PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
2nd Edition
ISBN: 9781285074788
Author: Ball
Publisher: CENGAGE L
Question
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Chapter 21, Problem 21.49E
Interpretation Introduction

(a)

Interpretation:

The specific chemical reaction whose enthalpy change represents the lattice energy of the given solid is to be stated.

Concept introduction:

The amount of energy released when one formula unit moles of oppositely charged gaseous ions binds together to form a crystal is known as the lattice energy. The value of lattice energy is negative. It is used as a measure for stability of a crystal.

Interpretation Introduction

(b)

Interpretation:

The specific chemical reaction whose enthalpy change represents the lattice energy of the given solid is to be stated.

Concept introduction:

The amount of energy released when one formula unit moles of oppositely charged gaseous ions binds together to form a crystal is known as the Lattice energy. The value of lattice energy is negative. It is used as a measure for stability of a crystal.

Interpretation Introduction

(c)

Interpretation:

The specific chemical reaction whose enthalpy change represents the lattice energy of the given solid is to be stated.

Concept introduction:

The amount of energy released when one formula unit moles of oppositely charged gaseous ions binds together to form a crystal is known as the Lattice energy. The value of lattice energy is negative. It is used as a measure for stability of a crystal.

Interpretation Introduction

(d)

Interpretation:

The specific chemical reaction whose enthalpy change represents the lattice energy of the given solid is to be stated.

Concept introduction:

The amount of energy released when one formula unit moles of oppositely charged gaseous ions binds together to form a crystal is known as the Lattice energy. The value of lattice energy is negative. It is used as a measure for stability of a crystal.

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3. (a) Using thermodynamics, explain the difference between a closed system and an open system. (b) State the first law in terms of internal energy of a system. In chemistry, why are changes in the enthalpy rather than internal energy used to study a chemical process. (c) State Hess's law.
(ii) The industrial process for producing sulphuric acid, H2SO4, from elemental sulphur has three steps, using the information below; (a) identify the three steps, and describe the nature of each step (in one phrase); (b) write an equation for the overall reaction. (c) using the data given below, calculate the enthalpy change for the overall reaction. S(s) + O2(g) SO-(g) A;H° = -296.8 kJ 2S0:(g) 2SO2(g) + O2(9) A;H° = -198.2 kJ SO((g) + H2O(1) H2SO4() A;H° = -227.7 kJ
The nitrogen atoms in an N2 molecule are held together by a triple bond; use enthalpies of formation in Appendix C to estimate the enthalpy of this bond, D(N‚N).

Chapter 21 Solutions

PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.

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