EBK FUNDAMENTALS OF GENERAL, ORGANIC, A
EBK FUNDAMENTALS OF GENERAL, ORGANIC, A
8th Edition
ISBN: 8220102895805
Author: Peterson
Publisher: PEARSON
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Chapter 16.2, Problem 16.3P

(a)

Interpretation Introduction

Interpretation: The structure of the given amine has to be determined.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amines are the derivatives of ammonia (NH3) with one or more of the hydrogens replaced with a substituent such as an alkyl group.

Depending on the number of carbon side chain of the nitrogen, different types of amines can form.

EBK FUNDAMENTALS OF GENERAL, ORGANIC, A, Chapter 16.2, Problem 16.3P , additional homework tip  1

From the name of the compound its structure can be determined.

Primary amines can be named in the IUPAC system in several ways,

For simple amines the suffix – amine is added to the name of the alkyl substituent.

The suffix-amine can be used in place of the final –e in the name of the parent compound.

For a secondary amine an N prefixes the compound giving the shorter carbon chain and its chain prefix name.

For a tertiary amine an N, N prefixes the compound giving the two shorter carbon chains and their side chain prefix names.

(b)

Interpretation Introduction

Interpretation: The structure of the given amine has to be determined.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amines are the derivatives of ammonia (NH3) with one or more of the hydrogens replaced with a substituent such as an alkyl group.

Depending on the number of carbon side chain of the nitrogen, different types of amines can form.

EBK FUNDAMENTALS OF GENERAL, ORGANIC, A, Chapter 16.2, Problem 16.3P , additional homework tip  2

From the name of the compound its structure can be determined.

Primary amines can be named in the IUPAC system in several ways,

For simple amines the suffix – amine is added to the name of the alkyl substituent.

The suffix-amine can be used in place of the final –e in the name of the parent compound.

For a secondary amine an N prefixes the compound giving the shorter carbon chain and its chain prefix name.

For a tertiary amine an N, N prefixes the compound giving the two shorter carbon chains and their side chain prefix names.

(c)

Interpretation Introduction

Interpretation: The structure of the given amine has to be determined.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amines are the derivatives of ammonia (NH3) with one or more of the hydrogens replaced with a substituent such as an alkyl group.

Depending on the number of carbon side chain of the nitrogen, different types of amines can form.

EBK FUNDAMENTALS OF GENERAL, ORGANIC, A, Chapter 16.2, Problem 16.3P , additional homework tip  3

From the name of the compound its structure can be determined.

Primary amines can be named in the IUPAC system in several ways,

For simple amines the suffix – amine is added to the name of the alkyl substituent.

The suffix-amine can be used in place of the final –e in the name of the parent compound.

For a secondary amine an N prefixes the compound giving the shorter carbon chain and its chain prefix name.

For a tertiary amine an N, N prefixes the compound giving the two shorter carbon chains and their side chain prefix names.

Aniline is an aromatic amine compound and its structure is,

EBK FUNDAMENTALS OF GENERAL, ORGANIC, A, Chapter 16.2, Problem 16.3P , additional homework tip  4

(d)

Interpretation Introduction

Interpretation: The structure of the given amine has to be determined.

Concept introduction:

In chemistry Structure is the arrangement of chemical bonds between atoms in a molecule, specifically which atoms are chemically bonded to what other atoms with what kind of chemical bond.

Amines are the derivatives of ammonia (NH3) with one or more of the hydrogens replaced with a substituent such as an alkyl group.

Depending on the number of carbon side chain of the nitrogen, different types of amines can form.

EBK FUNDAMENTALS OF GENERAL, ORGANIC, A, Chapter 16.2, Problem 16.3P , additional homework tip  5

From the name of the compound its structure can be determined.

Primary amines can be named in the IUPAC system in several ways,

For simple amines the suffix – amine is added to the name of the alkyl substituent.

The suffix-amine can be used in place of the final –e in the name of the parent compound.

For a secondary amine an N prefixes the compound giving the shorter carbon chain and its chain prefix name.

For a tertiary amine an N, N prefixes the compound giving the two shorter carbon chains and their side chain prefix names.

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Chapter 16 Solutions

EBK FUNDAMENTALS OF GENERAL, ORGANIC, A

Ch. 16.4 - Prob. 16.11PCh. 16.5 - Write an equation for the acid-base equilibrium...Ch. 16.5 - Prob. 16.13PCh. 16.5 - Prob. 16.14PCh. 16.5 - Prob. 16.15PCh. 16.5 - Prob. 16.16PCh. 16.6 - Prob. 16.17PCh. 16.6 - Prob. 16.18PCh. 16.6 - Prob. 16.19PCh. 16.6 - Prob. 16.20PCh. 16.6 - Prob. 16.21PCh. 16.6 - Prob. 16.22PCh. 16.7 - Prob. 16.1CIAPCh. 16.7 - Prob. 16.2CIAPCh. 16.7 - Prob. 16.3CIAPCh. 16 - (a) For the compound above, identify each nitrogen...Ch. 16 - The structure of the amino acid lysine (in its...Ch. 16 - Prob. 16.25UKCCh. 16 - Prob. 16.26UKCCh. 16 - Prob. 16.27UKCCh. 16 - Complete the following equations: (a) (b)...Ch. 16 - Prob. 16.29APCh. 16 - Draw the structures corresponding to the following...Ch. 16 - Name the following amines, and classify them as...Ch. 16 - Name the following amines, and identify them as...Ch. 16 - Prob. 16.33APCh. 16 - Which is a stronger base, diethyl ether or...Ch. 16 - Prob. 16.35APCh. 16 - Prob. 16.36APCh. 16 - The compound lidocaine is used medically as a...Ch. 16 - Prob. 16.38APCh. 16 - Draw the structures of the ammonium ions formed...Ch. 16 - Prob. 16.40APCh. 16 - Prob. 16.41APCh. 16 - Prob. 16.42APCh. 16 - Prob. 16.43APCh. 16 - Prob. 16.44APCh. 16 - Prob. 16.45CPCh. 16 - Prob. 16.46CPCh. 16 - Prob. 16.47CPCh. 16 - Prob. 16.48CPCh. 16 - How do amines differ from analogous alcohols in...Ch. 16 - Name at least two undesirable characteristics are...Ch. 16 - Prob. 16.52CPCh. 16 - Complete the following equations (Hint: Answers...Ch. 16 - Prob. 16.54CPCh. 16 - Prob. 16.55CPCh. 16 - Why is cyclohexylamine not considered to be a...Ch. 16 - Prob. 16.57CPCh. 16 - Prob. 16.58GPCh. 16 - 1-Propylamine, 1-propanol, acetic acid, and butane...Ch. 16 - Prob. 16.60GPCh. 16 - Lemon juice, which contains citric acid, is...
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