EBK FUNDAMENTALS OF GENERAL, ORGANIC, A
8th Edition
ISBN: 8220102895805
Author: Peterson
Publisher: PEARSON
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Chapter 16, Problem 16.57CP
Interpretation Introduction
Interpretation:
Reason for the difference in the miscibility of benzene and pyridine in water (benzene is immiscible in water and pyridine is miscible in water) should be explained.
Concept introduction:
The
Hydrogen bonding in amine is weaker than that of alcohols or
Hydrogen bond is an attractive force established between hydrogen atom attached to a highly electronegative element and another highly electronegative element of the same or different molecule.
Intermolecular hydrogen bonding:
When hydrogen bonding takes place between various molecules of the same or different compounds, it is called intermolecular hydrogen bonding.
Molecules which have this type of hydrogen bonding possess high solubility.
Intramolecular hydrogen bonding:
When hydrogen bonding occurs within the same molecule is termed as intramolecular hydrogen bonding.
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p=-59 degrees; y = +150 degrees; many Ser residues
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qp = +60 degrees; w = +60 degrees; many Gly residues
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Chapter 16 Solutions
EBK FUNDAMENTALS OF GENERAL, ORGANIC, A
Ch. 16.2 - Identify the following compounds as primary,...Ch. 16.2 - Prob. 16.2PCh. 16.2 - Prob. 16.3PCh. 16.2 - Prob. 16.4PCh. 16.2 - Prob. 16.5KCPCh. 16.2 - Prob. 16.6KCPCh. 16.3 - Arrange the following compounds in order of...Ch. 16.3 - Draw the structures of (a) ethylamine and (b)...Ch. 16.4 - Provide compounds that fit the following...Ch. 16.4 - Prob. 16.10P
Ch. 16.4 - Prob. 16.11PCh. 16.5 - Write an equation for the acid-base equilibrium...Ch. 16.5 - Prob. 16.13PCh. 16.5 - Prob. 16.14PCh. 16.5 - Prob. 16.15PCh. 16.5 - Prob. 16.16PCh. 16.6 - Prob. 16.17PCh. 16.6 - Prob. 16.18PCh. 16.6 - Prob. 16.19PCh. 16.6 - Prob. 16.20PCh. 16.6 - Prob. 16.21PCh. 16.6 - Prob. 16.22PCh. 16.7 - Prob. 16.1CIAPCh. 16.7 - Prob. 16.2CIAPCh. 16.7 - Prob. 16.3CIAPCh. 16 - (a) For the compound above, identify each nitrogen...Ch. 16 - The structure of the amino acid lysine (in its...Ch. 16 - Prob. 16.25UKCCh. 16 - Prob. 16.26UKCCh. 16 - Prob. 16.27UKCCh. 16 - Complete the following equations: (a) (b)...Ch. 16 - Prob. 16.29APCh. 16 - Draw the structures corresponding to the following...Ch. 16 - Name the following amines, and classify them as...Ch. 16 - Name the following amines, and identify them as...Ch. 16 - Prob. 16.33APCh. 16 - Which is a stronger base, diethyl ether or...Ch. 16 - Prob. 16.35APCh. 16 - Prob. 16.36APCh. 16 - The compound lidocaine is used medically as a...Ch. 16 - Prob. 16.38APCh. 16 - Draw the structures of the ammonium ions formed...Ch. 16 - Prob. 16.40APCh. 16 - Prob. 16.41APCh. 16 - Prob. 16.42APCh. 16 - Prob. 16.43APCh. 16 - Prob. 16.44APCh. 16 - Prob. 16.45CPCh. 16 - Prob. 16.46CPCh. 16 - Prob. 16.47CPCh. 16 - Prob. 16.48CPCh. 16 - How do amines differ from analogous alcohols in...Ch. 16 - Name at least two undesirable characteristics are...Ch. 16 - Prob. 16.52CPCh. 16 - Complete the following equations (Hint: Answers...Ch. 16 - Prob. 16.54CPCh. 16 - Prob. 16.55CPCh. 16 - Why is cyclohexylamine not considered to be a...Ch. 16 - Prob. 16.57CPCh. 16 - Prob. 16.58GPCh. 16 - 1-Propylamine, 1-propanol, acetic acid, and butane...Ch. 16 - Prob. 16.60GPCh. 16 - Lemon juice, which contains citric acid, is...
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