CHEMISTRY-MASTERINGCHEMISTRY W/ETEXT
8th Edition
ISBN: 9780135204634
Author: Robinson
Publisher: PEARSON
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Chapter 22, Problem 22.115SP
Could the strain in the
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10. Complete the substitution reaction of 2 pentanol with these reagents.
Reagents & Reaction Conditions use practice sheet. Please write only
major products, minor product like water, other gases are not
required.
Hint: In substitution of alcohol, we generally substitute OH group
with Halogens like cl, Br, F using some reagent containing
halogens. Ensure to add halogens to the same carbon number
where you are removing OH from
Examples
Alcohols can be converted to Alkyl Halides with HX acids
HBr
H₂O
HCI
+ H₂O
HI
+
H₂O
CH,CH₂OH + SOCI₂
CH,CH₂OH + PCI₁₂
A
BBYJU'S
CH CHCI + SO₂+ HCI
CH₂CH CIP(OH), + HCI
CH,CH₂OH + PCI CHCHCI + POCI + HCI
CH,CH₂OH + PBr, CH,CH,Br + P(OH), + HBr
1. Reaction with HBr with 2 Pentanol
2.Reaction with HI with 2 pentanol
© Byjus.com
3.Reaction with HCI+ZnCl,, with 2 pentanol (Zncl2 is catalyst no role)
4.Reaction with SOCI,, with 2 Pentanol
5.Reaction with PBr; or PCl, with 2 pentanol
3. Is 2-methyl-2-propanol a primary, secondary, or tertiary alcohol? Write
out the
structures of 2-methyl-2-propanol and also any oxidation products of 2-
methyl-2-
propanol. If there is more than one oxidation product, give the structure of
each
of the products.
4. 2-Propanol is the IUPAC systematic name of this alcohol. It has a
common name
by which it is much better known (You'll see it in the grocery store or
pharmacy).
Give that common name
5. Aldehydes can be synthesized by the oxidation of. Please choose from
below choices
A. Primary alcohols
B. Secondary alcohols
C. Organic acids
D. Inorganic acids
6. Tertiary alcohol Can undergo oxidation. yes or no. ? If yes then answer the
product.
Finish the reactions
hand written please
Chapter 22 Solutions
CHEMISTRY-MASTERINGCHEMISTRY W/ETEXT
Ch. 22 - Which element has more nonmetallic character:Cl or...Ch. 22 - Prob. 22.2ACh. 22 - Prob. 22.3PCh. 22 - Prob. 22.4ACh. 22 - Prob. 22.5PCh. 22 - Look at the location of elements A, B, C, and Din...Ch. 22 - What are the formula and charge of the silicate...Ch. 22 - Suggest a plausible structure for the silicate...Ch. 22 - Prob. 22.9PCh. 22 - Write balanced net ionic equations for the...
Ch. 22 - Liquid hydrogen has been used as a fuel in theU.S....Ch. 22 - (a) Write balanced equations for the...Ch. 22 - Write a balanced equation for the production of...Ch. 22 - Prob. 22.14PCh. 22 - Prob. 22.15PCh. 22 - Prob. 22.16PCh. 22 - Prob. 22.17PCh. 22 - Locate each of the following groups of elements on...Ch. 22 - Prob. 22.19CPCh. 22 - Prob. 22.20CPCh. 22 - Prob. 22.21CPCh. 22 - Prob. 22.22CPCh. 22 - Prob. 22.23CPCh. 22 - Prob. 22.24CPCh. 22 - Prob. 22.25CPCh. 22 - Prob. 22.26CPCh. 22 - Prob. 22.27CPCh. 22 - Prob. 22.28CPCh. 22 - Consider the six second- and third-row elements in...Ch. 22 - Prob. 22.30CPCh. 22 - Prob. 22.31CPCh. 22 - Which element in each of the following pairs has...Ch. 22 - Arrange the following elements in order of...Ch. 22 - Prob. 22.34SPCh. 22 - Arrange the following elements in order of...Ch. 22 - Prob. 22.36SPCh. 22 - Arrange the following elements in order of...Ch. 22 - Which element in each of the following pairs has...Ch. 22 - Which element in each of the following pairs has...Ch. 22 - Prob. 22.40SPCh. 22 - Prob. 22.41SPCh. 22 - Prob. 22.42SPCh. 22 - Prob. 22.43SPCh. 22 - Consider the elements C, Se, B, Sn, and Cl....Ch. 22 - Prob. 