Mechanism for the conversion of compound (A) to compound (B) has to be given. Concept Introduction: Acid catalyzed reactions: In an organic synthesis reactions, most of the reactions are initiated by the abstraction of proton from acids by the reactant. Sulphuric acid is one of the reagent used for this purposes.

Question

Give the structure(s) of the product(s) the reaction below, and be sure to indicate any relative stereochemistry (you can assume that each of the Diels-Alder reactions will proceed with endo selectivity). Draw out relevant enantiomer(s) if they are expected to form. If no reaction is expected to occur under the indicated conditions, then write "no reaction" or NR, and explain why you would expect nothing to occur. If more than one product is formed, please indicate which one will be the major product or if they will be formed in equal amounts. In all cases, equimolar amounts of both components/reagents are present unless indicated otherwise I'm struggling to see how this reaction will go! I am wondering if it will cycle on itself but I'm not sure how I drew out a decagon but I'm a bit lost

Answer 1

Question

Chapter 22, Problem 22.53P

(a)

Interpretation Introduction

Interpretation:

Mechanism for the conversion of compound (A) to compound (B) has to be given.

Concept Introduction:

Acid catalyzed reactions:

In an organic synthesis reactions, most of the reactions are initiated by the abstraction of proton from acids by the reactant. Sulphuric acid is one of the reagent used for this purposes.

(b)

Interpretation Introduction

Interpretation:

For the conversion of compound (B) to compound (C) reagents has to be proposed.

Concept Introduction:

Grignard addition:

It is an addition of organomagnesium halide to an aldehyde or ketone, to form a secondary or tertiary alcohol respectively.

(c)

Interpretation Introduction

Interpretation:

Mechanism for the conversion of compound (C) to compound (D) has to be given.

Concept Introduction:

Acid catalyzed reactions:

In an organic synthesis reactions, most of the reactions are initiated by the abstraction of proton from acids by the reactant. Sulphuric acid is one of the reagent used for this purposes.

(d)

Interpretation Introduction

Interpretation:

For the conversion of compound (d) to amitriptyline reagents has to be proposed.

Concept Introduction:

S_N2 reaction:

SN2 stands for bimolecular nucleophilic substitution reaction. In this type of reactions, simultaneous bond breaking and bond making steps are involved.

(e)

Interpretation Introduction

Interpretation:

The chirality of amitriptyline and the number of possible stereoisomers has to be checked.

Concept Introduction:

Stereoisomers and chiral:

Isomers differing only in their spatial arrangement of atoms are called as stereoisomers.

The geometric property of a molecule that cannot be superimposed on its mirror image is known as chirality. Chiral carbon is the one which is attached with four different groups or atoms.

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Give the structure(s) of the product(s) the reaction below, and be sure to indicate any relative stereochemistry (you can assume that each of the Diels-Alder reactions will proceed with endo selectivity). Draw out relevant enantiomer(s) if they are expected to form. If no reaction is expected to occur under the indicated conditions, then write "no reaction" or NR, and explain why you would expect nothing to occur. If more than one product is formed, please indicate which one will be the major product or if they will be formed in equal amounts. In all cases, equimolar amounts of both components/reagents are present unless indicated otherwise I'm struggling to see how this reaction will go! I am wondering if it will cycle on itself but I'm not sure how I drew out a decagon but I'm a bit lost

Give the structure(s) of the product(s) for the reactions below, and be sure to indicate any relative stereochemistry (you can assume that each of the Diels-Alder reactions will proceed with endo selectivity). Draw out relevant enantiomer(s) if they are expected to form. If no reaction is expected to occur under the indicated conditions, then write "no reaction" or NR, and explain why you would expect nothing to occur. If more than one product is formed, please indicate which one will be the major product or if they will be formed in equal amounts. In all cases, equimolar amounts of both components/reagents are present unless indicated otherwise .

Calculate the residence time of strontium (Sr2+) in the world ocean, given that the average concentration of strontium in the world’s rivers is approximately 0.87 µmol L-1 (5 pts).

Answer 2

Question

Chapter 22, Problem 22.53P

(a)

Interpretation Introduction

Interpretation:

Mechanism for the conversion of compound (A) to compound (B) has to be given.

