PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
2nd Edition
ISBN: 9781285074788
Author: Ball
Publisher: CENGAGE L
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Chapter 21, Problem 21.59E
Interpretation Introduction

Interpretation:

The defect caused by the hydrogen molecules in the solid Pd metal is to be predicted. The reason as to why hydrogen is absorbed by Pd and no other gas is to be stated.

Concept introduction:

There are two types of defects possible when additional atom is present in the unit cell. When the additional atom squeezes itself between the normally occupied positions, the defect is known as the interstitial defect and when the additional atom substitutes an atom in the unit cell then it is known as the substitution defect.

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Calculate the number density of valence electrons in a certain metallic element given that the element crystallises in a BCC structure with a lattice constant of 0.415 nm, and that the element is monovalent (i.e. each atom has a single valence electrons). Assuming that the mean free path of the electrons is 1.3 nm, calculate the collision time and the conductivity of the element at 350 K, using the classical Drude model of electrical conduction. O a. Electron density = 2.80 x 1028 m-3, collision time = 1.03 x 10-14 s; conductivity = 8.13 x 106 0'm Electron density = 4.56 x 1028 m-3; collision time = 2.45 x 10-14 s; conductivity = 3.88 x 106 Qm- O c. Electron density = 6.53 x 1026 m 3; collision time 2.45 x 10-14 s; conductivity 9.26 x 105'm d. Electron density 1.40 x 1028 m-3; collision time 1.03 x 10-14 s; conductivity = 4.07 x 106 Q 'm
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Chapter 21 Solutions

PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.

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