EBK FOUNDATIONS OF COLLEGE CHEMISTRY
EBK FOUNDATIONS OF COLLEGE CHEMISTRY
15th Edition
ISBN: 9781118930144
Author: Willard
Publisher: JOHN WILEY+SONS INC.
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Chapter 19, Problem 89AE
Interpretation Introduction

Interpretation:

The four identified functional groups in the given imaginary molecule has to be named.

Concept Introduction:

Alkyl halides:

Alkyl halides are halogenated hydrocarbons with the formula, RX in that molecules one of the hydrogen atom is substituted with the halogen atom such as F, Cl, Br and I. The general formula of alkyl halides is represented as follows:

EBK FOUNDATIONS OF COLLEGE CHEMISTRY, Chapter 19, Problem 89AE , additional homework tip  1

Alcohols:

Alcohols are organic compounds whose molecules contains the hydroxyl (OH) functional group bonded to sp3 hybridized carbon. The general formula of alkyl halides is represented as follows:

EBK FOUNDATIONS OF COLLEGE CHEMISTRY, Chapter 19, Problem 89AE , additional homework tip  2

Esters:

Esters are a class of organic compounds that can be derived from the dehydration reaction of carboxylic acids with alcohols. The generalized formula of esters is shown below:

EBK FOUNDATIONS OF COLLEGE CHEMISTRY, Chapter 19, Problem 89AE , additional homework tip  3

Ethers:

Ethers are organic compounds in which the sp3 hybridized oxygen atom is directly bonded to two alkyl groups. The general formula for ethers is shown here.

EBK FOUNDATIONS OF COLLEGE CHEMISTRY, Chapter 19, Problem 89AE , additional homework tip  4

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What are the IUPAC Names of all the compounds in the picture?
1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)
19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+

Chapter 19 Solutions

EBK FOUNDATIONS OF COLLEGE CHEMISTRY

Ch. 19.10 - Prob. 19.11PCh. 19.11 - Prob. 19.12PCh. 19.12 - Prob. 19.13PCh. 19 - Prob. 1RQCh. 19 - Prob. 2RQCh. 19 - Prob. 3RQCh. 19 - Prob. 4RQCh. 19 - Prob. 5RQCh. 19 - Prob. 6RQCh. 19 - Prob. 7RQCh. 19 - Prob. 8RQCh. 19 - Prob. 9RQCh. 19 - Prob. 10RQCh. 19 - Prob. 11RQCh. 19 - Prob. 12RQCh. 19 - Prob. 13RQCh. 19 - Prob. 14RQCh. 19 - Prob. 15RQCh. 19 - Prob. 16RQCh. 19 - Prob. 17RQCh. 19 - Prob. 18RQCh. 19 - Prob. 19RQCh. 19 - Prob. 20RQCh. 19 - Prob. 21RQCh. 19 - Prob. 23RQCh. 19 - Prob. 24RQCh. 19 - Prob. 25RQCh. 19 - Prob. 26RQCh. 19 - Prob. 27RQCh. 19 - Prob. 28RQCh. 19 - Prob. 29RQCh. 19 - Prob. 30RQCh. 19 - Prob. 31RQCh. 19 - Prob. 32RQCh. 19 - Prob. 33RQCh. 19 - Prob. 34RQCh. 19 - Prob. 35RQCh. 19 - Prob. 36RQCh. 19 - Prob. 37RQCh. 19 - Prob. 1PECh. 19 - Prob. 2PECh. 19 - Prob. 3PECh. 19 - Prob. 4PECh. 19 - Prob. 5PECh. 19 - Prob. 6PECh. 19 - Prob. 7PECh. 19 - Prob. 8PECh. 19 - Prob. 9PECh. 19 - Prob. 10PECh. 19 - Prob. 11PECh. 19 - Prob. 12PECh. 19 - Prob. 13PECh. 19 - Prob. 14PECh. 19 - Prob. 15PECh. 19 - Prob. 16PECh. 19 - Prob. 17PECh. 19 - Prob. 18PECh. 19 - Prob. 19PECh. 19 - Prob. 20PECh. 19 - Prob. 21PECh. 19 - Prob. 22PECh. 19 - Prob. 23PECh. 19 - Prob. 24PECh. 19 - Prob. 25PECh. 19 - Prob. 26PECh. 19 - Prob. 27PECh. 19 - Prob. 28PECh. 19 - Prob. 29PECh. 19 - Prob. 30PECh. 19 - Prob. 31PECh. 19 - Prob. 32PECh. 19 - Prob. 33PECh. 19 - Prob. 34PECh. 19 - Prob. 35PECh. 19 - Prob. 36PECh. 19 - Prob. 37PECh. 19 - Prob. 38PECh. 19 - Prob. 39PECh. 19 - Prob. 40PECh. 19 - Prob. 41PECh. 19 - Prob. 42PECh. 19 - Prob. 43PECh. 19 - Prob. 44PECh. 19 - Prob. 45PECh. 19 - Prob. 46PECh. 19 - Prob. 47PECh. 19 - Prob. 48PECh. 19 - Prob. 49PECh. 19 - Prob. 50PECh. 19 - Prob. 51PECh. 19 - Prob. 52PECh. 19 - Prob. 53PECh. 19 - Prob. 54PECh. 19 - Prob. 55PECh. 19 - Prob. 56PECh. 19 - Prob. 57PECh. 19 - Prob. 58PECh. 19 - Prob. 59PECh. 19 - Prob. 60PECh. 19 - Prob. 61PECh. 19 - Prob. 62PECh. 19 - Prob. 63PECh. 19 - Prob. 64PECh. 19 - Prob. 65AECh. 19 - Prob. 66AECh. 19 - Prob. 67AECh. 19 - Prob. 68AECh. 19 - Prob. 69AECh. 19 - Prob. 70AECh. 19 - Prob. 71AECh. 19 - Prob. 72AECh. 19 - Prob. 73AECh. 19 - Prob. 74AECh. 19 - Prob. 75AECh. 19 - Prob. 76AECh. 19 - Prob. 77AECh. 19 - Prob. 78AECh. 19 - Prob. 79AECh. 19 - Prob. 80AECh. 19 - Prob. 81AECh. 19 - Prob. 82AECh. 19 - Prob. 83AECh. 19 - Prob. 84AECh. 19 - Prob. 85AECh. 19 - Prob. 86AECh. 19 - Prob. 87AECh. 19 - Prob. 89AECh. 19 - Prob. 90AE
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