The information that can be determined from Δ G for a reaction; the information obtained from Δ G ° for a reaction; the reason as to how the Δ G ° allows the determination of the equilibrium constant for a reaction; the procedure to estimate the value of the equilibrium constant at temperatures other than 25 °C ; the estimation of temperature where K = 1 for a reaction and the possibility of all reactions having a specific temperature where K = 1 is to be stated. Concept introduction: The change in free energy observed during the formation of 1 mol of a given substance from its constituent elements, at standard states is known as the standard free energy of formation of that particular compound.
The information that can be determined from Δ G for a reaction; the information obtained from Δ G ° for a reaction; the reason as to how the Δ G ° allows the determination of the equilibrium constant for a reaction; the procedure to estimate the value of the equilibrium constant at temperatures other than 25 °C ; the estimation of temperature where K = 1 for a reaction and the possibility of all reactions having a specific temperature where K = 1 is to be stated. Concept introduction: The change in free energy observed during the formation of 1 mol of a given substance from its constituent elements, at standard states is known as the standard free energy of formation of that particular compound.
Solution Summary: The author explains how the value of Delta G indicates if a process is feasible or not.
Interpretation: The information that can be determined from
ΔG for a reaction; the information obtained from
ΔG° for a reaction; the reason as to how the
ΔG° allows the determination of the equilibrium constant for a reaction; the procedure to estimate the value of the equilibrium constant at temperatures other than
25°C; the estimation of temperature where
K=1 for a reaction and the possibility of all reactions having a specific temperature where
K=1 is to be stated.
Concept introduction: The change in free energy observed during the formation of
1mol of a given substance from its constituent elements, at standard states is known as the standard free energy of formation of that particular compound.
Q8. Draw the mechanism for this halogenation reaction. Show all steps including initiation,
propagation, and recombination.
Cl₂, hv
CI
Br
Br2, hv, heat
Q6. Given the following alkanes, draw the most likely product to form upon monohalogenation
with Br2 (keep in mind that this may not be the only product to form though). If the reaction was
performed with Cl2 would there be more or less selectivity in the desired product formation?
Why?
(a)
(b)
(c)
Q4. Radicals
a. For the following indicated bonds, rank them in order of decreasing AH° for homolytic
cleavage. Based on your answer, which bond would be most likely to break homolytically?
(c)
CH3
CH3
H3C
CH3
(a)
CH3
(b)
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The Laws of Thermodynamics, Entropy, and Gibbs Free Energy; Author: Professor Dave Explains;https://www.youtube.com/watch?v=8N1BxHgsoOw;License: Standard YouTube License, CC-BY