Chemistry & Chemical Reactivity
9th Edition
ISBN: 9781133949640
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Chapter 21, Problem 44PS
Interpretation Introduction
Interpretation: The structure for
Concept introduction:
Silicates are the anionic part of the compounds of silicon elements in which silicon is attached to oxygen atoms. Silicates can be classified into various categories like orthosilicates, disilicates, chain silicate, cyclic silicate and zeolites.
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Chapter 21 Solutions
Chemistry & Chemical Reactivity
Ch. 21.2 - Prob. 1CYUCh. 21.2 - Write the formula for each of the following (a)...Ch. 21.2 - Prob. 3CYUCh. 21.2 - Prob. 4CYUCh. 21.4 - Prob. 3RCCh. 21.5 - Prob. 1QCh. 21.5 - Prob. 2QCh. 21.8 - Prob. 1QCh. 21.8 - Prob. 2QCh. 21.8 - Prob. 3Q
Ch. 21.8 - Prob. 4QCh. 21.8 - Prob. 3RCCh. 21.11 - Prob. 1QCh. 21.11 - Prob. 2QCh. 21 - Give examples of two basic oxides. Write equations...Ch. 21 - Prob. 2PSCh. 21 - Prob. 3PSCh. 21 - Prob. 4PSCh. 21 - Prob. 5PSCh. 21 - Prob. 6PSCh. 21 - For the product of the reaction you selected in...Ch. 21 - For the product of the reaction you selected in...Ch. 21 - Prob. 9PSCh. 21 - Prob. 10PSCh. 21 - Place the following oxides in order of increasing...Ch. 21 - Place the following oxides in order of increasing...Ch. 21 - Prob. 13PSCh. 21 - Prob. 14PSCh. 21 - Prob. 15PSCh. 21 - Prob. 16PSCh. 21 - Prob. 17PSCh. 21 - Prob. 18PSCh. 21 - Prob. 19PSCh. 21 - Prob. 20PSCh. 21 - Prob. 21PSCh. 21 - Write balanced equations for the reaction of...Ch. 21 - Prob. 23PSCh. 21 - (a) Write equations for the half-reactions that...Ch. 21 - When magnesium bums in air, it forms both an oxide...Ch. 21 - Prob. 26PSCh. 21 - Prob. 27PSCh. 21 - Prob. 28PSCh. 21 - Calcium oxide, CaO, is used to remove SO2 from...Ch. 21 - Prob. 30PSCh. 21 - Prob. 31PSCh. 21 - The boron trihalides (except BF3) hydrolyze...Ch. 21 - When boron hydrides burn in air, the reactions are...Ch. 21 - Prob. 34PSCh. 21 - Write balanced equations for the reactions of...Ch. 21 - Prob. 36PSCh. 21 - Prob. 37PSCh. 21 - Alumina, Al2O3, is amphoteric. Among examples of...Ch. 21 - Prob. 39PSCh. 21 - Prob. 40PSCh. 21 - Describe the structure of pyroxenes (see page...Ch. 21 - Describe how ultrapure silicon can be produced...Ch. 21 - Prob. 43PSCh. 21 - Prob. 44PSCh. 21 - Prob. 45PSCh. 21 - Prob. 46PSCh. 21 - Prob. 47PSCh. 21 - The overall reaction involved in the industrial...Ch. 21 - Prob. 49PSCh. 21 - Prob. 50PSCh. 21 - Prob. 51PSCh. 21 - Prob. 52PSCh. 21 - Prob. 53PSCh. 21 - Prob. 54PSCh. 21 - Prob. 55PSCh. 21 - Sulfur forms a range of compounds with fluorine....Ch. 21 - The halogen oxides and oxoanions are good...Ch. 21 - Prob. 58PSCh. 21 - Bromine is obtained from brine wells. The process...Ch. 21 - Prob. 60PSCh. 21 - Prob. 61PSCh. 21 - Halogens combine with one another to produce...Ch. 21 - The standard enthalpy of formation of XeF4 is 218...Ch. 21 - Draw the Lewis electron dot structure for XeO3F2....Ch. 21 - Prob. 65PSCh. 21 - Prob. 66PSCh. 21 - Prob. 67GQCh. 21 - Prob. 68GQCh. 21 - Consider the chemistries of the elements...Ch. 21 - When BCl3 gas is passed through an electric...Ch. 21 - Prob. 71GQCh. 21 - Prob. 72GQCh. 21 - Prob. 73GQCh. 21 - Prob. 74GQCh. 21 - Prob. 75GQCh. 21 - Prob. 76GQCh. 21 - Prob. 77GQCh. 21 - Prob. 78GQCh. 21 - Prob. 79GQCh. 21 - Prob. 80GQCh. 21 - Prob. 81GQCh. 21 - Prob. 83GQCh. 21 - Prob. 84GQCh. 21 - A Boron and hydrogen form an extensive family of...Ch. 21 - In 1774, C. Scheele obtained a gas by reacting...Ch. 21 - What current must be used in a Downs cell...Ch. 21 - The chemistry of gallium: (a) Gallium hydroxide,...Ch. 21 - Prob. 89GQCh. 21 - Prob. 90GQCh. 21 - Prob. 91GQCh. 21 - Prob. 92GQCh. 21 - Prob. 93ILCh. 21 - Prob. 94ILCh. 21 - Prob. 95ILCh. 21 - Prob. 96ILCh. 21 - Prob. 97ILCh. 21 - Prob. 98ILCh. 21 - Prob. 99SCQCh. 21 - Prob. 100SCQCh. 21 - Prob. 101SCQCh. 21 - Prob. 102SCQCh. 21 - Prob. 103SCQCh. 21 - Prob. 104SCQCh. 21 - Prob. 105SCQCh. 21 - Prob. 106SCQCh. 21 - Prob. 107SCQCh. 21 - Prob. 108SCQCh. 21 - Prob. 109SCQCh. 21 - Prob. 110SCQCh. 21 - Comparing the chemistry of carbon and silicon. (a)...Ch. 21 - Prob. 112SCQCh. 21 - Xenon trioxide, XeO3, reacts with aqueous base to...
