Principles of Instrumental Analysis
7th Edition
ISBN: 9781305577213
Author: Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher: Cengage Learning
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Chapter 19, Problem 19.18QAP
Interpretation Introduction
Interpretation:
The 1H and 31P NMR spectra of methyl phosphorous acid P(OCH3)3 at 7.05 T should be compared.
Concept introduction:
The theory behind NMR is some nuclei can exist in specific nuclear states in the presence of external magnetic field. NMR detects the transition between these spin states. NMR applies to the nuclei whose spin is not equal to zero. Each nuclei absorbs only a specific frequency. So, NMR detect one type of isotope at a time. So NMR can be used to differentiate between elements which leads to different types of NMR, such as, 1H NMR, 13C NMR, and 31P NMR.
Spin-spin coupling is a phenomenon which is caused by the spin coupling between two chemically different nuclei which are NMR active. This effect is indicated through peak splitting in NMR spectra.
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Students have asked these similar questions
A certain compound was known to have a formula which could be represented as
[PdCxHyN₂ ](ClO4)2. Analysis showed that the compound contained 30.15% carbon,
5.06% hydrogen. When converted to the corresponding thiocyanate,
[PdC₂H₂N₂ ](SCN)₂, the analysis was 40.46% carbon and 5.94% hydrogen. Calculate
the value of x, y, and z.
A certain compound was known to have a formula which could be represented as
[PdCxHyN₂ ](ClO4)2. Analysis showed that the compound contained 30.15% carbon,
5.06% hydrogen. When converted to the corresponding thiocyanate,
[PdC₂H₂N₂ ](SCN)₂, the analysis was 40.46% carbon and 5.94% hydrogen. Calculate
the value of x, y, and z.
Ox=14, y = 28, z= 4
x = 28, y = 4, z= 14
Ox= 14, y = 4, z= 28
O x = 4, y = 14, z = 28
2. (a) Calculate the spin only magnetic moment of:
0=
V
O
SO₂
Chapter 19 Solutions
Principles of Instrumental Analysis
Ch. 19 - Prob. 19.1QAPCh. 19 - Prob. 19.2QAPCh. 19 - Prob. 19.3QAPCh. 19 - Prob. 19.4QAPCh. 19 - Prob. 19.5QAPCh. 19 - A nucleus has a spin quantum number of 7/2. How...Ch. 19 - Prob. 19.7QAPCh. 19 - Prob. 19.8QAPCh. 19 - Prob. 19.9QAPCh. 19 - Why is 133C-133C spin-spin splitting not observed...
Ch. 19 - Prob. 19.11QAPCh. 19 - Prob. 19.12QAPCh. 19 - Prob. 19.13QAPCh. 19 - What is a rotating frame of reference?Ch. 19 - How will E for an isolated 13C nucleus compare...Ch. 19 - Prob. 19.16QAPCh. 19 - Prob. 19.17QAPCh. 19 - Prob. 19.18QAPCh. 19 - Prob. 19.19QAPCh. 19 - Prob. 19.20QAPCh. 19 - Prob. 19.21QAPCh. 19 - Prob. 19.22QAPCh. 19 - Prob. 19.23QAPCh. 19 - Prob. 19.24QAPCh. 19 - Prob. 19.25QAPCh. 19 - Prob. 19.26QAPCh. 19 - Prob. 19.27QAPCh. 19 - Prob. 19.28QAPCh. 19 - Prob. 19.29QAPCh. 19 - Prob. 19.30QAPCh. 19 - The proton NMR spectrum in Figure 19.39 is for an...Ch. 19 - The proton NMR spectrum in Figure 19-40 is for a...Ch. 19 - Prob. 19.33QAPCh. 19 - Prob. 19.34QAPCh. 19 - Prob. 19.35QAPCh. 19 - From the proton NMR spectrum in Figure 19-44,...Ch. 19 - From the proton spectrum given in Figure 19-45,...Ch. 19 - Prob. 19.38QAPCh. 19 - Prob. 19.39QAPCh. 19 - Prob. 19.40QAPCh. 19 - Prob. 19.41QAPCh. 19 - Prob. 19.42QAP
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