Glucose is the major fuel for most living cells. The oxidative breakdown of glucose by our body to produce energy is called respiration. The reaction for the complete combustion of glucose is C 6 H 12 O 6 ( s ) + 6O 2 ( g ) → 6 CO 2 ( g ) + 6 H 2 O ( l ) If this combustion reaction could be harnessed as a fuel cell, calculate the theoretical voltage that could be produced at standard conditions. ( Hint: Use Δ G f ∘ values from Appendix 4.)
Glucose is the major fuel for most living cells. The oxidative breakdown of glucose by our body to produce energy is called respiration. The reaction for the complete combustion of glucose is C 6 H 12 O 6 ( s ) + 6O 2 ( g ) → 6 CO 2 ( g ) + 6 H 2 O ( l ) If this combustion reaction could be harnessed as a fuel cell, calculate the theoretical voltage that could be produced at standard conditions. ( Hint: Use Δ G f ∘ values from Appendix 4.)
Glucose is the major fuel for most living cells. The oxidative breakdown of glucose by our body to produce energy is called respiration. The reaction for the complete combustion of glucose is
C
6
H
12
O
6
(
s
)
+
6O
2
(
g
)
→
6
CO
2
(
g
)
+
6
H
2
O
(
l
)
If this combustion reaction could be harnessed as a fuel cell, calculate the theoretical voltage that could be produced at standard conditions. (Hint: Use
Δ
G
f
∘
values from Appendix 4.)
Predict the major organic product(s) of the following reactions. Indicate which of the following mechanisms is in operation: SN1, SN2, E1, or E2.
(c)
(4pts)
Mechanism:
heat
(E1)
CH3OH
+
1.5pts each
_E1 _ (1pt)
Br
CH3OH
(d)
(4pts)
Mechanism:
SN1
(1pt)
(e)
(3pts)
1111 I
H
10
Ill!!
H
LDA
THF (solvent)
Mechanism: E2
(1pt)
NC
(f)
Bri!!!!!
CH3
NaCN
(3pts)
acetone
Mechanism: SN2
(1pt)
(SN1)
-OCH3
OCH3
1.5pts each
2pts for either product
1pt if incorrect
stereochemistry
H
Br
(g)
“,、
(3pts)
H
CH3OH
+21
Mechanism:
SN2
(1pt)
H
CH3
2pts
1pt if incorrect
stereochemistry
H
2pts
1pt if incorrect
stereochemistry
A mixture of butyl acrylate and 4'-chloropropiophenone has been taken for proton NMR analysis. Based on this proton NMR, determine the relative percentage of each compound in the mixture
Chapter 17 Solutions
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