Concept Introduction:

Acid catalyzed reactions:

In an organic synthesis reactions, most of the reactions are initiated by the abstraction of proton from acids by the reactant. Sulphuric acid is one of the reagent used for this purposes.

(b)

Interpretation Introduction

Interpretation:

For the conversion of compound (B) to compound (C) reagents has to be proposed.

Concept Introduction:

Grignard addition:

It is an addition of organomagnesium halide to an aldehyde or ketone, to form a secondary or tertiary alcohol respectively.

(c)

Interpretation Introduction

Interpretation:

Mechanism for the conversion of compound (C) to compound (D) has to be given.

Concept Introduction:

Acid catalyzed reactions:

In an organic synthesis reactions, most of the reactions are initiated by the abstraction of proton from acids by the reactant. Sulphuric acid is one of the reagent used for this purposes.

(d)

Interpretation Introduction

Interpretation:

For the conversion of compound (d) to amitriptyline reagents has to be proposed.

Concept Introduction:

S_N2 reaction:

SN2 stands for bimolecular nucleophilic substitution reaction. In this type of reactions, simultaneous bond breaking and bond making steps are involved.

(e)

Interpretation Introduction

Interpretation:

The chirality of amitriptyline and the number of possible stereoisomers has to be checked.

Concept Introduction:

Stereoisomers and chiral:

Isomers differing only in their spatial arrangement of atoms are called as stereoisomers.

The geometric property of a molecule that cannot be superimposed on its mirror image is known as chirality. Chiral carbon is the one which is attached with four different groups or atoms.

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Answer 3

Question

Chapter 22, Problem 22.53P

(a)

Interpretation Introduction

Interpretation:

Mechanism for the conversion of compound (A) to compound (B) has to be given.

Concept Introduction:

Acid catalyzed reactions:

In an organic synthesis reactions, most of the reactions are initiated by the abstraction of proton from acids by the reactant. Sulphuric acid is one of the reagent used for this purposes.

(b)

Interpretation Introduction

Interpretation:

For the conversion of compound (B) to compound (C) reagents has to be proposed.

Concept Introduction:

Grignard addition:

It is an addition of organomagnesium halide to an aldehyde or ketone, to form a secondary or tertiary alcohol respectively.

(c)

Interpretation Introduction

Interpretation:

Mechanism for the conversion of compound (C) to compound (D) has to be given.

Concept Introduction:

Acid catalyzed reactions:

In an organic synthesis reactions, most of the reactions are initiated by the abstraction of proton from acids by the reactant. Sulphuric acid is one of the reagent used for this purposes.

(d)

Interpretation Introduction

Interpretation:

For the conversion of compound (d) to amitriptyline reagents has to be proposed.

Concept Introduction:

S_N2 reaction:

SN2 stands for bimolecular nucleophilic substitution reaction. In this type of reactions, simultaneous bond breaking and bond making steps are involved.

(e)

Interpretation Introduction

Interpretation:

The chirality of amitriptyline and the number of possible stereoisomers has to be checked.

Concept Introduction:

Stereoisomers and chiral:

Isomers differing only in their spatial arrangement of atoms are called as stereoisomers.

The geometric property of a molecule that cannot be superimposed on its mirror image is known as chirality. Chiral carbon is the one which is attached with four different groups or atoms.

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Answer 4

Question

Chapter 22, Problem 22.53P

(a)

Interpretation Introduction

Interpretation:

Mechanism for the conversion of compound (A) to compound (B) has to be given.

Concept Introduction:

Acid catalyzed reactions:

In an organic synthesis reactions, most of the reactions are initiated by the abstraction of proton from acids by the reactant. Sulphuric acid is one of the reagent used for this purposes.

(b)

Interpretation Introduction

Interpretation:

For the conversion of compound (B) to compound (C) reagents has to be proposed.

Concept Introduction:

Grignard addition:

It is an addition of organomagnesium halide to an aldehyde or ketone, to form a secondary or tertiary alcohol respectively.

(c)

Interpretation Introduction

Interpretation:

Mechanism for the conversion of compound (C) to compound (D) has to be given.

Concept Introduction:

Acid catalyzed reactions:

In an organic synthesis reactions, most of the reactions are initiated by the abstraction of proton from acids by the reactant. Sulphuric acid is one of the reagent used for this purposes.

