Introduction to General, Organic and Biochemistry
11th Edition
ISBN: 9781285869759
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Question
Chapter 2, Problem 2.19P
Interpretation Introduction
Interpretation:
Whether the given compositions disprove Proust’s law of constant composition or not.
The compound carbon monoxide contains 42.9%, carbon and 57.1% oxygen. The compound carbon dioxide contains 27.3% carbon and 72.7% oxygen.
Concept Introduction:
The law of constant composition or the law of definite composition sometimes called Proust's law which explains that a chemical compound does not depend on its source and method of preparation but always comprises its component elements in fixed ratio (by mass).
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04: (a) Nitrogen occurs naturally as 2 isotopes: N-14 and N-15
Nitrogen has an atomic number of 7. Suppose it gains 3 electrons. Draw the
structure of N ion which is formed, write down its formula and state whether it is a
cation or an anion.
(1)
The abundance of N-14 and N-15 are 99.6% and 0.4% respectively. What is the
atomic mass of N? Show all your working clearly.
(ii)
Write down the formula for the element Nitrogen
(b) Isotopes of certain elements, such as carbon-14 can be used in biochemical and medical
research. The second isotope of these elements is radioactive, is called a radioisotope and
is used in research because it has the same chemical properties as the non-radioactive
isotope. Why are the chemical properties of all isotopes of the same element identical?
O O D
Imagine that you have discovered several stable isotopes of a new element, which you call element X. The measured isotope masses and abundances are given in the table below.
Percent Abundance
Mass (amu)
353.1165
354.1330
356.3666
Isotope
353X
354X
356X
10.909%
41.304%
47.787%
What is the average atomic mass of this new element X? Provide at least 5 significant figures (2 decimal places) in your answer.
Show all of your work and calculations in the answer box below. You will not get full credit for this question if you do not show your work.
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Pick an element from the Periodic Table AFTER number 25, Mn, and do not pick a diatomic element. Pick something different and fun! Now answer the following questions on a piece of paper which you will upload as a pdf file, and show all your work with units for calculations for any credit. Use your CHM 130 Periodic Table for molar masses and use 6.02 x 1023 for Avogadro's number or you may be counted wrong!!!
1. What is the symbol for your element? (Must be after Mn in Periodic Table)
2. What is the molar mass of your element? (include units)
3. How many atoms are in a mole of your element? (No calculation needed)
4. If you had 14.5 grams of your element, how many moles is that?
5. If you had 14.5 grams of your element, how many atoms is that?
6. Theoretically speaking, if your element was in the gas state at STP, how many grams is 2.25 liters of your element? (Most elements are not gases at STP so this question is just theoretical) You may not use the Ideal Gas Law to solve this.
Chapter 2 Solutions
Introduction to General, Organic and Biochemistry
Ch. 2.2 - Problem 2-1 Write the formulas of compounds in...Ch. 2.4 - Problem 2-2 What is the mass number of an atom...Ch. 2.4 - Problem 2-3 Name the elements given in Problem...Ch. 2.4 - Problem 2-4 (a) What are the atomic numbers of...Ch. 2.4 - Prob. 2.5PCh. 2.4 - Problem 2-6 The atomic weight of lithium is 6.941...Ch. 2.6 - Problem 2-7 Write the Lewis dot structure for the...Ch. 2 - Prob. 2.8PCh. 2 - 9 Answer true or false. (a) Matter is divided into...Ch. 2 - Prob. 2.10P
Ch. 2 - Prob. 2.11PCh. 2 - 2-12 The elements game, Part 1. Name and give the...Ch. 2 - Prob. 2.13PCh. 2 - Prob. 2.14PCh. 2 - Prob. 2.15PCh. 2 - Prob. 2.16PCh. 2 - 2-17 How does Dalton’s atomic theory explain: (a)...Ch. 2 - Prob. 2.18PCh. 2 - Prob. 2.19PCh. 2 - 2-20 Calculate the percentage of hydrogen and...Ch. 2 - Prob. 2.21PCh. 2 - Prob. 2.22PCh. 2 - 2-23 It has been said, “The number of protons...Ch. 2 - Prob. 2.24PCh. 2 - Prob. 2.25PCh. 2 - 2-26 Given these mass numbers and number of...Ch. 2 - 2-27 If each atom in Problem 2-26 acquired two...Ch. 2 - Prob. 2.28PCh. 2 - 2-29 How many protons and how many neutrons does...Ch. 2 - Prob. 2.30PCh. 2 - 2-31 Tin-118 is one of the isotopes of tin. Name...Ch. 2 - Prob. 2.32PCh. 2 - Prob. 2.33PCh. 2 - 2-34 There are only two naturally occurring...Ch. 2 - 2-35 The two most abundant naturally occurring...Ch. 2 - Prob. 2.36PCh. 2 - Prob. 2.37PCh. 2 - Prob. 2.38PCh. 2 - Prob. 2.39PCh. 2 - Prob. 2.40PCh. 2 - Prob. 2.41PCh. 2 - Prob. 2.42PCh. 2 - 2-43 Which group(s) of the Periodic Table...Ch. 2 - 2-44 Which period(s) in the Periodic Table...Ch. 2 - Prob. 2.45PCh. 2 - Prob. 2.46PCh. 2 - 2-47 Which element in each pair is more metallic?...Ch. 2 - Prob. 2.48PCh. 2 - Prob. 2.49PCh. 