Chemistry & Chemical Reactivity
9th Edition
ISBN: 9781133949640
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Chapter 21, Problem 43PS
Interpretation Introduction
Interpretation: To draw the structure and predict the charge for the cyclic silicate ion
Concept introduction: Silicates are the materials that contain silicon and oxygen in a pattern. Cyclic silicates have a general formula of
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Part A)
Draw the Lewis dot structure for SiO44−. Use square brackets to denote the overall charge.
Part B)
Draw the Lewis dot structures for two connected SiO4 tetrahedra. (Hint: Look at it as O3Si−O−SiO3^6−.)
Define the term silicates?
What is the VSEPR geometrical shape of the silicate ion, SiO32- ?
Chapter 21 Solutions
Chemistry & Chemical Reactivity
Ch. 21.2 - Prob. 1CYUCh. 21.2 - Write the formula for each of the following (a)...Ch. 21.2 - Prob. 3CYUCh. 21.2 - Prob. 4CYUCh. 21.4 - Prob. 3RCCh. 21.5 - Prob. 1QCh. 21.5 - Prob. 2QCh. 21.8 - Prob. 1QCh. 21.8 - Prob. 2QCh. 21.8 - Prob. 3Q
Ch. 21.8 - Prob. 4QCh. 21.8 - Prob. 3RCCh. 21.11 - Prob. 1QCh. 21.11 - Prob. 2QCh. 21 - Give examples of two basic oxides. Write equations...Ch. 21 - Prob. 2PSCh. 21 - Prob. 3PSCh. 21 - Prob. 4PSCh. 21 - Prob. 5PSCh. 21 - Prob. 6PSCh. 21 - For the product of the reaction you selected in...Ch. 21 - For the product of the reaction you selected in...Ch. 21 - Prob. 9PSCh. 21 - Prob. 10PSCh. 21 - Place the following oxides in order of increasing...Ch. 21 - Place the following oxides in order of increasing...Ch. 21 - Prob. 13PSCh. 21 - Prob. 14PSCh. 21 - Prob. 15PSCh. 21 - Prob. 16PSCh. 21 - Prob. 17PSCh. 21 - Prob. 18PSCh. 21 - Prob. 19PSCh. 21 - Prob. 20PSCh. 21 - Prob. 21PSCh. 21 - Write balanced equations for the reaction of...Ch. 21 - Prob. 23PSCh. 21 - (a) Write equations for the half-reactions that...Ch. 21 - When magnesium bums in air, it forms both an oxide...Ch. 21 - Prob. 26PSCh. 21 - Prob. 27PSCh. 21 - Prob. 28PSCh. 21 - Calcium oxide, CaO, is used to remove SO2 from...Ch. 21 - Prob. 30PSCh. 21 - Prob. 31PSCh. 21 - The boron trihalides (except BF3) hydrolyze...Ch. 21 - When boron hydrides burn in air, the reactions are...Ch. 21 - Prob. 34PSCh. 21 - Write balanced equations for the reactions of...Ch. 21 - Prob. 36PSCh. 21 - Prob. 37PSCh. 21 - Alumina, Al2O3, is amphoteric. Among examples of...Ch. 21 - Prob. 39PSCh. 21 - Prob. 40PSCh. 21 - Describe the structure of pyroxenes (see page...Ch. 21 - Describe how ultrapure silicon can be produced...Ch. 21 - Prob. 43PSCh. 21 - Prob. 44PSCh. 21 - Prob. 45PSCh. 21 - Prob. 46PSCh. 21 - Prob. 47PSCh. 21 - The overall reaction involved in the industrial...Ch. 21 - Prob. 49PSCh. 21 - Prob. 50PSCh. 21 - Prob. 51PSCh. 21 - Prob. 52PSCh. 21 - Prob. 53PSCh. 21 - Prob. 54PSCh. 21 - Prob. 55PSCh. 21 - Sulfur forms a range of compounds with fluorine....Ch. 21 - The halogen oxides and oxoanions are good...Ch. 21 - Prob. 58PSCh. 21 - Bromine is obtained from brine wells. The process...Ch. 21 - Prob. 60PSCh. 21 - Prob. 61PSCh. 21 - Halogens combine with one another to produce...Ch. 21 - The standard enthalpy of formation of XeF4 is 218...Ch. 21 - Draw the Lewis electron dot structure for XeO3F2....Ch. 21 - Prob. 65PSCh. 21 - Prob. 66PSCh. 21 - Prob. 67GQCh. 21 - Prob. 68GQCh. 21 - Consider the chemistries of the elements...Ch. 21 - When BCl3 gas is passed through an electric...Ch. 21 - Prob. 71GQCh. 21 - Prob. 72GQCh. 21 - Prob. 73GQCh. 21 - Prob. 74GQCh. 21 - Prob. 75GQCh. 21 - Prob. 76GQCh. 21 - Prob. 77GQCh. 21 - Prob. 78GQCh. 21 - Prob. 79GQCh. 21 - Prob. 80GQCh. 21 - Prob. 81GQCh. 21 - Prob. 83GQCh. 21 - Prob. 84GQCh. 21 - A Boron and hydrogen form an extensive family of...Ch. 21 - In 1774, C. Scheele obtained a gas by reacting...Ch. 21 - What current must be used in a Downs cell...Ch. 21 - The chemistry of gallium: (a) Gallium hydroxide,...Ch. 21 - Prob. 89GQCh. 21 - Prob. 90GQCh. 21 - Prob. 91GQCh. 21 - Prob. 92GQCh. 21 - Prob. 93ILCh. 21 - Prob. 94ILCh. 21 - Prob. 95ILCh. 21 - Prob. 96ILCh. 21 - Prob. 97ILCh. 21 - Prob. 98ILCh. 21 - Prob. 99SCQCh. 21 - Prob. 100SCQCh. 21 - Prob. 101SCQCh. 21 - Prob. 102SCQCh. 21 - Prob. 103SCQCh. 21 - Prob. 104SCQCh. 21 - Prob. 105SCQCh. 21 - Prob. 106SCQCh. 21 - Prob. 107SCQCh. 21 - Prob. 108SCQCh. 21 - Prob. 109SCQCh. 21 - Prob. 110SCQCh. 21 - Comparing the chemistry of carbon and silicon. (a)...Ch. 21 - Prob. 112SCQCh. 21 - Xenon trioxide, XeO3, reacts with aqueous base to...
