(a) Interpretation: The structural formula and name of the products of the reaction between ethane and chlorine should be determined. In case of multiple products the type of product expected should be predicted. Concept Introduction: Alkanes undergo substitution reaction with halogen atoms in presence of light.

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Answer 1

Question

Chapter 20, Problem 119AP

Interpretation Introduction

(a)

Interpretation:

The structural formula and name of the products of the reaction between ethane and chlorine should be determined. In case of multiple products the type of product expected should be predicted.

Concept Introduction:

Alkanes undergo substitution reaction with halogen atoms in presence of light.

Interpretation Introduction

(b)

Interpretation:

The structural formula of platinum catalyzed hydrogenation product of but-2-ene should be determined along with the name. In case of multiple products the type of product expected should be predicted.

Concept Introduction:

But-2-ene is converted to a saturated hydrocarbon when it is hydrogenated in presence of platinum.

Interpretation Introduction

(c)

Interpretation:

The structural formula of the reaction product of 3-ethylpent-2-ene and bromine should be determined along with name of the product. In case of multiple products the type of product expected should be predicted.

Concept Introduction:

Alkenes undergo addition reaction with bromine in which dibromo product is obtained.

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Technetium is the first element in the periodic chart that does not have any stable isotopes. Technetium-99m is an especially interesting and valuable isotope as it emits a gamma ray with a half life ideally suited for medical tests. It would seem that the decay of technetium should fit the treatment above with the result In(c/c) = -kt. The table below includes data from the two sites: http://dailymed.nlm.nih.gov/dailymed/druginfo.cfm?id=7130 http://wiki.medpedia.com/Clinical: Neutrospec_(Technetium_(99m Tc)_fanolesomab). a. b. C. Graph the fraction (c/c.) on the vertical axis versus the time on the horizontal axis. Also graph In(c/c.) on the vertical axis versus time on the horizontal axis. When half of the original amount of starting material has hours fraction remaining disappeared, c/c = ½ and the equation In(c/c.) = -kt becomes In(0.5) = -kt1/2 where t₁₂ is the half life (the time for half of the material to decay away). Determine the slope of your In(c/c.) vs t graph and…

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1. a) Assuming that an atom of arsenic has hydrogen-like atomic orbitals, sketch the radial probability plots for 4p and 4d orbitals of S atom. Indicate angular and radial nodes in these orbitals. (4 points) b) Calculate Zeff experienced by and electron in 4p AO's in a arsenic atom. Use Slater rules that were discussed in lecture. (3 points)

Answer 2

Question

Chapter 20, Problem 119AP

Interpretation Introduction

(a)

Interpretation:

The structural formula and name of the products of the reaction between ethane and chlorine should be determined. In case of multiple products the type of product expected should be predicted.

Concept Introduction:

Alkanes undergo substitution reaction with halogen atoms in presence of light.

Interpretation Introduction

(b)

Interpretation:

The structural formula of platinum catalyzed hydrogenation product of but-2-ene should be determined along with the name. In case of multiple products the type of product expected should be predicted.

Concept Introduction:

But-2-ene is converted to a saturated hydrocarbon when it is hydrogenated in presence of platinum.

Interpretation Introduction

(c)

Interpretation:

The structural formula of the reaction product of 3-ethylpent-2-ene and bromine should be determined along with name of the product. In case of multiple products the type of product expected should be predicted.

Concept Introduction:

Alkenes undergo addition reaction with bromine in which dibromo product is obtained.

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Answer 3

Question

Chapter 20, Problem 119AP

Interpretation Introduction

(a)

Interpretation:

The structural formula and name of the products of the reaction between ethane and chlorine should be determined. In case of multiple products the type of product expected should be predicted.

Concept Introduction:

Alkanes undergo substitution reaction with halogen atoms in presence of light.

Interpretation Introduction

(b)

Interpretation:

The structural formula of platinum catalyzed hydrogenation product of but-2-ene should be determined along with the name. In case of multiple products the type of product expected should be predicted.

Concept Introduction:

But-2-ene is converted to a saturated hydrocarbon when it is hydrogenated in presence of platinum.

Interpretation Introduction

(c)

Interpretation:

The structural formula of the reaction product of 3-ethylpent-2-ene and bromine should be determined along with name of the product. In case of multiple products the type of product expected should be predicted.

