The given set of compounds has to be arranged in the increasing order of boing point. Concept introduction: The boiling points of carboxylic acids are higher than those of alcohol or aldehydes of similar relative molecular mass due to intermolecular hydrogen bonding. Intermolecular hydrogen bonding will increase the boiling point of an organic compound. Carboxylic acids can form dimers in which hydrogen bonds form between two carboxyl groups this will also increase their boiling point. Increasing order of boiling point of some organic compounds with similar molecular weight is shown below, Alkane < Ether < Alkyl halide < Amine < Ketone , aldehyde < Alcohol < Carboxylic acid The better hydrogen bond capability of a molecule will increase its boiling points.

Question

Which of the following pure compounds can form hydrogen bonds? Which can form hydrogen bonds with water? Which ones do you expect to be soluble in water?(a) (CH3CH2)2NH (b) (CH3CH2)3N (c) CH3CH2CH2OH

Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 17, Problem 17.15P

(a)

Interpretation Introduction

Interpretation:

The given set of compounds has to be arranged in the increasing order of boing point.

Concept introduction:

The boiling points of carboxylic acids are higher than those of alcohol or aldehydes of similar relative molecular mass due to intermolecular hydrogen bonding.

Intermolecular hydrogen bonding will increase the boiling point of an organic compound.

Carboxylic acids can form dimers in which hydrogen bonds form between two carboxyl groups this will also increase their boiling point.

Increasing order of boiling point of some organic compounds with similar molecular weight is shown below,

Alkane < Ether < Alkyl halide < Amine < Ketone , aldehyde < Alcohol < Carboxylic acid

The better hydrogen bond capability of a molecule will increase its boiling points.

(b)

Interpretation Introduction

Interpretation:

The given set of compounds has to be arranged in the increasing order of boing point.

Concept introduction:

The boiling points of carboxylic acids are higher than those of alcohol or aldehydes of similar relative molecular mass due to intermolecular hydrogen bonding.

Carboxylic acids can form dimers in which hydrogen bonds form between two carboxyl groups this will also increase their boiling point.

Intermolecular hydrogen bonding will increase the boiling point of an organic compound.

Increasing order of boiling point of some organic compounds with similar molecular weight is shown below,

Alkane < Ether < Alkyl halide < Amine < Ketone , aldehyde < Alcohol < Carboxylic acid

The better hydrogen bond capability of a molecule will increase its boiling points.

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Which of the following pure compounds can form hydrogen bonds? Which can form hydrogen bonds with water? Which ones do you expect to be soluble in water?(a) (CH3CH2)2NH (b) (CH3CH2)3N (c) CH3CH2CH2OH

What is the IUPAC name for the following compound? CH₂CH₂OH CH3CH₂C=CCH₂CH3 CH3 (A) 3-methyl-4-ethyl-3-hexen-6-ol B 4-ethyl-3-methyl-3,6-hexenol 3-ethyl-4-methyl-3-hexen-1-ol 3-methyl-4-(2-hydroxyethyl)-3-hexene E 3-(2-hydroxyethyl)-3-methyl-3-hexene

Arrange these compounds in order of increasing boiling point. Use the boiling point values of 0°C, 35°C, and 97°C. (a) CH3CH2CH2OH (b) CH3CH2OCH2CH3 (c) CH3CH2CH2CH3

Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 17, Problem 17.15P

(a)

Interpretation Introduction

Interpretation:

The given set of compounds has to be arranged in the increasing order of boing point.

Concept introduction:

The boiling points of carboxylic acids are higher than those of alcohol or aldehydes of similar relative molecular mass due to intermolecular hydrogen bonding.

Intermolecular hydrogen bonding will increase the boiling point of an organic compound.

Carboxylic acids can form dimers in which hydrogen bonds form between two carboxyl groups this will also increase their boiling point.

Increasing order of boiling point of some organic compounds with similar molecular weight is shown below,

Alkane < Ether < Alkyl halide < Amine < Ketone , aldehyde < Alcohol < Carboxylic acid

The better hydrogen bond capability of a molecule will increase its boiling points.

(b)

Interpretation Introduction

Interpretation:

The given set of compounds has to be arranged in the increasing order of boing point.

Concept introduction:

The boiling points of carboxylic acids are higher than those of alcohol or aldehydes of similar relative molecular mass due to intermolecular hydrogen bonding.

Carboxylic acids can form dimers in which hydrogen bonds form between two carboxyl groups this will also increase their boiling point.

Intermolecular hydrogen bonding will increase the boiling point of an organic compound.

Increasing order of boiling point of some organic compounds with similar molecular weight is shown below,

Alkane < Ether < Alkyl halide < Amine < Ketone , aldehyde < Alcohol < Carboxylic acid

The better hydrogen bond capability of a molecule will increase its boiling points.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 17, Problem 17.15P

(a)

Interpretation Introduction

Interpretation:

The given set of compounds has to be arranged in the increasing order of boing point.

Concept introduction:

The boiling points of carboxylic acids are higher than those of alcohol or aldehydes of similar relative molecular mass due to intermolecular hydrogen bonding.

Intermolecular hydrogen bonding will increase the boiling point of an organic compound.

Carboxylic acids can form dimers in which hydrogen bonds form between two carboxyl groups this will also increase their boiling point.

Increasing order of boiling point of some organic compounds with similar molecular weight is shown below,

Alkane < Ether < Alkyl halide < Amine < Ketone , aldehyde < Alcohol < Carboxylic acid

The better hydrogen bond capability of a molecule will increase its boiling points.

(b)

Interpretation Introduction

Interpretation:

The given set of compounds has to be arranged in the increasing order of boing point.

Concept introduction:

The boiling points of carboxylic acids are higher than those of alcohol or aldehydes of similar relative molecular mass due to intermolecular hydrogen bonding.

Carboxylic acids can form dimers in which hydrogen bonds form between two carboxyl groups this will also increase their boiling point.

Intermolecular hydrogen bonding will increase the boiling point of an organic compound.

Increasing order of boiling point of some organic compounds with similar molecular weight is shown below,

Alkane < Ether < Alkyl halide < Amine < Ketone , aldehyde < Alcohol < Carboxylic acid

The better hydrogen bond capability of a molecule will increase its boiling points.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 17, Problem 17.15P

(a)

Interpretation Introduction