Introduction to General, Organic and Biochemistry
11th Edition
ISBN: 9781285869759
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 2.6, Problem 2.7P
Problem 2-7
Write the Lewis dot structure for the element that has the following ground-state electron configuration. What is the name of this element?
1s22s22p2x2p2y2p2z3s23p1x
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It is not unexpected that the methoxyl substituent on a cyclohexane ring
prefers to adopt the equatorial conformation.
OMe
H
A G₂ = +0.6 kcal/mol
OMe
What is unexpected is that the closely related 2-methoxytetrahydropyran
prefers the axial conformation:
H
H
OMe
OMe
A Gp=-0.6 kcal/mol
Methoxy: CH3O group
Please be specific and clearly write the reason why this is observed. This effect that provides
stabilization of the axial OCH 3 group in this molecule is called the anomeric effect. [Recall in the way of
example, the staggered conformer of ethane is more stable than eclipsed owing to bonding MO
interacting with anti-bonding MO...]
206 Pb
82
Express your answers as integers. Enter your answers separated by a comma.
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VAΣ
ΜΕ ΑΣΦ
Np, N₁ = 82,126
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?
protons, neutrons
Please draw the inverted chair forms of the products for the two equilibrium reactions
shown below. Circle the equilibrium reaction that would have a AG = 0, i.e., the relative energy of
the reactant (to the left of the equilibrium arrows) equals the relative energy of the product? [No
requirement to show or do calculations.]
CH3
CH3
HH
CH3
1
-CH3
Chapter 2 Solutions
Introduction to General, Organic and Biochemistry
Ch. 2.2 - Problem 2-1 Write the formulas of compounds in...Ch. 2.4 - Problem 2-2 What is the mass number of an atom...Ch. 2.4 - Problem 2-3 Name the elements given in Problem...Ch. 2.4 - Problem 2-4 (a) What are the atomic numbers of...Ch. 2.4 - Prob. 2.5PCh. 2.4 - Problem 2-6 The atomic weight of lithium is 6.941...Ch. 2.6 - Problem 2-7 Write the Lewis dot structure for the...Ch. 2 - Prob. 2.8PCh. 2 - 9 Answer true or false. (a) Matter is divided into...Ch. 2 - Prob. 2.10P
Ch. 2 - Prob. 2.11PCh. 2 - 2-12 The elements game, Part 1. Name and give the...Ch. 2 - Prob. 2.13PCh. 2 - Prob. 2.14PCh. 2 - Prob. 2.15PCh. 2 - Prob. 2.16PCh. 2 - 2-17 How does Dalton’s atomic theory explain: (a)...Ch. 2 - Prob. 2.18PCh. 2 - Prob. 2.19PCh. 2 - 2-20 Calculate the percentage of hydrogen and...Ch. 2 - Prob. 2.21PCh. 2 - Prob. 2.22PCh. 2 - 2-23 It has been said, “The number of protons...Ch. 2 - Prob. 2.24PCh. 2 - Prob. 2.25PCh. 2 - 2-26 Given these mass numbers and number of...Ch. 2 - 2-27 If each atom in Problem 2-26 acquired two...Ch. 2 - Prob. 2.28PCh. 2 - 2-29 How many protons and how many neutrons does...Ch. 2 - Prob. 2.30PCh. 2 - 2-31 Tin-118 is one of the isotopes of tin. Name...Ch. 2 - Prob. 2.32PCh. 2 - Prob. 2.33PCh. 2 - 2-34 There are only two naturally occurring...Ch. 2 - 2-35 The two most abundant naturally occurring...Ch. 2 - Prob. 2.36PCh. 2 - Prob. 2.37PCh. 2 - Prob. 2.38PCh. 2 - Prob. 2.39PCh. 2 - Prob. 2.40PCh. 2 - Prob. 2.41PCh. 2 - Prob. 2.42PCh. 2 - 2-43 Which group(s) of the Periodic Table...Ch. 2 - 2-44 Which period(s) in the Periodic Table...Ch. 2 - Prob. 2.45PCh. 2 - Prob. 2.46PCh. 2 - 2-47 Which element in each pair is more metallic?...Ch. 2 - Prob. 2.48PCh. 2 - Prob. 2.49PCh. 2 - Prob. 2.50PCh. 2 - 2-51 What is the correlation between the group...Ch. 2 - Prob. 2.52PCh. 2 - Prob. 2.53PCh. 2 - Prob. 2.54PCh. 2 - Prob. 2.55PCh. 2 - Prob. 2.56PCh. 2 - Prob. 2.57PCh. 2 - Prob. 2.58PCh. 2 - 2-59 You are presented with a Lewis dot structure...Ch. 2 - Prob. 2.60PCh. 2 - Prob. 2.61PCh. 2 - Prob. 2.62PCh. 2 - Prob. 2.63PCh. 2 - 2-64 Consider the elements B, C, and N. Using only...Ch. 2 - Prob. 