Introduction to General, Organic and Biochemistry
11th Edition
ISBN: 9781285869759
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 2, Problem 2.94P
2-94 Using your knowledge of trends in element sizes in going across a period of the Periodic Table, exp lain why the density of the elements increases from potassium through vanadium. (Recall from Section 1-7 that specific gravity is numerically the same as density but has no units.)
Element Specific Gravity
K 0.862
Ca 1.55
Se 2.99
Ti 4.54
V 6.11
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f) The unusual molecule [2.2.2] propellane is pictured.
1) Given the bond length and bond angles in the image, what hybridization scheme
best describes the carbons marked by the askerisks?
2) What types of orbitals are used in the bond between the two carbons marked by
the askerisks?
3) How does this bond compare to an ordinary carbon-carbon bond (which is usually
1.54 Å long)?
CH2 1.60Å
H₂C *
H₂C
CH2
C
H2C
*
C
Of
H₂
120°
e) Determine the hybridization and geometry around the indicated carbon atoms.
H3C
CH3
B
HC
CH2
A
C
C
C
CH3
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Chapter 2 Solutions
Introduction to General, Organic and Biochemistry
Ch. 2.2 - Problem 2-1 Write the formulas of compounds in...Ch. 2.4 - Problem 2-2 What is the mass number of an atom...Ch. 2.4 - Problem 2-3 Name the elements given in Problem...Ch. 2.4 - Problem 2-4 (a) What are the atomic numbers of...Ch. 2.4 - Prob. 2.5PCh. 2.4 - Problem 2-6 The atomic weight of lithium is 6.941...Ch. 2.6 - Problem 2-7 Write the Lewis dot structure for the...Ch. 2 - Prob. 2.8PCh. 2 - 9 Answer true or false. (a) Matter is divided into...Ch. 2 - Prob. 2.10P
Ch. 2 - Prob. 2.11PCh. 2 - 2-12 The elements game, Part 1. Name and give the...Ch. 2 - Prob. 2.13PCh. 2 - Prob. 2.14PCh. 2 - Prob. 2.15PCh. 2 - Prob. 2.16PCh. 2 - 2-17 How does Dalton’s atomic theory explain: (a)...Ch. 2 - Prob. 2.18PCh. 2 - Prob. 2.19PCh. 2 - 2-20 Calculate the percentage of hydrogen and...Ch. 2 - Prob. 2.21PCh. 2 - Prob. 2.22PCh. 2 - 2-23 It has been said, “The number of protons...Ch. 2 - Prob. 2.24PCh. 2 - Prob. 2.25PCh. 2 - 2-26 Given these mass numbers and number of...Ch. 2 - 2-27 If each atom in Problem 2-26 acquired two...Ch. 2 - Prob. 2.28PCh. 2 - 2-29 How many protons and how many neutrons does...Ch. 2 - Prob. 2.30PCh. 2 - 2-31 Tin-118 is one of the isotopes of tin. Name...Ch. 2 - Prob. 2.32PCh. 2 - Prob. 2.33PCh. 2 - 2-34 There are only two naturally occurring...Ch. 2 - 2-35 The two most abundant naturally occurring...Ch. 2 - Prob. 2.36PCh. 2 - Prob. 2.37PCh. 2 - Prob. 2.38PCh. 2 - Prob. 2.39PCh. 2 - Prob. 2.40PCh. 2 - Prob. 2.41PCh. 2 - Prob. 2.42PCh. 2 - 2-43 Which group(s) of the Periodic Table...Ch. 2 - 2-44 Which period(s) in the Periodic Table...Ch. 2 - Prob. 2.45PCh. 2 - Prob. 2.46PCh. 2 - 2-47 Which element in each pair is more metallic?...Ch. 2 - Prob. 2.48PCh. 2 - Prob. 2.49PCh. 2 - Prob. 2.50PCh. 2 - 2-51 What is the correlation between the group...Ch. 2 - Prob. 2.52PCh. 2 - Prob. 2.53PCh. 2 - Prob. 2.54PCh. 2 - Prob. 2.55PCh. 2 - Prob. 2.56PCh. 2 - Prob. 2.57PCh. 2 - Prob. 2.58PCh. 2 - 2-59 You are presented with a Lewis dot structure...Ch. 2 - Prob. 2.60PCh. 2 - Prob. 2.61PCh. 2 - Prob. 2.62PCh. 2 - Prob. 2.63PCh. 2 - 2-64 Consider the elements B, C, and N. Using only...Ch. 2 - Prob. 2.65PCh. 2 - Prob. 2.66PCh. 2 - 2-67 Account for the fact that the first...Ch. 2 - Prob. 2.68PCh. 2 - 2-69 (Chemical Connections 2A) Why does the body...Ch. 2 - Prob. 2.70PCh. 2 - Prob. 2.71PCh. 2 - Prob. 2.72PCh. 2 - 2-73 (Chemical Connections 2D) Copper is a soft...Ch. 2 - Prob. 2.74PCh. 2 - Prob. 2.75PCh. 2 - Prob. 2.76PCh. 2 - Prob. 2.77PCh. 2 - Prob. 2.78PCh. 2 - Prob. 2.79PCh. 2 - Prob. 2.80PCh. 2 - Prob. 2.81PCh. 2 - Prob. 2.82PCh. 2 - 2-83 The natural abundance of boron isotopes is as...Ch. 2 - Prob. 2.84PCh. 2 - 2-85 The mass of a proton is 1.67 × 10-24g. The...Ch. 2 - Prob. 2.86PCh. 2 - Prob. 2.87PCh. 2 - Prob. 2.88PCh. 2 - 2-89 Assume that a new element has been discovered...Ch. 2 - Prob. 2.90PCh. 2 - 2-91 These are the first two ionization energy for...Ch. 2 - Prob. 2.92PCh. 2 - Prob. 2.93PCh. 2 - 2-94 Using your knowledge of trends in element...Ch. 2 - Prob. 2.95PCh. 2 - Prob. 2.96PCh. 2 - 2-97 Explain why the Ca3+ ion is not found in...Ch. 2 - 2-98 Explain how the ionization energy of atoms...Ch. 2 - 2-99 A 7.12 g sample of magnesium is heated with...Ch. 2 - 2-100 A 0.100 g sample of magnesium, when combined...Ch. 2 - 2-101 Complete the following table: Symbol Atomic...Ch. 2 - 2-102 An element consists of 90.51% of an isotope...Ch. 2 - 2-103 The element silver has two naturally...Ch. 2 - 2-104 The average atomic weight of lithium is...Ch. 2 - Prob. 2.105PCh. 2 - Prob. 2.106P
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