Organic Chemistry
8th Edition
ISBN: 9781305580350
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
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Textbook Question
Chapter 22, Problem 22.24P
The insecticide DDT is prepared by the following route. Suggest a mechanism for this reaction. The abbreviation DDT is derived from the common name dichlorodiphenyltrichloroethane.
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Use the expression below to
⚫ calculate its value and report it to the proper number of significant digits (you may need to
round your answer).
⚫ calculate the % error (or % relative error or % inherent error)
⚫ calculate the absolute error.
(20.54±0.02 × 0.254±0.003) / (3.21±0.05) =
Value:
% Error:
Absolute error: ± |
% (only 1 significant digit)
(only 1 significant digit)
In each case (more ductile, more brittle, more tough or resistant), indicate which parameter has a larger value.
parameter Elastic limit Tensile strength
more ductile
Strain at break Strength Elastic modulus
more fragile
more tough or resistant
None
Chapter 22 Solutions
Organic Chemistry
Ch. 22.1 - Prob. 22.1PCh. 22.1 - Write a structural formula for the product from...Ch. 22.1 - Prob. 22.3PCh. 22.2 - Prob. 22.4PCh. 22.2 - Predict the major produce(s) of each electrophilic...Ch. 22.3 - In SN2 reactions of haloalkanes, the order of...Ch. 22 - Prob. 22.8PCh. 22 - Prob. 22.9PCh. 22 - Addition of m-xylene to the strongly acidic...Ch. 22 - Addition of tert-butylbenzene to the strongly...
Ch. 22 - What product do you predict from the reaction of...Ch. 22 - Other groups besides H+ can act as leaving groups...Ch. 22 - Prob. 22.14PCh. 22 - Prob. 22.15PCh. 22 - Prob. 22.16PCh. 22 - Prob. 22.17PCh. 22 - Suggest a reason why the nitroso group, N=O, is...Ch. 22 - Prob. 22.19PCh. 22 - Prob. 22.20PCh. 22 - The following molecules each contain two aromatic...Ch. 22 - Prob. 22.22PCh. 22 - Prob. 22.23PCh. 22 - The insecticide DDT is prepared by the following...Ch. 22 - Prob. 22.25PCh. 22 - Prob. 22.26PCh. 22 - Prob. 22.27PCh. 22 - Prob. 22.28PCh. 22 - Prob. 22.29PCh. 22 - Prob. 22.32PCh. 22 - Show how to prepare each compound from...Ch. 22 - Prob. 22.34PCh. 22 - Show reagents and conditions to bring about the...Ch. 22 - Prob. 22.36PCh. 22 - Propose a synthesis for each compound from...Ch. 22 - The first widely used herbicide for the control of...Ch. 22 - The first widely used herbicide for the control of...Ch. 22 - Prob. 22.40PCh. 22 - Prob. 22.41PCh. 22 - Prob. 22.42PCh. 22 - Prob. 22.43PCh. 22 - Cancer of the prostate is the second leading cause...Ch. 22 - Prob. 22.45PCh. 22 - Prob. 22.46PCh. 22 - Prob. 22.47PCh. 22 - When certain aromatic compounds are treated with...Ch. 22 - Prob. 22.49PCh. 22 - Following is the structure of miconazole, the...Ch. 22 - Prob. 22.51PCh. 22 - Prob. 22.52PCh. 22 - Prob. 22.53PCh. 22 - Show how the antidepressant venlafaxine (Effexor)...Ch. 22 - Prob. 22.57PCh. 22 - Given this retrosynthetic analysis, propose a...Ch. 22 - Prob. 22.59PCh. 22 - Prob. 22.60PCh. 22 - Prob. 22.61PCh. 22 - A newer generation of antipsychotics, among them...Ch. 22 - Prob. 22.63P
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- What functional groups are present in this IRarrow_forwardIn each case (more ductile, more brittle, more tough or resistant), indicate which parameter has a larger value. parameter Elastic limit Tensile strength more ductile Strain at break Strength Elastic modulus more fragile more tough or resistantarrow_forward4) A typical bottle of pop holds carbon dioxide at a pressure of 5 atm. What is the concentration of carbon dioxide in th solution? 5) A stream flowing over rocks and such is exposed to the atmosphere and well aerated. What would be the nitrogen concentration in the water at 25°C? (Air pressure is 1.000 bar.)arrow_forward
- Use the expression below to ⚫ calculate its value and report it to the proper number of significant digits (you may need to round your answer). ⚫ calculate the % error (or % relative error or % inherent error) ⚫ calculate the absolute error. (30.078±0.003) - (20.174±0.001) + (9.813±0.005) = Value: % Error: absolute error: ± % (only 1 significant digit) (only 1 significant digit)arrow_forwardDon't used Ai solution and don't used hand raitingarrow_forwardCircle the letter next to the most appropriate response. 1) Which is likely to be the least soluble with water? a) hexane b) acetone c) trichloromethane d) trinitro-toluene 2) Which is likely to be the most soluble in 3,4-dimethyloctane? a) hexane b) acetone c) trichloromethane d) trinitro-toluene 3) When ammonium nitrate is dissolved in water, the solution: a) gets warmer. b) gets colder. c) stays the same temperature. d) is none of the above because potassium nitrate is insoluble.arrow_forward
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