(a) Interpretation: The functional groups of methylphenidate needs to be identified. Concept introduction: The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. Some of the functional groups are hydroxyl, methyl, carbonyl, carboxyl, amino, phosphate, and sulfhydryl.

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Answer 1

Question

Chapter 18, Problem 75P

Interpretation Introduction

(a)

Interpretation:

The functional groups of methylphenidate needs to be identified.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. Some of the functional groups are hydroxyl, methyl, carbonyl, carboxyl, amino, phosphate, and sulfhydryl.

Interpretation Introduction

(b)

Interpretation:

The given amine needs to be labelled as 1⁰, 2⁰ or 3⁰.

Concept introduction:

Amines are derivatives which are derived from ammonia, wherein one or more hydrogen atoms have been replaced by a substituent such as an alkyl or aryl group. They can be called as alkylamines and arylamines.

Interpretation Introduction

(c)

Interpretation:

The chiral centers of methylphenidate molecule needs to be labelled.

Concept Introduction:

The molecules with chiral center that can form superimposable mirror image and known as enantiomers. There should not be any plane of symmetry in a molecule to be chiral. A plane that bisects a molecule into two equal halves is known as a plane of symmetry. If there is a plane of symmetry in a molecule and it is identical to any of its mirror image, it is considered as achiral. The chiral center is carbon attached to 4 different groups attached to it.

Interpretation Introduction

(d)

Interpretation:

The 2-phenylethylamine needs to be located in methylphenidate molecule.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. The structure of 2-phenylethylamine is as follows:

Interpretation Introduction

(e)

Interpretation:

The structure of methylphenidatehydrochloride molecule needs to be drawn.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. Methylphenidatehydrochloride can be defined as the hydrochloride salt of methylphenidate.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?

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Answer 2

Question

Chapter 18, Problem 75P

Interpretation Introduction

(a)

Interpretation:

The functional groups of methylphenidate needs to be identified.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. Some of the functional groups are hydroxyl, methyl, carbonyl, carboxyl, amino, phosphate, and sulfhydryl.

Interpretation Introduction

(b)

Interpretation:

The given amine needs to be labelled as 1⁰, 2⁰ or 3⁰.

Concept introduction:

Amines are derivatives which are derived from ammonia, wherein one or more hydrogen atoms have been replaced by a substituent such as an alkyl or aryl group. They can be called as alkylamines and arylamines.

Interpretation Introduction

(c)

Interpretation:

The chiral centers of methylphenidate molecule needs to be labelled.

Concept Introduction:

The molecules with chiral center that can form superimposable mirror image and known as enantiomers. There should not be any plane of symmetry in a molecule to be chiral. A plane that bisects a molecule into two equal halves is known as a plane of symmetry. If there is a plane of symmetry in a molecule and it is identical to any of its mirror image, it is considered as achiral. The chiral center is carbon attached to 4 different groups attached to it.

Interpretation Introduction

(d)

Interpretation:

The 2-phenylethylamine needs to be located in methylphenidate molecule.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. The structure of 2-phenylethylamine is as follows:

Interpretation Introduction

(e)

Interpretation:

The structure of methylphenidatehydrochloride molecule needs to be drawn.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. Methylphenidatehydrochloride can be defined as the hydrochloride salt of methylphenidate.

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Answer 3

Question

Chapter 18, Problem 75P

Interpretation Introduction

(a)

Interpretation:

The functional groups of methylphenidate needs to be identified.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. Some of the functional groups are hydroxyl, methyl, carbonyl, carboxyl, amino, phosphate, and sulfhydryl.

Interpretation Introduction

(b)

Interpretation:

The given amine needs to be labelled as 1⁰, 2⁰ or 3⁰.

Concept introduction:

Amines are derivatives which are derived from ammonia, wherein one or more hydrogen atoms have been replaced by a substituent such as an alkyl or aryl group. They can be called as alkylamines and arylamines.

Interpretation Introduction

(c)

Interpretation:

The chiral centers of methylphenidate molecule needs to be labelled.

Concept Introduction:

The molecules with chiral center that can form superimposable mirror image and known as enantiomers. There should not be any plane of symmetry in a molecule to be chiral. A plane that bisects a molecule into two equal halves is known as a plane of symmetry. If there is a plane of symmetry in a molecule and it is identical to any of its mirror image, it is considered as achiral. The chiral center is carbon attached to 4 different groups attached to it.

Interpretation Introduction

(d)

Interpretation:

The 2-phenylethylamine needs to be located in methylphenidate molecule.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. The structure of 2-phenylethylamine is as follows:

Interpretation Introduction

(e)

Interpretation:

The structure of methylphenidatehydrochloride molecule needs to be drawn.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. Methylphenidatehydrochloride can be defined as the hydrochloride salt of methylphenidate.

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Answer 4

Question

Chapter 18, Problem 75P

Interpretation Introduction

(a)

Interpretation:

The functional groups of methylphenidate needs to be identified.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. Some of the functional groups are hydroxyl, methyl, carbonyl, carboxyl, amino, phosphate, and sulfhydryl.

Interpretation Introduction

(b)

Interpretation:

The given amine needs to be labelled as 1⁰, 2⁰ or 3⁰.

Concept introduction:

Amines are derivatives which are derived from ammonia, wherein one or more hydrogen atoms have been replaced by a substituent such as an alkyl or aryl group. They can be called as alkylamines and arylamines.

Interpretation Introduction

(c)

Interpretation:

The chiral centers of methylphenidate molecule needs to be labelled.

Concept Introduction:

The molecules with chiral center that can form superimposable mirror image and known as enantiomers. There should not be any plane of symmetry in a molecule to be chiral. A plane that bisects a molecule into two equal halves is known as a plane of symmetry. If there is a plane of symmetry in a molecule and it is identical to any of its mirror image, it is considered as achiral. The chiral center is carbon attached to 4 different groups attached to it.

