
Concept explainers
Interpretation:
The concentration of
Concept Introduction:
Consider a ligand ‘X’ co-ordinates to central metal ion ‘A’, and the reaction is represented as,
The formation constant,

Answer to Problem 22.72QP
Concentration of
Concentration of
Concentration of
Explanation of Solution
The reaction between
From the figure 17.2 given in the text book is, the reaction constant for the above reaction is
In this reaction ammonia is the limiting reagent and it is completely consumed during the formation of complex and the complex dissociates slightly later on. The concentration of each reactant species and the product at equilibrium is given as,
As we know,
Substitute the concentration
Numerical value of ‘x’ is negligible compared to
Rearranging the above equation and solving for x,
Therefore, at equilibrium,
Concentration of
Concentration of
Concentration of
Concentration of product and reactant species can be determined knowing the reaction and formation constant of the reaction.
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Chapter 22 Solutions
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