2.65PCh. 2 - Prob. 2.66PCh. 2 - 2-67 Account for the fact that the first...Ch. 2 - Prob. 2.68PCh. 2 - 2-69 (Chemical Connections 2A) Why does the body...Ch. 2 - Prob. 2.70PCh. 2 - Prob. 2.71PCh. 2 - Prob. 2.72PCh. 2 - 2-73 (Chemical Connections 2D) Copper is a soft...Ch. 2 - Prob. 2.74PCh. 2 - Prob. 2.75PCh. 2 - Prob. 2.76PCh. 2 - Prob. 2.77PCh. 2 - Prob. 2.78PCh. 2 - Prob. 2.79PCh. 2 - Prob. 2.80PCh. 2 - Prob. 2.81PCh. 2 - Prob. 2.82PCh. 2 - 2-83 The natural abundance of boron isotopes is as...Ch. 2 - Prob. 2.84PCh. 2 - 2-85 The mass of a proton is 1.67 × 10-24g. The...Ch. 2 - Prob. 2.86PCh. 2 - Prob. 2.87PCh. 2 - Prob. 2.88PCh. 2 - 2-89 Assume that a new element has been discovered...Ch. 2 - Prob. 2.90PCh. 2 - 2-91 These are the first two ionization energy for...Ch. 2 - Prob. 2.92PCh. 2 - Prob. 2.93PCh. 2 - 2-94 Using your knowledge of trends in element...Ch. 2 - Prob. 2.95PCh. 2 - Prob. 2.96PCh. 2 - 2-97 Explain why the Ca3+ ion is not found in...Ch. 2 - 2-98 Explain how the ionization energy of atoms...Ch. 2 - 2-99 A 7.12 g sample of magnesium is heated with...Ch. 2 - 2-100 A 0.100 g sample of magnesium, when combined...Ch. 2 - 2-101 Complete the following table: Symbol Atomic...Ch. 2 - 2-102 An element consists of 90.51% of an isotope...Ch. 2 - 2-103 The element silver has two naturally...Ch. 2 - 2-104 The average atomic weight of lithium is...Ch. 2 - Prob. 2.105PCh. 2 - Prob. 2.106P
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- 5. Please consider the Newman projection of tartaric acid drawn below as an eclipsed conformer (1). Please draw the most stable conformer and two intermediate energy conformers noting that staggered conformers are lower in energy than eclipsed forms even if the staggered conformers have gauche relationships between groups. [Draw the substituents H and OH on the front carbons and H, OH and CO₂H on the back carbons based on staggered forms. -CO₂H is larger than -OH.] OH COH ICOOH COOH COOH 1 2 COOH COOH 3 4 Staggered Staggered Staggered (most stable) Indicate the number of each conformer above (1, 2, 3 and 4) that corresponds to the relative energies below. Ref=0 Rotation 6. (60 points) a. Are compounds 1 and 2 below enantiomers, diastereomers or identical? OH OH HO HO LOH HO HO OH 2 OH OH b. Please complete the zig-zag conformation of the compound (3R,4S)-3,4-dichloro-2,5-dimethylhexane by writing the respective atoms in the boxes. 3.arrow_forwardThe plutonium isotope with 144 neutrons Enter the chemical symbol of the isotope.arrow_forwardThe mass ratio of sodium to fluorine in sodium fluoride is 1.21:1. A sample of sodium fluoride produced 26.1 gg of sodium upon decomposition. How much fluorine was formed?arrow_forward
- 32S 16 Enter your answers numerically separated by a comma. Np. Nn = 跖 ΟΙ ΑΣΦ Submit Request Answer ? protons, neutronsarrow_forward2. Which dimethylcyclohexane compounds shown below exhibit symmetry and therefore are not chiral and would not rotate plane polarized light. 1 CH3 CH CH3 CH3 2 3 CH3arrow_forwardDon't used hand raitingarrow_forward
- Can you please explain why the answer is structures 2 and 3? Please include a detailed explanation and show how the synthesis can be done with those two structures.arrow_forwardCan you please explain why the correct answer to this question is option 2? I am having trouble understanding how and why. Please provide a detailed explanation and a drawing of how the diene and dienophile would create the product in the question.arrow_forwardCan you please explain why the correct answer is molecules 2 and 4? Base your explanation off of the rules for aromaticity and well as the principles of the Huckel rule of aromaticity. Please give a detailed explanation of what Hucekl's rule is.arrow_forward
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