2E Ch. 22.5 - Prob. 22.2CC Ch. 22.5 - Prob. 22.3E Ch. 22.5 - Prob. 22.4E Ch. 22.5 - Prob. 22.3CC Ch. 22.7 - Prob. 22.5E Ch. 22.7 - Prob. 22.6E Ch. 22.7 - Prob. 22.7E

Solution Summary: The author explains that optical isomers are non-superimposable mirror images of atoms or groups of molecules.

Concept explainers

Want to see the full answer?

Chapter 22 Solutions