The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined. Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula, Δ G = Δ H − T Δ S To determine: The authenticity of the statement, “The given reaction is an endothermic reaction”.

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Answer 1

Question

Chapter 16, Problem 101CWP

(a)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “The given reaction is an endothermic reaction”.

(b)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “The $ΔS∘$ for the given reaction is negative”.

(c)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “If temperature is increased in the given reaction, the ratio $PCl5PCl3$ will increase”.

(d)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “The $ΔG∘$ for the given reaction is negative at all temperatures”.

(e)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “When $ΔG∘$ for the given reaction is negative, then $Kp$ is greater than $1.00$ ”.

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Answer 2

Question

Chapter 16, Problem 101CWP

(a)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “The given reaction is an endothermic reaction”.

(b)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “The $ΔS∘$ for the given reaction is negative”.

(c)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “If temperature is increased in the given reaction, the ratio $PCl5PCl3$ will increase”.

(d)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “The $ΔG∘$ for the given reaction is negative at all temperatures”.

(e)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “When $ΔG∘$ for the given reaction is negative, then $Kp$ is greater than $1.00$ ”.

Expert Solution & Answer

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See solution

Answer 3

Question

Chapter 16, Problem 101CWP

(a)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “The given reaction is an endothermic reaction”.

(b)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “The $ΔS∘$ for the given reaction is negative”.

(c)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “If temperature is increased in the given reaction, the ratio $PCl5PCl3$ will increase”.

(d)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “The $ΔG∘$ for the given reaction is negative at all temperatures”.

(e)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “When $ΔG∘$ for the given reaction is negative, then $Kp$ is greater than $1.00$ ”.

Expert Solution & Answer

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See solution

Answer 4

Question

Chapter 16, Problem 101CWP

(a)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “The given reaction is an endothermic reaction”.

(b)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “The $ΔS∘$ for the given reaction is negative”.

(c)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “If temperature is increased in the given reaction, the ratio $PCl5PCl3$ will increase”.

(d)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “The $ΔG∘$ for the given reaction is negative at all temperatures”.

(e)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “When $ΔG∘$ for the given reaction is negative, then $Kp$ is greater than $1.00$ ”.

Expert Solution & Answer

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Answer 5

Chapter 16, Problem 101CWP

(a)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “The given reaction is an endothermic reaction”.

(b)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “The $ΔS∘$ for the given reaction is negative”.

(c)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “If temperature is increased in the given reaction, the ratio $PCl5PCl3$ will increase”.

(d)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “The $ΔG∘$ for the given reaction is negative at all temperatures”.

(e)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “When $ΔG∘$ for the given reaction is negative, then $Kp$ is greater than $1.00$ ”.

Answer 6

Chapter 16, Problem 101CWP

(a)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “The given reaction is an endothermic reaction”.

Answer 7

Chapter 16, Problem 101CWP

(a)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “The given reaction is an endothermic reaction”.

Answer 8

(b)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “The $ΔS∘$ for the given reaction is negative”.

Answer 9

(b)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “The $ΔS∘$ for the given reaction is negative”.

Answer 10

(c)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “If temperature is increased in the given reaction, the ratio $PCl5PCl3$ will increase”.

Answer 11

(c)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “If temperature is increased in the given reaction, the ratio $PCl5PCl3$ will increase”.

Answer 12

(d)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “The $ΔG∘$ for the given reaction is negative at all temperatures”.

Answer 13

(d)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “The $ΔG∘$ for the given reaction is negative at all temperatures”.

Answer 14

(e)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “When $ΔG∘$ for the given reaction is negative, then $Kp$ is greater than $1.00$ ”.

Answer 15

(e)

Interpretation Introduction

Interpretation: The statements which are true out of the given statements at the given values of temperature and standard enthalpy change for the given reaction are to be determined.

Concept Introduction: The relation between standard free energy change, standard entropy change and standard free energy change is determined by using the formula,

$ΔG=ΔH−TΔS$

To determine: The authenticity of the statement, “When $ΔG∘$ for the given reaction is negative, then $Kp$ is greater than $1.00$ ”.

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 16 - Define the following: a. spontaneous process b....Ch. 16 - What is the second law of thermodynamics? For any...Ch. 16 - Prob. 3RQ Ch. 16 - Prob. 4RQ Ch. 16 - Prob. 5RQ Ch. 16 - What is the standard free energy change, G, for a...Ch. 16 - If you calculate a value for G for a reaction...Ch. 16 - Consider the equation G = G + RT ln(Q). What is...Ch. 16 - Even if G is negative, the reaction may not occur....Ch. 16 - Prob. 10RQ

Solution Summary: The author explains that the relation between standard free energy change, standard entropy change and standard-free energy changes is determined by using the formula.

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