22.45SPCh. 22 - BF3 reacts with F to give BF4 , but AlF3 reacts...Ch. 22 - GeCl4 reacts with Cl to give GeCl62 , but CCl4...Ch. 22 - At ordinary temperatures, sulfur exists as S8 but...Ch. 22 - Carbon, nitrogen, and oxygen form bonds, but...Ch. 22 - Prob. 22.50SPCh. 22 - Consider the elements Mn, Al, C, S, and Si. Which...Ch. 22 - Prob. 22.52SPCh. 22 - Prob. 22.53SPCh. 22 - Prob. 22.54SPCh. 22 - The hydrogen-filled dirigible Hindenburg had a...Ch. 22 - Write the chemical formula of a compound that...Ch. 22 - Prob. 22.57SPCh. 22 - Prob. 22.58SPCh. 22 - Prob. 22.59SPCh. 22 - Prob. 22.60SPCh. 22 - Prob. 22.61SPCh. 22 - Prob. 22.62SPCh. 22 - Describe the molecular geometry of: (a) GeH4(b)...Ch. 22 - Prob. 22.64SPCh. 22 - Explain why the hydrogen atoms in interstitial...Ch. 22 - Write a balanced net ionic equation for the...Ch. 22 - Write a balanced net ionic equation for the...Ch. 22 - Look at the properties of the alkali metals...Ch. 22 - Why does chemical reactivity increase from top to...Ch. 22 - Prob. 22.70SPCh. 22 - Prob. 22.71SPCh. 22 - Prob. 22.72SPCh. 22 - Prob. 22.73SPCh. 22 - Prob. 22.74SPCh. 22 - Prob. 22.75SPCh. 22 - Magnesium metal is produced by electrolysis of...Ch. 22 - How many hours are required to produce 10.0 kg of...Ch. 22 - Assign charges to the oxygen-containing anions in...Ch. 22 - Assign charges to the oxygen-containing anions in...Ch. 22 - Prob. 22.80SPCh. 22 - Prob. 22.81SPCh. 22 - Prob. 22.82SPCh. 22 - What is the oxidation state of the group 3A...Ch. 22 - Prob. 22.84SPCh. 22 - Prob. 22.85SPCh. 22 - Prob. 22.86SPCh. 22 - Prob. 22.87SPCh. 22 - Prob. 22.88SPCh. 22 - Prob. 22.89SPCh. 22 - Prob. 22.90SPCh. 22 - Prob. 22.91SPCh. 22 - Draw the electron-dot structure for CO, CO2 , and...Ch. 22 - What is the hybridization and geometry around...Ch. 22 - Which of the group 4A elements have allot ropes...Ch. 22 - Prob. 22.95SPCh. 22 - Prob. 22.96SPCh. 22 - Prob. 22.97SPCh. 22 - Prob. 22.98SPCh. 22 - Prob. 22.99SPCh. 22 - Prob. 22.100SPCh. 22 - Suggest a plausible structure for the silicate...Ch. 22 - Carbon is an essential element in the molecules on...Ch. 22 - Prob. 22.103SPCh. 22 - Prob. 22.104SPCh. 22 - Prob. 22.105SPCh. 22 - Prob. 22.106SPCh. 22 - Prob. 22.107SPCh. 22 - Draw an electron-dot structure for N2 , and...Ch. 22 - Describe the structures of the white and red...Ch. 22 - Prob. 22.110SPCh. 22 - Prob. 22.111SPCh. 22 - Account for each of the following observations....Ch. 22 - Compare and contrast the properties of ammonia and...Ch. 22 - Draw all the possible resonance structure for N2O...Ch. 22 - Could the strain in the P4 molecule be reduced by...Ch. 22 - Prob. 22.116SPCh. 22 - Prob. 22.117SPCh. 22 - In industry O2 is prepared by fractional...Ch. 22 - Prob. 22.119SPCh. 22 - Prob. 22.120SPCh. 22 - Prob. 22.121SPCh. 22 - Prob. 22.122SPCh. 22 - Prob. 22.123SPCh. 22 - Prob. 22.124SPCh. 22 - Prob. 22.125SPCh. 22 - Prob. 22.126SPCh. 22 - Prob. 22.127SPCh. 22 - Which is more acidic? (a) Cr2O3orCrO3 (b)...Ch. 22 - Prob. 22.129SPCh. 22 - Write a balanced net ionic equation for the...Ch. 22 - Write a balanced net ionic equation for the...Ch. 22 - Prob. 22.132SPCh. 22 - Write a balanced net ionic equation for the...Ch. 22 - Describe the structure of the sulfur molecules in:...Ch. 22 - The viscosity of liquid sulfur increases sharply...Ch. 22 - Prob. 22.136SPCh. 22 - Write a balanced net ionic equation for each of...Ch. 22 - Prob. 22.138SPCh. 22 - Prob. 22.139SPCh. 22 - Write electron-dot structures for each of the...Ch. 22 - (a) Why is the SO3 molecule trigonal planar hut...Ch. 22 - Prob. 