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- Carbon forms the CO32− ion, yet silicon does not form an analogous SiO32− ion. Why?arrow_forwardConsider the series of reactions to synthesize the alum (KAl(SO4 )2 · xH2O(s)) from the introduction. (a) Assuming an excess of the other reagents, from one mole of aluminum Al (s), how many moles of alum will be produced? (b) Assuming an excess of the other reagents, from one mole of potassium hydroxide KOH, how many moles of alum will be produced? (c) Assuming an excess of the other reagents, from one mole of sulfuric acid H2SO4 , how many moles of alum will be produced? (d) If you start the synthesis with 1.00 g of Al, 40.0 mL of 1.50 M KOH, and 20.0 mL of 9.00 M H2SO4 , which of the three will be the limiting reagent? (e) Assuming that the product is anhydrous (that there are no waters of hydration), calculate the theoretical yield of alum, in grams, based on the amounts of reagents in part (d). 3. Consider the nickel salt: (NH4 )2Ni(SO4 )2 ·y H2O (Ammonium Nickel Sulfate Hydrate), where y is the number of coordinated waters. (a) Assuming that the product is anhydrous (y = 0),…arrow_forwardTourmaline is the most colorful of all gemstones. It neutralizes negative forces and offers emotional stability. It is crystalline boron silicates compounded with metals such as Mg, Fe, Al, Na and Li. The three most well-known minerals of tourmaline are: Elbaite Na(LiAl2)Al6Si6O18(BO3)3(OH)4 Schorl Na(Fe3)Al6(BO3)3Si6O18(OH)4 Dravite Na(Mg3)Al6(BO3)3Si6O18(OH)4 On a basis of 1000 kg of tourmaline rocks containing 25% Elbaite, 35% Schorl, 30% Dravite and 10% inerts, calculate the following: a) kg-mol Elbaite b) % by wt BO3 in tourmaline rocksarrow_forward
- Tourmaline is the most colorful of all gemstones. It neutralizes negative forces and offers emotional stability. It is crystalline boron silicates compounded with metals such as Mg, Fe, Al, Na and Li. The three most well-known minerals of tourmaline are: Elbaite Na(LiAl2)Al6Si6O18(BO3)3(OH)4 Schorl Na(Fe3)Al6(BO3)3Si6O18(OH)4 Dravite Na(Mg3)Al6(BO3)3Si6O18(OH)4 On a basis of 1000 kg of tourmaline rocks containing 25% Elbaite, 35% Schorl, 30% Dravite and 10% inerts, calculate the following: a) kg Fe b) total kg-atom O and kg-mol O2 in the three minerals c) total number of Mg atoms in the rocksarrow_forwardIn basic solution, molecular chlorine, Cl 2 , reacts with hydroxide ions, OH − , to yield chloride ions, Cl − and chlorate ions, ClO 4 − . HINT: This is a disproportionation reaction in which the element chlorine is both oxidized and reduced. Write a balanced equation for this reaction.arrow_forwardThe aluminium in a 1.2 g sample of impure NH4Al (SO4)2 was precipitated as hydrous Al2O3. The precipitate was filtered and ignited at 100° c to give anhydrous Al2O3 which weighed 0.1798 g. Calculate the % Al in the sample. (number of moles Al = 2; Al2O3 = 1)arrow_forward
- Consider the series of reactions to synthesize the alum (KAl(SO4 )2 · xH2O(s)). ) Assuming an excess of the other reagents, from one mole of sulfuric acid H2SO4 , how many moles of alum will be produced?arrow_forwardI need a step by step explanation for this question.arrow_forwardWrite the balanced net ionic equation for the reaction of hydrogen sulfide (H2S) with bromate ions, BrO3-, in acidic solution to form sulfur ions and bromide ions. How many H+ are there in the balanced equation?arrow_forward
- In the mineral beryl, six silicate tetrahedra are connectedto form a ring as shown here. The negative charge of thispolyanion is balanced by Be2 + and Al3 + cations. If elemental analysis gives a Be:Si ratio of 1:2 and an Al:Si ratio of 1:3 whatis the empirical formula of beryl: (a) Be2Al3Si6O19,(b) Be3Al2 (SiO4)6, (c) Be3Al2Si6O18, (d) BeAl2Si6O15?arrow_forwardUsing oxidation and reduction half-reactions, balance the skeletal equation N2H4(g) + ClO−3(aq) → NO(g) + Cl−(aq) of hydrazine with chlorate ions. The reaction takes place in basic solution. What is the smallest possible integer coefficient of ClO−3 in the balanced equation?arrow_forwardWhat is the Lewis structure for SiO32- ?arrow_forward
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