(d)

Interpretation Introduction

Interpretation:

For the conversion of compound (d) to amitriptyline reagents has to be proposed.

Concept Introduction:

S_N2 reaction:

SN2 stands for bimolecular nucleophilic substitution reaction. In this type of reactions, simultaneous bond breaking and bond making steps are involved.

(e)

Interpretation Introduction

Interpretation:

The chirality of amitriptyline and the number of possible stereoisomers has to be checked.

Concept Introduction:

Stereoisomers and chiral:

Isomers differing only in their spatial arrangement of atoms are called as stereoisomers.

The geometric property of a molecule that cannot be superimposed on its mirror image is known as chirality. Chiral carbon is the one which is attached with four different groups or atoms.

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Answer 5

Chapter 22, Problem 22.53P

(a)

Interpretation Introduction

Interpretation:

Mechanism for the conversion of compound (A) to compound (B) has to be given.

Concept Introduction:

Acid catalyzed reactions:

In an organic synthesis reactions, most of the reactions are initiated by the abstraction of proton from acids by the reactant. Sulphuric acid is one of the reagent used for this purposes.

(b)

Interpretation Introduction

Interpretation:

For the conversion of compound (B) to compound (C) reagents has to be proposed.

Concept Introduction:

Grignard addition:

It is an addition of organomagnesium halide to an aldehyde or ketone, to form a secondary or tertiary alcohol respectively.

(c)

Interpretation Introduction

Interpretation:

Mechanism for the conversion of compound (C) to compound (D) has to be given.

Concept Introduction:

Acid catalyzed reactions:

In an organic synthesis reactions, most of the reactions are initiated by the abstraction of proton from acids by the reactant. Sulphuric acid is one of the reagent used for this purposes.

(d)

Interpretation Introduction

Interpretation:

For the conversion of compound (d) to amitriptyline reagents has to be proposed.

Concept Introduction:

S_N2 reaction:

SN2 stands for bimolecular nucleophilic substitution reaction. In this type of reactions, simultaneous bond breaking and bond making steps are involved.

(e)

Interpretation Introduction

Interpretation:

The chirality of amitriptyline and the number of possible stereoisomers has to be checked.

Concept Introduction:

Stereoisomers and chiral:

Isomers differing only in their spatial arrangement of atoms are called as stereoisomers.

The geometric property of a molecule that cannot be superimposed on its mirror image is known as chirality. Chiral carbon is the one which is attached with four different groups or atoms.

Answer 6

Chapter 22, Problem 22.53P

(a)

Interpretation Introduction

Interpretation:

Mechanism for the conversion of compound (A) to compound (B) has to be given.

Concept Introduction:

Acid catalyzed reactions:

In an organic synthesis reactions, most of the reactions are initiated by the abstraction of proton from acids by the reactant. Sulphuric acid is one of the reagent used for this purposes.

Answer 7

Chapter 22, Problem 22.53P

(a)

Interpretation Introduction

Interpretation:

Mechanism for the conversion of compound (A) to compound (B) has to be given.

Concept Introduction:

Acid catalyzed reactions:

In an organic synthesis reactions, most of the reactions are initiated by the abstraction of proton from acids by the reactant. Sulphuric acid is one of the reagent used for this purposes.

Answer 8

(b)

Interpretation Introduction

Interpretation:

For the conversion of compound (B) to compound (C) reagents has to be proposed.

Concept Introduction:

Grignard addition:

It is an addition of organomagnesium halide to an aldehyde or ketone, to form a secondary or tertiary alcohol respectively.

Answer 9

(b)

Interpretation Introduction

Interpretation:

For the conversion of compound (B) to compound (C) reagents has to be proposed.

Concept Introduction:

Grignard addition:

It is an addition of organomagnesium halide to an aldehyde or ketone, to form a secondary or tertiary alcohol respectively.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Mechanism for the conversion of compound (C) to compound (D) has to be given.

Concept Introduction:

Acid catalyzed reactions:

In an organic synthesis reactions, most of the reactions are initiated by the abstraction of proton from acids by the reactant. Sulphuric acid is one of the reagent used for this purposes.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Mechanism for the conversion of compound (C) to compound (D) has to be given.