22.142SPCh. 22 - Prob. 22.143SPCh. 22 - Little is known about the chemistry of astatine...Ch. 22 - Prob. 22.145SPCh. 22 - Prob. 22.146SPCh. 22 - Prob. 22.147SPCh. 22 - Prob. 22.148SPCh. 22 - Prob. 22.149SPCh. 22 - Prob. 22.150SPCh. 22 - Prob. 22.151SPCh. 22 - Prob. 22.152SPCh. 22 - Prob. 22.153SPCh. 22 - Prob. 22.154SPCh. 22 - Prob. 22.155SPCh. 22 - Prob. 22.156SPCh. 22 - Prob. 22.157SPCh. 22 - Prob. 22.158SPCh. 22 - Prob. 22.159SPCh. 22 - Prob. 22.160MPCh. 22 - Prob. 22.161MPCh. 22 - Prob. 22.162MPCh. 22 - Prob. 22.163MPCh. 22 - Prob. 22.164MPCh. 22 - Prob. 22.165MPCh. 22 - Prob. 22.166MPCh. 22 - Prob. 22.167MP
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- Part A Identify each alcohol as primary, secondary, or tertiary Drag the appropriate items to their respective bins. CH₂ H₂C- -C-OH HO CH₂ Primary Он OH CH₂ OH CCH₂OH CH₂ сн Secondary Tertiary Reset Help CH,CH₂ (CH)CHCH,OH CH,CH,CH,CCH, CHOH CH₂ Different types of alcohol groups Alcohol and its reaction: 8. Combing two alcohol molecules below and completing the reaction with Product .( Hint Reaction called etherification as ether is formed and name the ether once you complete the reaction. Hint.: R-O-H+H-O-RR-O-R Do the reaction: CH₂OH + CH₂OH---→ + H-O-H 9. Write the reaction of formation of alcohol from alkene by adding water: Addition reaction also called hydration reaction as we are adding water which occur always in presence of acid Hint: Break the double bond and add H and OH if symmetrical then add anywhere if unsymmetrical then follow Markovnikov rule H should go to that double bone carbon which has more hydrogen CH2=CH2 + H₂O-→arrow_forwardComplete the reaction hand written pleasearrow_forwardPredict the major products of this organic reaction: HBr (1 equiv) cold ? Some important notes: • Draw the major product, or products, of this reaction in the drawing area below. • You can draw the products in any arrangement you like. • Pay careful attention to the reaction conditions, and only include the major products. • Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are enantiomers. • Note that there is only 1 equivalent of HBr reactant, so you need not consider the case of multiple additions. dm Re Explanation Check ©2025 McGraw Hill LLC. All Rights Reserved. Termarrow_forward
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- Indicate the products of the reaction between CH3COCH2COOC2H5 and Na+-OC2H5.arrow_forwardPrimary, Secondary, and Tertiary Alcohols O-H O-H O-H R₁-C-H R₁-C-H R₁-C-R₁ H R₂ R₂ Primary Alcohol Secondary Alcohol ChemistryLearner.com R stands for Carbon group like ethyl methyl propyl Tertiary Alcohol If 1 carbon group with two H attached to alcoholic carbon, then primary If 2 carbon group and 1 H are attached to alcoholic carbon, then secondary IF 3 carbon group and no H attach to alcoholic carbon then tertiary. The bottom line Starting "Weak" oxidant material PCC, DMP, Swern, etc Primary alcohol Aldehyde OH Secondary alcohol Ketone OH "Strong" oxidant KMnO4, H₂CrO4 (or equivalent) OH Carboxylic acid 요 Ketone No reaction No reaction Tertiary alcohol 1. Is ethanol a primary, secondary, or tertiary alcohol? Write out the structures of ethanol and any oxidation products of ethanol. If there is more than one oxidation product, give the structure of each of the products. 2. Is 2-propanol a primary, secondary, or tertiary alcohol? Write out the structures of 2-propanol and any…arrow_forwardFormulate the reaction: Naphthalene with CrO3 in acetic acid at 25ºCarrow_forward
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