Interpretation Introduction

(d)

Interpretation:

The 2-phenylethylamine needs to be located in methylphenidate molecule.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. The structure of 2-phenylethylamine is as follows:

Interpretation Introduction

(e)

Interpretation:

The structure of methylphenidatehydrochloride molecule needs to be drawn.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. Methylphenidatehydrochloride can be defined as the hydrochloride salt of methylphenidate.

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Answer 5

Chapter 18, Problem 75P

Interpretation Introduction

(a)

Interpretation:

The functional groups of methylphenidate needs to be identified.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. Some of the functional groups are hydroxyl, methyl, carbonyl, carboxyl, amino, phosphate, and sulfhydryl.

Interpretation Introduction

(b)

Interpretation:

The given amine needs to be labelled as 1⁰, 2⁰ or 3⁰.

Concept introduction:

Amines are derivatives which are derived from ammonia, wherein one or more hydrogen atoms have been replaced by a substituent such as an alkyl or aryl group. They can be called as alkylamines and arylamines.

Interpretation Introduction

(c)

Interpretation:

The chiral centers of methylphenidate molecule needs to be labelled.

Concept Introduction:

The molecules with chiral center that can form superimposable mirror image and known as enantiomers. There should not be any plane of symmetry in a molecule to be chiral. A plane that bisects a molecule into two equal halves is known as a plane of symmetry. If there is a plane of symmetry in a molecule and it is identical to any of its mirror image, it is considered as achiral. The chiral center is carbon attached to 4 different groups attached to it.

Interpretation Introduction

(d)

Interpretation:

The 2-phenylethylamine needs to be located in methylphenidate molecule.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. The structure of 2-phenylethylamine is as follows:

Interpretation Introduction

(e)

Interpretation:

The structure of methylphenidatehydrochloride molecule needs to be drawn.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. Methylphenidatehydrochloride can be defined as the hydrochloride salt of methylphenidate.

Answer 6

Chapter 18, Problem 75P

Interpretation Introduction

(a)

Interpretation:

The functional groups of methylphenidate needs to be identified.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. Some of the functional groups are hydroxyl, methyl, carbonyl, carboxyl, amino, phosphate, and sulfhydryl.

Answer 7

Chapter 18, Problem 75P

Interpretation Introduction

(a)

Interpretation:

The functional groups of methylphenidate needs to be identified.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. Some of the functional groups are hydroxyl, methyl, carbonyl, carboxyl, amino, phosphate, and sulfhydryl.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The given amine needs to be labelled as 1⁰, 2⁰ or 3⁰.

Concept introduction:

Amines are derivatives which are derived from ammonia, wherein one or more hydrogen atoms have been replaced by a substituent such as an alkyl or aryl group. They can be called as alkylamines and arylamines.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The given amine needs to be labelled as 1⁰, 2⁰ or 3⁰.

Concept introduction:

Amines are derivatives which are derived from ammonia, wherein one or more hydrogen atoms have been replaced by a substituent such as an alkyl or aryl group. They can be called as alkylamines and arylamines.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The chiral centers of methylphenidate molecule needs to be labelled.

Concept Introduction:

The molecules with chiral center that can form superimposable mirror image and known as enantiomers. There should not be any plane of symmetry in a molecule to be chiral. A plane that bisects a molecule into two equal halves is known as a plane of symmetry. If there is a plane of symmetry in a molecule and it is identical to any of its mirror image, it is considered as achiral. The chiral center is carbon attached to 4 different groups attached to it.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The chiral centers of methylphenidate molecule needs to be labelled.

Concept Introduction:

The molecules with chiral center that can form superimposable mirror image and known as enantiomers. There should not be any plane of symmetry in a molecule to be chiral. A plane that bisects a molecule into two equal halves is known as a plane of symmetry. If there is a plane of symmetry in a molecule and it is identical to any of its mirror image, it is considered as achiral. The chiral center is carbon attached to 4 different groups attached to it.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The 2-phenylethylamine needs to be located in methylphenidate molecule.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. The structure of 2-phenylethylamine is as follows:

Answer 13

Interpretation Introduction

(d)

Interpretation:

The 2-phenylethylamine needs to be located in methylphenidate molecule.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. The structure of 2-phenylethylamine is as follows:

Answer 14

Interpretation Introduction

(e)

Interpretation:

The structure of methylphenidatehydrochloride molecule needs to be drawn.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. Methylphenidatehydrochloride can be defined as the hydrochloride salt of methylphenidate.

Answer 15

Interpretation Introduction

(e)

Interpretation:

The structure of methylphenidatehydrochloride molecule needs to be drawn.

Concept introduction:

The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. Methylphenidatehydrochloride can be defined as the hydrochloride salt of methylphenidate.

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 18.1 - Prob. 18.1PP Ch. 18.1 - Prob. 18.1P Ch. 18.1 - Prob. 18.2P Ch. 18.1 - Prob. 18.3P Ch. 18.2 - Prob. 18.2PP Ch. 18.2 - Prob. 18.4P Ch. 18.2 - Prob. 18.5P Ch. 18.3 - Prob. 18.3PP Ch. 18.4 - Decaffeinated coffee is produced by extracting the...Ch. 18.4 - Prob. 18.7P

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Chapter 18 Solutions

Concept explainers

(d) Interpretation: The 2-phenylethylamine needs to be located in methylphenidate molecule. Concept introduction: The functional groups are attached to carbon skeleton in any organic molecule which determines the properties of the organic molecule. The structure of 2-phenylethylamine is as follows:

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Chapter 18 Solutions