General, Organic, & Biological Chemistry
General, Organic, & Biological Chemistry
3rd Edition
ISBN: 9780073511245
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Chapter 17, Problem 17.74P
Interpretation Introduction

(a)

Interpretation:

The carboxylic acid and alcohol required to form (CH3)3CCO2CH3 ester by Fischer esterification needs to be determined.

Concept Introduction:

When carboxylic acid (RCOOH) is treated with an alcohol (R'OH) in an acidic medium, an ester (RCOOR') formation can be observed. This process is known as the Fischer esterification.

In this esterification process, the OR' group of an alcohol replaces the OH group of the starting carboxylic acid.

General reaction is represented as follows:

General, Organic, & Biological Chemistry, Chapter 17, Problem 17.74P , additional homework tip  1

Interpretation Introduction

(b)

Interpretation:

The carboxylic acid and alcoholneeded to synthesize the given ester by Fischer esterification needs to be determined.

General, Organic, & Biological Chemistry, Chapter 17, Problem 17.74P , additional homework tip  2

Concept Introduction:

When carboxylic acid (RCOOH) is treated with an alcohol (R'OH) in an acidic medium, an ester (RCOOR') formation can be observed. This process is known as the Fischer esterification.

In this esterification process, the OR' group of an alcohol replaces the OH group of the starting carboxylic acid.

General reaction is represented as follows:

General, Organic, & Biological Chemistry, Chapter 17, Problem 17.74P , additional homework tip  3

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Questions 4 and 5
For a titration of 40.00 mL of 0.0500 M oxalic acid H2C2O4 with 0.1000 M KOH, calculate the pH at each of the following volume of KOH used in the titration: 1) before the titration begin;2) 15 mL; 3) 20 mL; 4) 25 mL; 5) 40 mL; 6) 50 mL. Ka1 = 5.90×10^-2, Ka2 = 6.50×10^-5 for oxalic acid.
Predict the major organic product(s), if any, of the following reactions.  Assume all reagents are in excess unless otherwise indicated.

Chapter 17 Solutions

General, Organic, & Biological Chemistry

Ch. 17.2 - Prob. 17.11PCh. 17.3 - Which compound in each pair has the higher boiling...Ch. 17.4 - Prob. 17.13PCh. 17.5 - In addition to ethyl butanoate (Section 17.5),...Ch. 17.6 - Prob. 17.15PCh. 17.6 - Prob. 17.16PCh. 17.6 - Prob. 17.17PCh. 17.6 - Prob. 17.18PCh. 17.6 - Prob. 17.19PCh. 17.7 - Prob. 17.20PCh. 17.7 - Ibuprofen is another pain reliever that is a...Ch. 17.8 - Prob. 17.22PCh. 17.8 - Prob. 17.23PCh. 17.8 - Prob. 17.24PCh. 17.8 - Prob. 17.25PCh. 17.8 - Prob. 17.26PCh. 17.9 - Prob. 17.27PCh. 17.9 - Prob. 17.28PCh. 17.9 - Prob. 17.29PCh. 17.9 - Prob. 17.30PCh. 17.9 - Prob. 17.31PCh. 17.9 - Prob. 17.32PCh. 17.10 - Prob. 17.33PCh. 17.10 - Prob. 17.34PCh. 17.10 - Prob. 17.35PCh. 17.11 - Prob. 17.36PCh. 17 - Prob. 17.37PCh. 17 - Prob. 17.38PCh. 17 - Prob. 17.39PCh. 17 - Prob. 17.40PCh. 17 - Prob. 17.41PCh. 17 - Prob. 17.42PCh. 17 - Prob. 17.43PCh. 17 - Prob. 17.44PCh. 17 - Prob. 17.45PCh. 17 - Prob. 17.46PCh. 17 - Prob. 17.47PCh. 17 - Give an acceptable name for each ester. a. CH3CO2(...Ch. 17 - Prob. 17.49PCh. 17 - Prob. 17.50PCh. 17 - Prob. 17.51PCh. 17 - Give an acceptable name for each compound. a. b....Ch. 17 - Prob. 17.53PCh. 17 - Draw the structure corresponding to each name. a....Ch. 17 - Draw the structure corresponding to each name. a....Ch. 17 - Draw the structure corresponding to each name. a....Ch. 17 - Prob. 17.57PCh. 17 - Prob. 17.58PCh. 17 - Prob. 17.59PCh. 17 - Prob. 17.60PCh. 17 - Prob. 17.61PCh. 17 - Prob. 17.62PCh. 17 - Prob. 17.63PCh. 17 - Prob. 17.64PCh. 17 - Prob. 17.65PCh. 17 - Prob. 17.66PCh. 17 - What ester is formed when butanoic acid...Ch. 17 - Prob. 17.68PCh. 17 - Prob. 17.69PCh. 17 - Prob. 17.70PCh. 17 - Prob. 17.71PCh. 17 - Prob. 17.72PCh. 17 - Prob. 17.73PCh. 17 - Prob. 17.74PCh. 17 - Prob. 17.75PCh. 17 - Prob. 17.76PCh. 17 - Prob. 17.77PCh. 17 - Prob. 17.78PCh. 17 - Prob. 17.79PCh. 17 - Prob. 17.80PCh. 17 - Prob. 17.81PCh. 17 - Prob. 17.82PCh. 17 - Prob. 17.83PCh. 17 - Prob. 17.84PCh. 17 - Prob. 17.85PCh. 17 - Prob. 17.86PCh. 17 - What is the difference between saponification and...Ch. 17 - You have now learned three different types of...Ch. 17 - Draw the products formed in each reaction. Ch. 17 - Prob. 17.90PCh. 17 - Answer the following questions about A, depicted...Ch. 17 - Answer the following questions about B, depicted...Ch. 17 - Prob. 17.93PCh. 17 - Prob. 17.94PCh. 17 - Prob. 17.95PCh. 17 - Prob. 17.96PCh. 17 - Prob. 17.97PCh. 17 - Prob. 17.98PCh. 17 - Prob. 17.99PCh. 17 - Prob. 17.100PCh. 17 - Prob. 17.101PCh. 17 - Prob. 17.102PCh. 17 - Prob. 17.103CPCh. 17 - Lactams can be hydrolyzed with base, just like...
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