Concept Introduction:

Alkenes undergo addition reaction with bromine in which dibromo product is obtained.

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Answer 4

Question

Chapter 20, Problem 119AP

Interpretation Introduction

(a)

Interpretation:

The structural formula and name of the products of the reaction between ethane and chlorine should be determined. In case of multiple products the type of product expected should be predicted.

Concept Introduction:

Alkanes undergo substitution reaction with halogen atoms in presence of light.

Interpretation Introduction

(b)

Interpretation:

The structural formula of platinum catalyzed hydrogenation product of but-2-ene should be determined along with the name. In case of multiple products the type of product expected should be predicted.

Concept Introduction:

But-2-ene is converted to a saturated hydrocarbon when it is hydrogenated in presence of platinum.

Interpretation Introduction

(c)

Interpretation:

The structural formula of the reaction product of 3-ethylpent-2-ene and bromine should be determined along with name of the product. In case of multiple products the type of product expected should be predicted.

Concept Introduction:

Alkenes undergo addition reaction with bromine in which dibromo product is obtained.

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Answer 5

Chapter 20, Problem 119AP

Interpretation Introduction

(a)

Interpretation:

The structural formula and name of the products of the reaction between ethane and chlorine should be determined. In case of multiple products the type of product expected should be predicted.

Concept Introduction:

Alkanes undergo substitution reaction with halogen atoms in presence of light.

Interpretation Introduction

(b)

Interpretation:

The structural formula of platinum catalyzed hydrogenation product of but-2-ene should be determined along with the name. In case of multiple products the type of product expected should be predicted.

Concept Introduction:

But-2-ene is converted to a saturated hydrocarbon when it is hydrogenated in presence of platinum.

Interpretation Introduction

(c)

Interpretation:

The structural formula of the reaction product of 3-ethylpent-2-ene and bromine should be determined along with name of the product. In case of multiple products the type of product expected should be predicted.

Concept Introduction:

Alkenes undergo addition reaction with bromine in which dibromo product is obtained.

Answer 6

Chapter 20, Problem 119AP

Interpretation Introduction

(a)

Interpretation:

The structural formula and name of the products of the reaction between ethane and chlorine should be determined. In case of multiple products the type of product expected should be predicted.

Concept Introduction:

Alkanes undergo substitution reaction with halogen atoms in presence of light.

Answer 7

Chapter 20, Problem 119AP

Interpretation Introduction

(a)

Interpretation:

The structural formula and name of the products of the reaction between ethane and chlorine should be determined. In case of multiple products the type of product expected should be predicted.

Concept Introduction:

Alkanes undergo substitution reaction with halogen atoms in presence of light.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structural formula of platinum catalyzed hydrogenation product of but-2-ene should be determined along with the name. In case of multiple products the type of product expected should be predicted.

Concept Introduction:

But-2-ene is converted to a saturated hydrocarbon when it is hydrogenated in presence of platinum.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structural formula of platinum catalyzed hydrogenation product of but-2-ene should be determined along with the name. In case of multiple products the type of product expected should be predicted.

Concept Introduction:

But-2-ene is converted to a saturated hydrocarbon when it is hydrogenated in presence of platinum.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structural formula of the reaction product of 3-ethylpent-2-ene and bromine should be determined along with name of the product. In case of multiple products the type of product expected should be predicted.

Concept Introduction:

Alkenes undergo addition reaction with bromine in which dibromo product is obtained.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structural formula of the reaction product of 3-ethylpent-2-ene and bromine should be determined along with name of the product. In case of multiple products the type of product expected should be predicted.

Concept Introduction:

Alkenes undergo addition reaction with bromine in which dibromo product is obtained.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 20.2 - Exercise 20.1 Give the molecular formulas for the...Ch. 20.4 - Exercise 20.2 Name the following molecules. a. b.Ch. 20.4 - Exercise 20.3 Write the structural formula for...Ch. 20.5 - Petroleum is a very valuable raw material for the...Ch. 20.7 - Exercise 20.4 Name the following molecules. a. b.Ch. 20.9 - Prob. 20.5SC Ch. 20.11 - Prob. 20.6SC Ch. 20.14 - Prob. 20.7SC Ch. 20 - What is meant by the term “unsaturated...Ch. 20 - Prob. 2ALQ

Solution Summary: The author explains that the structural formula and name of the reactions between ethane and chlorine should be determined.

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