Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
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Chapter 21, Problem 58QAP
Interpretation Introduction
Interpretation:
The amount in kilograms of sodium perchlorate should be detremined which is produced in an eight-hour run when current of
Concept introduction:
From Faraday’s law of
Where, Q is charge, I is current and t is time.
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8. Draw all the resonance forms for each of the fling molecules or ions, and indicate the major
contributor in each case, or if they are equivalent (45)
(2)
-PH2
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Also calculate the amount of starting materials chlorobenzaldehyde and p-chloroacetophenone
required to prepare 400 mg of the given chalcone product 1, 3-bis(4-chlorophenyl)prop-2-en-1-one
molar mass ok 1,3-bis(4-Chlorophenyl) prop-2-en-1-one = 277.1591m01
number of moles= 0.400/277.15 = 0.00144 moles
2 x 0.00 144=0.00288 moves
arams of acetophenone = 0.00144 X 120.16 = 0.1739
0.1739x2=0.3469
grams of benzaldehyde = 0.00144X106.12=0.1539
0.1539x2 = 0.3069
Starting materials:
0.3469 Ox acetophenone,
0.3069 of benzaldehyde
3
1.
Answer the questions about the following reaction:
(a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this
reaction. Be sure to include any relevant stereochemistry in the product structure.
+
SK
F
Br
+
(b) In which solvent would this reaction proceed the fastest (Circle one)
Methanol
Acetone
(c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the
one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you
observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest
other products that are formed? Draw them in the box provided.
Chapter 21 Solutions
Chemistry: Principles and Reactions
Ch. 21 - Prob. 1QAPCh. 21 - Prob. 2QAPCh. 21 - Prob. 3QAPCh. 21 - Prob. 4QAPCh. 21 - Prob. 5QAPCh. 21 - Prob. 6QAPCh. 21 - Give the formula for the acidic oxide of (a) HNO3...Ch. 21 - Prob. 8QAPCh. 21 - Write the formulas of the following compounds. (a)...Ch. 21 - Prob. 10QAP
Ch. 21 - Prob. 11QAPCh. 21 - Prob. 12QAPCh. 21 - Prob. 13QAPCh. 21 - Prob. 14QAPCh. 21 - Prob. 15QAPCh. 21 - Prob. 16QAPCh. 21 - Prob. 17QAPCh. 21 - Write a balanced net ionic equation for the...Ch. 21 - Prob. 19QAPCh. 21 - Prob. 20QAPCh. 21 - Prob. 21QAPCh. 21 - Prob. 22QAPCh. 21 - Prob. 23QAPCh. 21 - Prob. 24QAPCh. 21 - Prob. 25QAPCh. 21 - Prob. 26QAPCh. 21 - Prob. 27QAPCh. 21 - Prob. 28QAPCh. 21 - Prob. 29QAPCh. 21 - Prob. 30QAPCh. 21 - Prob. 31QAPCh. 21 - Prob. 32QAPCh. 21 - Prob. 33QAPCh. 21 - Prob. 34QAPCh. 21 - The average concentration of bromine (as bromide)...Ch. 21 - Prob. 36QAPCh. 21 - Iodine can be prepared by allowing an aqueous...Ch. 21 - Prob. 38QAPCh. 21 - Prob. 39QAPCh. 21 - Prob. 40QAPCh. 21 - Prob. 41QAPCh. 21 - Prob. 42QAPCh. 21 - Prob. 43QAPCh. 21 - Prob. 44QAPCh. 21 - Prob. 45QAPCh. 21 - Given...Ch. 21 - What is the concentration of fluoride ion in a...Ch. 21 - Calculate the solubility in grams per 100 mL of...Ch. 21 - Prob. 49QAPCh. 21 - Follow the directions for Problem 49 for the...Ch. 21 - Consider the equilibrium system HF(aq)H+(aq)+F(aq)...Ch. 21 - Applying the tables in Appendix 1 to...Ch. 21 - Consider the reaction 4NH3(g)+5O2(g)4NO(g)+6H2O(g)...Ch. 21 - Data are given in Appendix 1 for white phosphorus,...Ch. 21 - Prob. 55QAPCh. 21 - Prob. 56QAPCh. 21 - Sodium hypochlorite is produced by the...Ch. 21 - Prob. 58QAPCh. 21 - Prob. 59QAPCh. 21 - Prob. 60QAPCh. 21 - Consider the reduction of nitrate ion in acidic...Ch. 21 - Prob. 62QAPCh. 21 - Choose the strongest acid from each group. (a)...Ch. 21 - Prob. 64QAPCh. 21 - Prob. 65QAPCh. 21 - Prob. 66QAPCh. 21 - Prob. 67QAPCh. 21 - Prob. 68QAPCh. 21 - Prob. 69QAPCh. 21 - Explain why (a) acid strength increases as the...Ch. 21 - Prob. 71QAPCh. 21 - Prob. 72QAPCh. 21 - The amount of sodium hypochlorite in a bleach...Ch. 21 - Prob. 74QAP
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- 3. For the reactions below, draw the arrows corresponding to the transformations and draw in the boxes the reactants or products as indicated. Note: Part A should have arrows drawn going from the reactants to the middle structure and the arrows on the middle structure that would yield the final structure. For part B, you will need to draw in the reactant before being able to draw the arrows corresponding to product formation. A. B. Rearrangement ΘΗarrow_forward2. Draw the arrows required to make the following reactions occur. Please ensure your arrows point from exactly where you want to exactly where you want. If it is unclear from where arrows start or where they end, only partial credit will be given. Note: You may need to draw in lone pairs before drawing the arrows. A. B. H-Br 人 C Θ CI H Cl Θ + Br Oarrow_forward4. For the reactions below, draw the expected product. Be sure to indicate relevant stereochemistry or formal charges in the product structure. a) CI, H e b) H lux ligh Br 'Harrow_forward
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- 3. Assign absolute configuration (Rors) to each chirality center. a. H Nitz C. он b. 0 H-C. C H 7 C. ་-4 917-417 refs H 1つ ८ ડુ d. Но f. -2- 01 Ho -OH 2HNarrow_forwardHow many signals do you expect in the H NMR spectrum for this molecule? Br Br Write the answer below. Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H atoms that would contribute to the same signal as the H already highlighted red. Note for advanced students: In this question, any multiplet is counted as one signal. Number of signals in the 'H NMR spectrum. For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to the same signal as the H atom already highlighted red. If no other H atoms will contribute, check the box at right. No additional Hs to color in top molecule For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute to the same signal as the H atom already highlighted red. If no other H atoms will contribute, check the box at right. No additional Hs to color in bottom moleculearrow_forwardIn the drawing area below, draw the major products of this organic reaction: 1. NaOH ? 2. CH3Br If there are no major products, because nothing much will happen to the reactant under these reaction conditions, check the box under the drawing area instead. No reaction. Click and drag to start drawing a structure. ☐ : A คarrow_forward
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