The reason corresponding to the fact that p − hydroxy benzoic acid is less acidic than benzoic acid, o − hydroxy benzoic acid is slightly more acidic than benzoic acid is to be explained. Concept introduction: The inductive effect is due to the difference in electronegativity between the atoms. Its effect decreases as the number of carbon atoms increase. Electron withdrawing groups shows − I effect and electron releasing group shows + I effect.

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Answer 1

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Chapter 19, Problem 19.70P

Interpretation Introduction

Interpretation: The reason corresponding to the fact that p− hydroxy benzoic acid is less acidic than benzoic acid, o− hydroxy benzoic acid is slightly more acidic than benzoic acid is to be explained.

Concept introduction: The inductive effect is due to the difference in electronegativity between the atoms. Its effect decreases as the number of carbon atoms increase. Electron withdrawing groups shows −I effect and electron releasing group shows +I effect.

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Rank the following compounds in their correct order of acidity. 1=Most acidic and 4=least acidic.

Answer 2

Question

Chapter 19, Problem 19.70P

Interpretation Introduction

Interpretation: The reason corresponding to the fact that p− hydroxy benzoic acid is less acidic than benzoic acid, o− hydroxy benzoic acid is slightly more acidic than benzoic acid is to be explained.

Concept introduction: The inductive effect is due to the difference in electronegativity between the atoms. Its effect decreases as the number of carbon atoms increase. Electron withdrawing groups shows −I effect and electron releasing group shows +I effect.

Expert Solution & Answer

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Answer 3

Question

Chapter 19, Problem 19.70P

Interpretation Introduction

Interpretation: The reason corresponding to the fact that p− hydroxy benzoic acid is less acidic than benzoic acid, o− hydroxy benzoic acid is slightly more acidic than benzoic acid is to be explained.

Concept introduction: The inductive effect is due to the difference in electronegativity between the atoms. Its effect decreases as the number of carbon atoms increase. Electron withdrawing groups shows −I effect and electron releasing group shows +I effect.

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Answer 4

Question

Chapter 19, Problem 19.70P

Interpretation Introduction

Interpretation: The reason corresponding to the fact that p− hydroxy benzoic acid is less acidic than benzoic acid, o− hydroxy benzoic acid is slightly more acidic than benzoic acid is to be explained.

Concept introduction: The inductive effect is due to the difference in electronegativity between the atoms. Its effect decreases as the number of carbon atoms increase. Electron withdrawing groups shows −I effect and electron releasing group shows +I effect.

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Answer 5

Chapter 19, Problem 19.70P

Interpretation Introduction

Interpretation: The reason corresponding to the fact that p− hydroxy benzoic acid is less acidic than benzoic acid, o− hydroxy benzoic acid is slightly more acidic than benzoic acid is to be explained.

Concept introduction: The inductive effect is due to the difference in electronegativity between the atoms. Its effect decreases as the number of carbon atoms increase. Electron withdrawing groups shows −I effect and electron releasing group shows +I effect.

Answer 6

Chapter 19, Problem 19.70P

Interpretation Introduction

Interpretation: The reason corresponding to the fact that p− hydroxy benzoic acid is less acidic than benzoic acid, o− hydroxy benzoic acid is slightly more acidic than benzoic acid is to be explained.

Concept introduction: The inductive effect is due to the difference in electronegativity between the atoms. Its effect decreases as the number of carbon atoms increase. Electron withdrawing groups shows −I effect and electron releasing group shows +I effect.

Answer 7

Chapter 19, Problem 19.70P

Interpretation Introduction

Interpretation: The reason corresponding to the fact that p− hydroxy benzoic acid is less acidic than benzoic acid, o− hydroxy benzoic acid is slightly more acidic than benzoic acid is to be explained.

Concept introduction: The inductive effect is due to the difference in electronegativity between the atoms. Its effect decreases as the number of carbon atoms increase. Electron withdrawing groups shows −I effect and electron releasing group shows +I effect.

Answer 8

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Answer 11

Ch. 19 - Prob. 19.1P Ch. 19 - Problem 19.2 Give the structure corresponding to...Ch. 19 - Problem 19.3 Draw the structure corresponding to...Ch. 19 - Prob. 19.4P Ch. 19 - Prob. 19.5P Ch. 19 - Problem 19.6 Rank the following compounds in order...Ch. 19 - Problem 19.7 Explain how you could use IR...Ch. 19 - Prob. 19.8P Ch. 19 - Problem 19.9 How many tetrahedral stereogenic...Ch. 19 - Problem 19.10 What alcohol can be oxidized to each...

Solution Summary: The author explains the inductive effect of p- hydroxy benzoic acid, and the strength of its conjugate base.

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