Concept Introduction:

Acid catalyzed reactions:

In an organic synthesis reactions, most of the reactions are initiated by the abstraction of proton from acids by the reactant. Sulphuric acid is one of the reagent used for this purposes.

Answer 12

(d)

Interpretation Introduction

Interpretation:

For the conversion of compound (d) to amitriptyline reagents has to be proposed.

Concept Introduction:

S_N2 reaction:

SN2 stands for bimolecular nucleophilic substitution reaction. In this type of reactions, simultaneous bond breaking and bond making steps are involved.

Answer 13

(d)

Interpretation Introduction

Interpretation:

For the conversion of compound (d) to amitriptyline reagents has to be proposed.

Concept Introduction:

S_N2 reaction:

SN2 stands for bimolecular nucleophilic substitution reaction. In this type of reactions, simultaneous bond breaking and bond making steps are involved.

Answer 14

(e)

Interpretation Introduction

Interpretation:

The chirality of amitriptyline and the number of possible stereoisomers has to be checked.

Concept Introduction:

Stereoisomers and chiral:

Isomers differing only in their spatial arrangement of atoms are called as stereoisomers.

The geometric property of a molecule that cannot be superimposed on its mirror image is known as chirality. Chiral carbon is the one which is attached with four different groups or atoms.

Answer 15

(e)

Interpretation Introduction

Interpretation:

The chirality of amitriptyline and the number of possible stereoisomers has to be checked.

Concept Introduction:

Stereoisomers and chiral:

Isomers differing only in their spatial arrangement of atoms are called as stereoisomers.

The geometric property of a molecule that cannot be superimposed on its mirror image is known as chirality. Chiral carbon is the one which is attached with four different groups or atoms.

Answer 16

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Ch. 22.1 - Prob. 22.1P Ch. 22.1 - Write a structural formula for the product from...Ch. 22.1 - Prob. 22.3P Ch. 22.2 - Prob. 22.4P Ch. 22.2 - Predict the major produce(s) of each electrophilic...Ch. 22.3 - In SN2 reactions of haloalkanes, the order of...Ch. 22 - Prob. 22.8P Ch. 22 - Prob. 22.9P Ch. 22 - Addition of m-xylene to the strongly acidic...Ch. 22 - Addition of tert-butylbenzene to the strongly...

Solution Summary: The author explains how Sulphuric acid is used in acid catalyzed reactions, and the mechanism for conversion to amitriptyline reagents.

Interpretation:

For the conversion of compound (B) to compound (C) reagents has to be proposed.

Concept Introduction:

Grignard addition:

It is an addition of organomagnesium halide to an aldehyde or ketone, to form a secondary or tertiary alcohol respectively.

Interpretation:

For the conversion of compound (d) to amitriptyline reagents has to be proposed.

Concept Introduction:

S_N2 reaction:

SN2 stands for bimolecular nucleophilic substitution reaction. In this type of reactions, simultaneous bond breaking and bond making steps are involved.

Chapter 22 Solutions

Solution Summary: The author explains how Sulphuric acid is used in acid catalyzed reactions, and the mechanism for conversion to amitriptyline reagents.

Interpretation: For the conversion of compound (B) to compound (C) reagents has to be proposed. Concept Introduction: Grignard addition: It is an addition of organomagnesium halide to an aldehyde or ketone, to form a secondary or tertiary alcohol respectively.

Interpretation: For the conversion of compound (d) to amitriptyline reagents has to be proposed. Concept Introduction: SN2 reaction: SN2 stands for bimolecular nucleophilic substitution reaction. In this type of reactions, simultaneous bond breaking and bond making steps are involved.

Chapter 22 Solutions

Interpretation:

For the conversion of compound (B) to compound (C) reagents has to be proposed.

Concept Introduction:

Grignard addition:

It is an addition of organomagnesium halide to an aldehyde or ketone, to form a secondary or tertiary alcohol respectively.

Interpretation:

For the conversion of compound (d) to amitriptyline reagents has to be proposed.

Concept Introduction:

S_N2 reaction:

SN2 stands for bimolecular nucleophilic substitution reaction. In this type of reactions, simultaneous bond breaking and bond making steps are involved.