Principles of Instrumental Analysis
7th Edition
ISBN: 9781305577213
Author: Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher: Cengage Learning
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Question
Chapter 19, Problem 19.33QAP
Interpretation Introduction
Interpretation:
The name of the organic compound from the following proton NMR data should be predicted.
Concept introduction:
Nuclear magnetic resonance is a technique that is used to predict the structural formula of the compound. NMR spectroscopy involves the examination of the nucleus under the external magnetic field.
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In a 300 MHz NMR spectrometer, A) what is the
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OA) 25 MHz; B) 0.35 ppm
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OA) 25 MHz; B) 0.55 ppm
What would be the nuclear magnetic resonance spectrum for a proton resonance line that was split by interaction with seven identical protons?
Sketch the form of an A3M2X4 spectrum, where A, M, and X are protons with distinctly different chemical shifts and JAM > JAX > JMX ·
Chapter 19 Solutions
Principles of Instrumental Analysis
Ch. 19 - Prob. 19.1QAPCh. 19 - Prob. 19.2QAPCh. 19 - Prob. 19.3QAPCh. 19 - Prob. 19.4QAPCh. 19 - Prob. 19.5QAPCh. 19 - A nucleus has a spin quantum number of 7/2. How...Ch. 19 - Prob. 19.7QAPCh. 19 - Prob. 19.8QAPCh. 19 - Prob. 19.9QAPCh. 19 - Why is 133C-133C spin-spin splitting not observed...
Ch. 19 - Prob. 19.11QAPCh. 19 - Prob. 19.12QAPCh. 19 - Prob. 19.13QAPCh. 19 - What is a rotating frame of reference?Ch. 19 - How will E for an isolated 13C nucleus compare...Ch. 19 - Prob. 19.16QAPCh. 19 - Prob. 19.17QAPCh. 19 - Prob. 19.18QAPCh. 19 - Prob. 19.19QAPCh. 19 - Prob. 19.20QAPCh. 19 - Prob. 19.21QAPCh. 19 - Prob. 19.22QAPCh. 19 - Prob. 19.23QAPCh. 19 - Prob. 19.24QAPCh. 19 - Prob. 19.25QAPCh. 19 - Prob. 19.26QAPCh. 19 - Prob. 19.27QAPCh. 19 - Prob. 19.28QAPCh. 19 - Prob. 19.29QAPCh. 19 - Prob. 19.30QAPCh. 19 - The proton NMR spectrum in Figure 19.39 is for an...Ch. 19 - The proton NMR spectrum in Figure 19-40 is for a...Ch. 19 - Prob. 19.33QAPCh. 19 - Prob. 19.34QAPCh. 19 - Prob. 19.35QAPCh. 19 - From the proton NMR spectrum in Figure 19-44,...Ch. 19 - From the proton spectrum given in Figure 19-45,...Ch. 19 - Prob. 19.38QAPCh. 19 - Prob. 19.39QAPCh. 19 - Prob. 19.40QAPCh. 19 - Prob. 19.41QAPCh. 19 - Prob. 19.42QAP
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Similar questions
- The proton NMR spectrum in Figure 19-40 is for a compound having an empirical formula C4H7BrO2. Identify the compound.arrow_forwardFrom the proton spectrum given in Figure 19-45, determine the structure of this compound, a commc used painkiller; its empirical formula is C10H13NO2.arrow_forwardThe proton NMR spectrum in Figure 19.39 is for an organic compound containing a single atom of bromine. Identify the compound.arrow_forward
- The organic compound 1,4-dimethylbenzene (also known as p-xylene) has the formula (CH3)2C6H4. Its structure has two CH3 (methyl) groups substituted at opposite positions on the benzene (C6H6) ring. Predict the number of peaks in the low-resolution proton NMR spectrum of this compound and the relative areas of the peaks.arrow_forwardWe calculated that the resonance frequency of an 1H in the presence of an 11.74 tesla magnet was 500MHz, and we later saw that a 13C nucleus resonantes at approximately 125 MHz in this same magnetic field. What is the resonance frequency of a 19F nucleus in the presence of an 11.74 tesla magnet?arrow_forward(a) Calculate the energy difference between the two spin states of 1H and of 13C in a magnetic field of 6.8 T. 1H 4.0 1.91e-29 X J 13C 4.80e-33 X J (b) What is the precession frequency of a 'H nucleus at this magnetic field? Of a 13C nucleus? 1H 4.0 290 MHz 13C 4.0 73 MHz (c) At what magnetic field do protons precess at a frequency of 300. MHz? [4.0 7.04arrow_forward
- (a) Calculate the energy difference between the two spin states of 1H and of 13C in a magnetic field of 6.8 T. 1H 4.0 1.19e-25 X J 13C 4.0 J (b) What is the precession frequency of a 1H nucleus at this magnetic field? Of a 13C nucleus? 1H 4.0 290 MHz 13C 4.0 73 MHz (c) At what magnetic field do protons precess at a frequency of 300. MHz? 4.0 7.04 Tarrow_forwardWhich molecule matches this mass spectrumarrow_forwardWhat will be the 1H-NMR spectrum for the next molecule BrClCHCH2COCH3 and illustrate the corresponding signals according to their chemical displacement, multiplicity and integration. Indicate two basic differences that exist between the spectra of 1H y 13C in NMR. Establish the difference between the multiplicity of a signal and the integral (integration) of the signal in spectroscopy of 1H-NMR.arrow_forward
- The centre of the EPR spectrum of atomic hydrogen lies at 329.12 mT in a spectrometer operating at 9.2231 GHz. What is the g-value of the electron in this atom?arrow_forwardThe picture of the question is attachedarrow_forwardSketch the form of an A2M2X3 spectrum, where A, M, and X are protons with distinctivelydifferent chemical shifts, and JAM > JAX> JMX. What is the total number of lines in thespectrum?arrow_forward
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