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(a)
Interpretation:
The given reaction equation should be completed.
Concept introduction:
Depending on the number of carbon side chain of the nitrogen, different types of amines can form.
Reaction of amines and acid will give amine salt an (ammonium ion).
(b)
Interpretation:
The given reaction equation should be completed.
Concept introduction:
Amines are the derivatives of ammonia
Depending on the number of carbon side chain of the nitrogen, different types of amines can form.
Reaction of amines and acid will give amine salt an (ammonium ion).
Treating an amine salt with a strong base regenerates the “parent” amine.
(c)
Interpretation:
The given reaction equation should be completed.
Concept introduction:
Amines are the derivatives of ammonia
Depending on the number of carbon side chain of the nitrogen, different types of amines can form.
Reaction of amines and acid will give amine salt an (ammonium ion).
Amine are weak bases (proton
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Chapter 16 Solutions
EBK FUNDAMENTALS OF GENERAL, ORGANIC, A
- 13. What is the IUPAC name of this compound? A) 5-hydroxy-3,3-dimethylpentanoic acid B) 3,3-dimethylpentanoic acid C) 3,3-dimethyl-1-oxo-1,5-pentanediol D) 1,5-dihydroxy-3,3-dimethylpentanal E) 4-hydroxy-2,2-dimethylbutanoic acid HO OHarrow_forwardHelp me understand how carbon disulfide leads to toxicity in the brain, using terms like distal axonopathy, neurofilaments, covalent cross-linking, adducts, etc.,...please intuitively explain what is happening and where and the effects of it. For example, I know that CS2 reacts with amide and sulfhydryl groups on proteins, but what proteins exactly and where are they located?arrow_forwardWhat is the standard free energy change (in kJ/mole) of the spontaneous reaction between Oxygen and NADH to form H2O2 and NAD+?arrow_forward
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- A transporter is responsible for antiporting calcium and glucose. The transporter brings glucose into the cell and sends calcium out of the cell. If blood [calcium] = 2.55mM and intracellular [calcium] = 7uM, blood [glucose] = 5.2mM, and intracellular [glucose] = 40uM, what is the free energy of transport? Assume a membrane potential of 62mV (negative inside).arrow_forwardAn ATP-coupled transporter is used to import 1 phosphate from the extracellular environment. Intracellular phosphate exists at 65mM, while it is 2mM outside.Assume a free energy change of ATP hydrolysis of -42.7 kJ/mol. What is the net free energy change of the coupled reaction? Assume a membrane potential of 70mV.arrow_forwardAnother transporter brings 3 chloride ions into the cell. Outside, chloride has a concentration of 107mM, and 4mM inside the cell. Assuming a membrane potential of 62mV (negative inside), what is the free energy of transport of these ions?arrow_forward
- For the Oxaloacetate -> Malate reaction, assume the normal ratio of NAD/NADH, what is the maximum ratio of Malate/Oxaloacetate that will allow reaction progress?arrow_forwardA particular particle is trying to cross a membrane by simple diffusion from a high concentration of 20mM to a low concentration of 20uM. If a membrane is 15uM in width, and the diffusion coefficient of the particle is 5 uM/sec, what is the influx in uM/sec?arrow_forwardMechanisms: 1. Give a full arrow-pushing mechanism for the hydrolysis of the gamma phosphate of ATP by an ATPase. 2. Give a full arrow pushing mechanism of the spontaneous redox reaction between NAD+/NADH and oxaloacetate/malate.arrow_forward
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