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- Alumina, Al2O3, is amphoteric. Among examples of its amphoteric character are the reactions that occur when Al2O3 is heated strongly or fused with acidic oxides and basic oxides. (a) Write a balanced equation for the reaction of alumina with silica, an acidic oxide, to give aluminum metasilicate, Al2(SiO3)3. (b) Write a balanced equation for the reaction of alumina with the basic oxide CaO to give calcium aluminate, Ca(AlO2)2.arrow_forwardPhosphorous acid, H3PO3, is oxidized to phosphoric acid, H3PO4, by nitric acid, which is reduced to nitrogen monoxide, NO. Write the balanced equation for this reaction.arrow_forward4.48 Elemental phosphorous is used in the semiconductor industry. It can be obtained from an ore called fluoroapatite via reaction with SiO2 and C: 4Ca5( PO4)3F+18SiO2+30C3P4+30CO+18CaSiO3+2CaF2 Suppose a particular semiconductor production plant requires 1500 kg of P4. If the recovery of P4 from this reaction is 73% efficient, what mass of fluoroapatite is needed?arrow_forward
- Xenon trioxide, XeO3, is reduced to xenon in acidic solution by iodide ion. Iodide ion is oxidized to iodine, I2. Write a balanced chemical equation for the reaction.arrow_forwardThe amount of sodium hypochlorite in a bleach solution can be determined by using a given volume of bleach to oxidize excess iodide ion to iodine; ClO- is reduced to Cl-. The amount of iodine produced by the redox reaction is determined by titration with sodium thiosulfate, Na2S2O3; I2 is reduced to I-. The sodium thiosulfate is oxidized to sodium tetrathionate, Na2S4O6. In this analysis, potassium iodide was added in excess to 5.00 mL of bleach (d=1.00g/cm3) . If 25.00 mL of 0.0700 M Na2S2O3 was required to reduce all the iodine produced by the bleach back to iodide, what is the mass percent of NaClO in the bleach?arrow_forwardThe amount of sodium hypochlorite in a bleach solution can be determined by using a given volume of bleach to oxidize excess iodide ion to iodine, because the reaction goes to completion. The amount of iodine produced is then determined by titration with sodium thiosulfate, Na2S2O3, which is oxidized to sodium tetrathionate, Na2S4O6. Potassium iodide was added in excess to 5.00 mL of bleach (density = 1.00 g/mL). This solution, containing the iodine released in the reaction, was titrated with 0.100 M Na2S2O3. If 34.6 mL of sodium thiosulfate was required to reach the endpoint (detected by disappearance of the blue color of the starch iodine complex), what was the mass percentage of NaClO in the bleach?arrow_forward
- Tourmaline is the most colorful of all gemstones. It neutralizes negative forces and offers emotional stability. It is crystalline boron silicates compounded with metals such as Mg, Fe, Al, Na and Li. The three most well-known minerals of tourmaline are: Elbaite Na(LiAl2)Al6Si6O18(BO3)3(OH)4 Schorl Na(Fe3)Al6(BO3)3Si6O18(OH)4 Dravite Na(Mg3)Al6(BO3)3Si6O18(OH)4 On a basis of 1000 kg of tourmaline rocks containing 25% Elbaite, 35% Schorl, 30% Dravite and 10% inerts, calculate the following: a) kg-mol Elbaite b) % by wt BO3 in tourmaline rocksarrow_forwardTourmaline is the most colorful of all gemstones. It neutralizes negative forces and offers emotional stability. It is crystalline boron silicates compounded with metals such as Mg, Fe, Al, Na and Li. The three most well-known minerals of tourmaline are: Elbaite Na(LiAl2)Al6Si6O18(BO3)3(OH)4 Schorl Na(Fe3)Al6(BO3)3Si6O18(OH)4 Dravite Na(Mg3)Al6(BO3)3Si6O18(OH)4 On a basis of 1000 kg of tourmaline rocks containing 25% Elbaite, 35% Schorl, 30% Dravite and 10% inerts, calculate the following: a) kg Fe b) total kg-atom O and kg-mol O2 in the three minerals c) total number of Mg atoms in the rocksarrow_forwardPart A) Draw the Lewis dot structure for SiO44−. Use square brackets to denote the overall charge. Part B) Draw the Lewis dot structures for two connected SiO4 tetrahedra. (Hint: Look at it as O3Si−O−SiO3^6−.)arrow_forward
- Define the term empiricalchemical formula What is the shape of the SiO4 unit in complicated silicate anions?arrow_forwardThe thermal decomposition of 1.826 g of a hydrate of MnCl2 produces 1.161 g of anhydrous MnCl2. Calculate the mass percent of water in the hydrate.arrow_forwardLooking up one snowy afternoon from a book titled The Moral Case Against Turning Lead Into Gold (Or Vice Versa), your friend Maria (an expert chemist) says this: "Metal sulfides roasted with oxygen produce the corresponding oxide and sulfur dioxide gas." Using Maria's statement, and what you already know about chemistry, predict the products of the following reaction. Be sure your chemical equation is balanced! NiS (s) + O₂(g) → 0-0 0+0 X 00 NO REACTION Sarrow_forward
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