Consider the equation ∆G = ∆G° + RT ln(Q). What is the value of ∆G for a reaction at equilibrium? What does Q equal at equilibrium? At equilibrium, the previous equation reduces to ∆G° = −RT ln(K). When ∆G° > 0, what does it indicate about K? When ∆G° < 0, what does it indicate about K? When t ∆G° = 0, what does it indicate about K? ∆G predicts spontaneity for a reaction, whereas ∆G° predicts the equilibrium position. Explain what this statement means. Under what conditions can you use ∆G° to determine the spontaneity of a reaction?
Trending nowThis is a popular solution!
Chapter 16 Solutions
Chemistry: An Atoms First Approach
Additional Science Textbook Solutions
Chemistry: Structure and Properties (2nd Edition)
Organic Chemistry As a Second Language: Second Semester Topics
Chemistry: A Molecular Approach
General, Organic, and Biological Chemistry - 4th edition
Essential Organic Chemistry (3rd Edition)
The Organic Chem Lab Survival Manual: A Student's Guide to Techniques
- Which contains greater entropy, a quantity of frozen benzene or the same quantity of liquid benzene at the same temperature? Explain in terms of the dispersal of energy in the substance.arrow_forwardWhat determines Ssurr for a process? To calculate Ssurr at constant pressure and temperature, we use the following equation: Ssurr = H/T. Why does a minus sign appear in the equation, and why is Ssurr inversely proportional to temperature?arrow_forwardFor each process, predict whether entropy increases or decreases, and explain how you arrived at your prediction. 2 CO2(g) → 2 CO(g) + O2(g) NaCl(s) → NaCl(aq) MgCO3(s) → MgO(s) + CO2(g)arrow_forward
- Elemental boron, in the form of thin fibers, can be made by reducing a boron halide with H2. BCl3(g) + 3/2 H2(g) B(s) + 3HCl(g) Calculate H, S, and G at 25 C for this reaction. Is the reaction predicted to be product favored at equilibrium at 25 C? If so, is it enthalpy driven or entropy driven?arrow_forwardWhat is the sign of the standard Gibbs free-energy change at low temperatures and at high temperatures for the synthesis of ammonia? 3H2(g) + N2(g) 2NH3(g)arrow_forward10.46 Discuss the effect of temperature change on the spontaneity of the following reactions at 1 atm. (a) Al2O3(s)+2Fe(s)2Al(s)+Fe2O3(s) H = 851.5kJ; S =38.5 J/K (b) N2H4(l)N2(g)+2H2(g) H =-50.6 kJ; S= 0.3315 kJ/K (c) SO3(g)SO2(g)+12O2(g) H = 98.9 kJ; S= 0.0939 kJ/Karrow_forward
- a Calculate K1, at 25C for sulfurous acid: H2SO3(aq)H+(aq)+HSO3(aq) b Which thermodynamic factor is the most significant in accounting for the fact that sulfurous acid is a weak acid? Why?arrow_forwardThe standard free energies of formation and the standard enthalpies of formation at 298 K for difluoroacetylene (C2F2) and hexafluorobenzene (C6F6) are Gfo(KJ/mol) Hfo(KJ/mol) C2F2(g) 191.2 241.3 Hexane 78.2 132.8 For the following reaction: C6F6(g)3C2F2(g) a. calculate S at 298 K. b. calculate K at 298 K. c. estimate K at 3000. K, assuming H and S do not depend on temperature.arrow_forwardA student determines the value of the equilibrium constant to be 4.03×10-18 for the following reaction.Fe3O4(s) + 4H2(g)3Fe(s) + 4H2O(g)Based on this value of Keq:G° for this reaction is expected to be (greater, less) fill in the blank 1 than zero.Calculate the free energy change for the reaction of 2.37 moles of Fe3O4(s) at standard conditions at 298K. G°rxn = kJarrow_forward
- What is K for a reaction if ∆G° =-171.1 kJ/mol at 25°C? (R = 8.314 J/mol ・ K)arrow_forwardFor the gas-phase equilibrium A(g) + 2 B(g) ⇌ C(g) the initial partial pressures of A, B, and C are all 0.300 atm. After equilibrium is established at 25°C, it is found that the partial pressure of C is 0.220 atm. What is ∆G° for this reaction? (R = 8.314 J/mol・K).arrow_forwardConsider 8 the following reaction: 2NH3(g) + CO2(g) → NH2CONH2(aq) + H2O(l) ∆G° = -13.6 kJ at 25°C What is the value of ∆G at 25°C for this reaction under the following set of conditions? 25.0 atm NH3 (g) 0.500 atm CO2 (g) 1.00 M NH2CONH2 (aq) Group of answer choices -18.1 kJ 0.63 kJ -27.8 kJ 14.2 kJ -20.0 kJarrow_forward
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage LearningChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
- Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning