CHEMISTRY-MASTERINGCHEMISTRY W/ETEXT
8th Edition
ISBN: 9780135204634
Author: Robinson
Publisher: PEARSON
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Chapter 22, Problem 22.146SP
Interpretation Introduction
Interpretation:
The balance net ionic equation for the oxidation of aqueous potassium bromide with solid manganese (IV) oxide in aqueous acidic solution should be determined.
Concept introduction:
A redox reaction leads to oxidation and reduction processes simultaneously.
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206 Pb
82
Express your answers as integers. Enter your answers separated by a comma.
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VAΣ
ΜΕ ΑΣΦ
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protons, neutrons
Please draw the inverted chair forms of the products for the two equilibrium reactions
shown below. Circle the equilibrium reaction that would have a AG = 0, i.e., the relative energy of
the reactant (to the left of the equilibrium arrows) equals the relative energy of the product? [No
requirement to show or do calculations.]
CH3
CH3
HH
CH3
1
-CH3
5.
Please consider the Newman projection of tartaric acid drawn below as an eclipsed
conformer (1). Please draw the most stable conformer and two intermediate energy conformers
noting that staggered conformers are lower in energy than eclipsed forms even if the staggered
conformers have gauche relationships between groups. [Draw the substituents H and OH on the front
carbons and H, OH and CO₂H on the back carbons based on staggered forms. -CO₂H is larger than -OH.]
OH
COH
ICOOH
COOH
COOH
1
2
COOH
COOH
3
4
Staggered
Staggered
Staggered (most stable)
Indicate the number of each conformer above (1, 2, 3 and 4) that corresponds to the relative energies
below.
Ref=0
Rotation
6. (60 points)
a. Are compounds 1 and 2 below enantiomers, diastereomers or identical?
OH
OH
HO
HO
LOH
HO
HO
OH
2
OH
OH
b. Please complete the zig-zag conformation of the compound
(3R,4S)-3,4-dichloro-2,5-dimethylhexane by writing the respective atoms in the boxes.
3.
Chapter 22 Solutions
CHEMISTRY-MASTERINGCHEMISTRY W/ETEXT
Ch. 22 - Which element has more nonmetallic character:Cl or...Ch. 22 - Prob. 22.2ACh. 22 - Prob. 22.3PCh. 22 - Prob. 22.4ACh. 22 - Prob. 22.5PCh. 22 - Look at the location of elements A, B, C, and Din...Ch. 22 - What are the formula and charge of the silicate...Ch. 22 - Suggest a plausible structure for the silicate...Ch. 22 - Prob. 22.9PCh. 22 - Write balanced net ionic equations for the...
Ch. 22 - Liquid hydrogen has been used as a fuel in theU.S....Ch. 22 - (a) Write balanced equations for the...Ch. 22 - Write a balanced equation for the production of...Ch. 22 - Prob. 22.14PCh. 22 - Prob. 22.15PCh. 22 - Prob. 22.16PCh. 22 - Prob. 22.17PCh. 22 - Locate each of the following groups of elements on...Ch. 22 - Prob. 22.19CPCh. 22 - Prob. 22.20CPCh. 22 - Prob. 22.21CPCh. 22 - Prob. 22.22CPCh. 22 - Prob. 22.23CPCh. 22 - Prob. 22.24CPCh. 22 - Prob. 22.25CPCh. 22 - Prob. 22.26CPCh. 22 - Prob. 22.27CPCh. 22 - Prob. 22.28CPCh. 22 - Consider the six second- and third-row elements in...Ch. 22 - Prob. 22.30CPCh. 22 - Prob. 22.31CPCh. 22 - Which element in each of the following pairs has...Ch. 22 - Arrange the following elements in order of...Ch. 22 - Prob. 22.34SPCh. 22 - Arrange the following elements in order of...Ch. 22 - Prob. 22.36SPCh. 22 - Arrange the following elements in order of...Ch. 22 - Which element in each of the following pairs has...Ch. 22 - Which element in each of the following pairs has...Ch. 22 - Prob. 22.40SPCh. 22 - Prob. 22.41SPCh. 22 - Prob. 22.42SPCh. 22 - Prob. 22.43SPCh. 22 - Consider the elements C, Se, B, Sn, and Cl....Ch. 22 - Prob. 22.45SPCh. 22 - BF3 reacts with F to give BF4 , but AlF3 reacts...Ch. 22 - GeCl4 reacts with Cl to give GeCl62 , but CCl4...Ch. 22 - At ordinary temperatures, sulfur exists as S8 but...Ch. 22 - Carbon, nitrogen, and oxygen form bonds, but...Ch. 22 - Prob. 22.50SPCh. 22 - Consider the elements Mn, Al, C, S, and Si. Which...Ch. 22 - Prob. 22.52SPCh. 22 - Prob. 22.53SPCh. 22 - Prob. 22.54SPCh. 22 - The hydrogen-filled dirigible Hindenburg had a...Ch. 22 - Write the chemical formula of a compound that...Ch. 22 - Prob. 22.57SPCh. 22 - Prob. 22.58SPCh. 22 - Prob. 22.59SPCh. 22 - Prob. 22.60SPCh. 22 - Prob. 22.61SPCh. 22 - Prob. 22.62SPCh. 22 - Describe the molecular geometry of: (a) GeH4(b)...Ch. 22 - Prob. 22.64SPCh. 22 - Explain why the hydrogen atoms in interstitial...Ch. 22 - Write a balanced net ionic equation for the...Ch. 22 - Write a balanced net ionic equation for the...Ch. 22 - Look at the properties of the alkali metals...Ch. 22 - Why does chemical reactivity increase from top to...Ch. 22 - Prob. 22.70SPCh. 22 - Prob. 22.71SPCh. 22 - Prob. 22.72SPCh. 22 - Prob. 22.73SPCh. 22 - Prob. 22.74SPCh. 22 - Prob. 22.75SPCh. 22 - Magnesium metal is produced by electrolysis of...Ch. 22 - How many hours are required to produce 10.0 kg of...Ch. 22 - Assign charges to the oxygen-containing anions in...Ch. 22 - Assign charges to the oxygen-containing anions in...Ch. 22 - Prob. 22.80SPCh. 22 - Prob. 22.81SPCh. 22 - Prob. 22.82SPCh. 22 - What is the oxidation state of the group 3A...Ch. 22 - Prob. 22.84SPCh. 22 - Prob. 22.85SPCh. 22 - Prob. 22.86SPCh. 22 - Prob. 22.87SPCh. 22 - Prob. 22.88SPCh. 22 - Prob. 22.89SPCh. 22 - Prob. 22.90SPCh. 22 - Prob. 22.91SPCh. 22 - Draw the electron-dot structure for CO, CO2 , and...Ch. 22 - What is the hybridization and geometry around...Ch. 22 - Which of the group 4A elements have allot ropes...Ch. 22 - Prob. 22.95SPCh. 22 - Prob. 22.96SPCh. 22 - Prob. 22.97SPCh. 22 - Prob. 22.98SPCh. 22 - Prob. 22.99SPCh. 22 - Prob. 22.100SPCh. 22 - Suggest a plausible structure for the silicate...Ch. 22 - Carbon is an essential element in the molecules on...Ch. 22 - Prob. 22.103SPCh. 22 - Prob. 22.104SPCh. 22 - Prob. 22.105SPCh. 22 - Prob. 22.106SPCh. 22 - Prob. 22.107SPCh. 22 - Draw an electron-dot structure for N2 , and...Ch. 22 - Describe the structures of the white and red...Ch. 22 - Prob. 22.110SPCh. 22 - Prob. 22.111SPCh. 22 - Account for each of the following observations....Ch. 22 - Compare and contrast the properties of ammonia and...Ch. 22 - Draw all the possible resonance structure for N2O...Ch. 22 - Could the strain in the P4 molecule be reduced by...Ch. 22 - Prob. 22.116SPCh. 22 - Prob. 22.117SPCh. 22 - In industry O2 is prepared by fractional...Ch. 22 - Prob. 22.119SPCh. 22 - Prob. 22.120SPCh. 22 - Prob. 22.121SPCh. 22 - Prob. 22.122SPCh. 22 - Prob. 22.123SPCh. 22 - Prob. 22.124SPCh. 22 - Prob. 22.125SPCh. 22 - Prob. 22.126SPCh. 22 - Prob. 22.127SPCh. 22 - Which is more acidic? (a) Cr2O3orCrO3 (b)...Ch. 22 - Prob. 22.129SPCh. 22 - Write a balanced net ionic equation for the...Ch. 22 - Write a balanced net ionic equation for the...Ch. 22 - Prob. 22.132SPCh. 22 - Write a balanced net ionic equation for the...Ch. 22 - Describe the structure of the sulfur molecules in:...Ch. 22 - The viscosity of liquid sulfur increases sharply...Ch. 22 - Prob. 22.136SPCh. 22 - Write a balanced net ionic equation for each of...Ch. 22 - Prob. 22.138SPCh. 22 - Prob. 22.139SPCh. 22 - Write electron-dot structures for each of the...Ch. 22 - (a) Why is the SO3 molecule trigonal planar hut...Ch. 22 - Prob. 22.142SPCh. 22 - Prob. 22.143SPCh. 22 - Little is known about the chemistry of astatine...Ch. 22 - Prob. 22.145SPCh. 22 - Prob. 22.146SPCh. 22 - Prob. 22.147SPCh. 22 - Prob. 22.148SPCh. 22 - Prob. 22.149SPCh. 22 - Prob. 22.150SPCh. 22 - Prob. 22.151SPCh. 22 - Prob. 22.152SPCh. 22 - Prob. 22.153SPCh. 22 - Prob. 22.154SPCh. 22 - Prob. 22.155SPCh. 22 - Prob. 22.156SPCh. 22 - Prob. 22.157SPCh. 22 - Prob. 22.158SPCh. 22 - Prob. 22.159SPCh. 22 - Prob. 22.160MPCh. 22 - Prob. 22.161MPCh. 22 - Prob. 22.162MPCh. 22 - Prob. 22.163MPCh. 22 - Prob. 22.164MPCh. 22 - Prob. 22.165MPCh. 22 - Prob. 22.166MPCh. 22 - Prob. 22.167MP
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