Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 22, Problem 22.16E
Interpretation Introduction

Interpretation:

The reason as to why the same expression is not obtained when the Laplace-Young equation is derived in a different and incorrect way by writing the area of a sphere in terms of volume and then evaluating AV is to be stated.

Concept introduction:

Laplace-Young equation is a fundamental equation for the behavior of an interface. This equation relates the pressure difference on either side of an interface with the surface tension and the area of the liquid changes with volume. The Laplace-Young equation is shown below.

(pIpII)=γ(AVI)

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9. The following reaction, which proceeds via the SN1/E1 mechanisms, gives three alkene products (A, B, C) as well as an ether (D). (a) Show how each product arises mechanistically. (b) For the alkenes, determine the major product and justify your answer. (c) What clues in the reaction as shown suggest that this reaction does not go by the SN2/E2 mechanism route? (CH3)2CH-CH-CH3 CH3OH 1 Bl CH3OH ⑧· (CH3)2 CH-CH=CH2 heat H ⑥③ (CH3)2 C = C = CH3 © СнЗ-С-Снаснз сна (CH 3 ) 2 C H G H CH 3 оснз
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