2 - Prob. 2.50PCh. 2 - 2-51 What is the correlation between the group...Ch. 2 - Prob. 2.52PCh. 2 - Prob. 2.53PCh. 2 - Prob. 2.54PCh. 2 - Prob. 2.55PCh. 2 - Prob. 2.56PCh. 2 - Prob. 2.57PCh. 2 - Prob. 2.58PCh. 2 - 2-59 You are presented with a Lewis dot structure...Ch. 2 - Prob. 2.60PCh. 2 - Prob. 2.61PCh. 2 - Prob. 2.62PCh. 2 - Prob. 2.63PCh. 2 - 2-64 Consider the elements B, C, and N. Using only...Ch. 2 - Prob. 2.65PCh. 2 - Prob. 2.66PCh. 2 - 2-67 Account for the fact that the first...Ch. 2 - Prob. 2.68PCh. 2 - 2-69 (Chemical Connections 2A) Why does the body...Ch. 2 - Prob. 2.70PCh. 2 - Prob. 2.71PCh. 2 - Prob. 2.72PCh. 2 - 2-73 (Chemical Connections 2D) Copper is a soft...Ch. 2 - Prob. 2.74PCh. 2 - Prob. 2.75PCh. 2 - Prob. 2.76PCh. 2 - Prob. 2.77PCh. 2 - Prob. 2.78PCh. 2 - Prob. 2.79PCh. 2 - Prob. 2.80PCh. 2 - Prob. 2.81PCh. 2 - Prob. 2.82PCh. 2 - 2-83 The natural abundance of boron isotopes is as...Ch. 2 - Prob. 2.84PCh. 2 - 2-85 The mass of a proton is 1.67 × 10-24g. The...Ch. 2 - Prob. 2.86PCh. 2 - Prob. 2.87PCh. 2 - Prob. 2.88PCh. 2 - 2-89 Assume that a new element has been discovered...Ch. 2 - Prob. 2.90PCh. 2 - 2-91 These are the first two ionization energy for...Ch. 2 - Prob. 2.92PCh. 2 - Prob. 2.93PCh. 2 - 2-94 Using your knowledge of trends in element...Ch. 2 - Prob. 2.95PCh. 2 - Prob. 2.96PCh. 2 - 2-97 Explain why the Ca3+ ion is not found in...Ch. 2 - 2-98 Explain how the ionization energy of atoms...Ch. 2 - 2-99 A 7.12 g sample of magnesium is heated with...Ch. 2 - 2-100 A 0.100 g sample of magnesium, when combined...Ch. 2 - 2-101 Complete the following table: Symbol Atomic...Ch. 2 - 2-102 An element consists of 90.51% of an isotope...Ch. 2 - 2-103 The element silver has two naturally...Ch. 2 - 2-104 The average atomic weight of lithium is...Ch. 2 - Prob. 2.105PCh. 2 - Prob. 2.106P
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Similar questions
- 2-17 How does Dalton’s atomic theory explain: (a) the law of conservation of mass? (b) the law of constant composition?arrow_forward2-100 A 0.100 g sample of magnesium, when combined with oxygen, yields 0.166 g of magnesium oxide. What masses of magnesium and oxygen must be combined to make exactly 2.00 g of magnesium oxide?arrow_forward2-73 (Chemical Connections 2D) Copper is a soft metal. how can it be made harder?arrow_forward
- 2-43 Which group(s) of the Periodic Table contain(s): (a) Only metals? (b) Only metalloids? (c) Only nonmetals?arrow_forward2-99 A 7.12 g sample of magnesium is heated with 1.80 g of bromine. All the bromine is used up, and 2.07 g of magnesium bromide is produced. What mass of magnesium remains unreacted?arrow_forward2-83 The natural abundance of boron isotopes is as follows: 19.9sf boron-l0 (10.013 amu) and 80.1% boron-11 (11.009 amu). Calculate the atomic weight of boron (watch the significant figures) and compare your calculated value with that given in the Periodic Table.arrow_forward
- Reference Section 5-2 to find the atomic masses of 12C and 13C, the relative abundance of 12C and 13C in natural carbon, and the average mass (in u) of a carbon atom. If you had a sample of natural carbon containing exactly 10,000 atoms, determine the number of 12C and 13C atoms present. What would be the average mass (in u) and the total mass (in u) of the carbon atoms in this 10,000-atom sample? If you had a sample of natural carbon containing 6.0221 1023 atoms, determine the number of 12C and 13C atoms present What would be the average mass (in u) and the total mass (in u) of this 6.0221 1023 atom sample? Given that 1 g = 6.0221 1023 u, what is the total mass of I mole of natural carbon in units of grams?arrow_forward3-45 Which formulas are not correct? For each that is not correct, write the correct formula. (a) Ammonium phosphate; (NH4 )2PO4 (b) Barium carbonate; Ba2CO3 (c) Aluminum sulfide; Al2S3 (d) Magnesium sulfide; MgSarrow_forward3-58 In Section 2-3B, we saw that there are seven diatomic elements. (a) Draw Lewis structures for each of these diatomic elements. (b) Which diatomic elements are gases at room temperature? Which are liquids? Which are solids?arrow_forward
- The mass spectrum of CH3Cl is illustrated here. You know that carbon has two stable isotopes, and 13C with relative abundances of 98.9% and 1.1%, respectively, and chlorine has two isotopes, 35a and 37CI with abundances of 75.77% and 24.23%, respectively. (a) What molecular species gives rise to the lines at m/Z of 50 and 52? Why is the line at 52 about 1/3 the height of the line at 50? (b) What species might be responsible for the line at m/Z = 51?arrow_forwardPayalbenarrow_forward7B-2. Consider this chemical reaction: 2 MnI2(s) + 13 F2(g) 2 MNF3(s) + 4 IFs(1) If 83.5 kilograms of manganese(IIl) fluoride are produced, then how many liters of iodine pentafluoride are also produced? The density of iodine pentafluoride is 3.75 g/mL.arrow_forward
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