Concept explainers
(a)
Interpretation:
Given compounds has to be arranged in their decreasing order of reactivity towards electrophilic
(a)
Explanation of Solution
Given compounds,
General trend of compounds reactivity in electrophilic aromatic substitution for a set of compounds having similar structure is given by,
So, electron donating substituents will increases the reactivity, while electron withdrawing substituents will decreases the reactivity.
Therefore, the decreasing order of reactivity towards electrophilic aromatic substitution of the given compounds are given below,
(b)
Interpretation:
Given compounds has to be arranged in their decreasing order of reactivity towards electrophilic aromatic substitution.
(b)
Explanation of Solution
Given compounds,
General trend of compounds reactivity in electrophilic aromatic substitution for a set of compounds having similar structure is given by,
So, electron donating substituents will increases the reactivity, while electron withdrawing substituents will decreases the reactivity.
Therefore, the decreasing order of reactivity towards electrophilic aromatic substitution of the given compounds are given below,
(c)
Interpretation:
Given compounds has to be arranged in their decreasing order of reactivity towards electrophilic aromatic substitution.
(c)
Explanation of Solution
Given compounds,
General trend of compounds reactivity in electrophilic aromatic substitution for a set of compounds having similar structure is given by,
So, electron donating substituents will increases the reactivity, while electron withdrawing substituents will decreases the reactivity.
Therefore, the decreasing order of reactivity towards electrophilic aromatic substitution of the given compounds are given below,
(d)
Interpretation:
Given compounds has to be arranged in their decreasing order of reactivity towards electrophilic aromatic substitution.
(d)
Explanation of Solution
Given compounds,
General trend of compounds reactivity in electrophilic aromatic substitution for a set of compounds having similar structure is given by,
So, electron donating substituents will increases the reactivity, while electron withdrawing substituents will decreases the reactivity.
Therefore, the decreasing order of reactivity towards electrophilic aromatic substitution of the given compounds are given below,
(e)
Interpretation:
Given compounds has to be arranged in their decreasing order of reactivity towards electrophilic aromatic substitution.
(e)
Explanation of Solution
Given compounds,
General trend of compounds reactivity in electrophilic aromatic substitution for a set of compounds having similar structure is given by,
So, electron donating substituents will increases the reactivity, while electron withdrawing substituents will decreases the reactivity.
Therefore, the decreasing order of reactivity towards electrophilic aromatic substitution of the given compounds are given below,
Want to see more full solutions like this?
Chapter 22 Solutions
Organic Chemistry
- 16. Which one of the compunds below is the final product of the reaction sequence shown here? عملاء .OH Br. (CH3)2CH-C=C H+,H,O 2 mol H2, Pt A OH B OH D OH E OH C OHarrow_forwardIndicate whether any of the two options is correct.a) The most common coordination structure for isopolianions is the prismb) Heteropolianions incorporate alkaline cations into their structuresarrow_forwardPlease correct answer and don't use hand ratingarrow_forward
- Wavelength (nm) I'm not sure what equation I can come up with other than the one generated with my graph. Can you please show me the calculations that were used to find this equation? Give an equation that relates energy to wavelength. Explain how you arrived at your equation. Wavelength Energy (kJ/mol) (nm) 350 341.8 420 284.8 470 254.5 530 225.7 580 206.3 620 192.9 700 170.9 750 159.5 Energy vs. Wavelength (Graph 1) 400 350 y=-0.4367x+470.82 300 250 200 150 100 50 O 0 100 200 300 400 500 600 700 800 Energy (kJ/mol)arrow_forward6. For the following molecules: draw Lewis dot-structures; use VSEPR method to determine geometries of the following molecules/ions. Are the central atoms in these molecules/ions considered of normal valency, or are they hypervalent? (please read paragraph 2.6) a) BrF3 (6 points) b) BrF4 c) IF₂ 4arrow_forwardNonearrow_forward
- 7. Use Pauling's electronegativity values (Table 1.7) and Ketelaar triangle (Fig. 2.28) to classify bonding in: (3 points) a) CIF3 b) ZnCl2 c) PbSarrow_forward7. What is the IUPAC name of the following compound? A) (R)-1-oxo-2-butanol C) (R)-2-hydroxybutanal E) (S)-1-formyl-1-propanol B) (S)-1-oxo-2-butanol D) (S)-2-hydroxybutanal OH Harrow_forwardCual es la formula semidesarrollada del 3-metil-1-butino?arrow_forward
- 2. A graph shown below shows first ionization energies for elements from H to Ne. First ionization energy/kJ mol 2500 2000 1500 1000 500 T T T T 1 2 3 5 6 7 8 9 10 Atomic number a) Using arguments of electronic structure, explain why ionization energy of Li is much lower than that of H. (2 points) then dips at O. b) Using the same arguments, explain why ionization energy increases from B to N, and (3 points)arrow_forwardGive the name of this compound, including stereochemistry if relevant: CICH2 CH3 Br CH₂CH=CH2 Write in the product, including stereochemistry where relevant, for these reactions. See end of ch. 8, p. 301-303. 1. 03 a) 2-methyl-2-pentene -> 2. Zn, H* Br2 b) 1-ethylcyclopentene -->arrow_forwardNonearrow_forward
Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning