Chemistry: An Atoms First Approach
2nd Edition
ISBN: 9781305079243
Author: Steven S. Zumdahl, Susan A. Zumdahl
Publisher: Cengage Learning
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Chapter 16, Problem 116CP
Interpretation Introduction
Interpretation: The value of
Concept introduction:
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What is the absorption spectrum of a solution of naphthalene in benzene , and the vibronic transitions responsible for the vibrational fine structure ?
3. Titanium(III) chloride can be used to catalyze the polymerization of ethylene. It is prepared by hydrogen reduction of
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hydrogen chloride gas.
(a) Write a BALANCED chemical reaction for the preparation of titanium(III) chloride
(b) A 250 L reaction vessel at 325°C is filled with hydrogen gas to a pressure of 1.3 atm. Titanium(IV) chloride is then added
to bring the total pressure to 3.00 atm. How many grams of titanium(III) chloride will be produced after completion of the
reaction?
(c) What will be the pressure of the resulting hydrogen chloride gas that is also produced?
Chapter 16 Solutions
Chemistry: An Atoms First Approach
Ch. 16 - Define the following: a. spontaneous process b....Ch. 16 - What is the second law of thermodynamics? For any...Ch. 16 - Prob. 3RQCh. 16 - Prob. 4RQCh. 16 - Prob. 5RQCh. 16 - What is the standard free energy change, G, for a...Ch. 16 - If you calculate a value for G for a reaction...Ch. 16 - Consider the equation G = G + RT ln(Q). What is...Ch. 16 - Even if G is negative, the reaction may not occur....Ch. 16 - Prob. 10RQ
Ch. 16 - For the process A(l) A(g), which direction is...Ch. 16 - Prob. 2ALQCh. 16 - Gas A2 reacts with gas B2 to form gas AB at a...Ch. 16 - Prob. 4ALQCh. 16 - Prob. 5ALQCh. 16 - Prob. 6ALQCh. 16 - Predict the sign of S for each of the following...Ch. 16 - Is Ssurr favorable or unfavorable for exothermic...Ch. 16 - At 1 atm, liquid water is heated above 100C. For...Ch. 16 - Prob. 10ALQCh. 16 - The synthesis of glucose directly from CO2 and H2O...Ch. 16 - When the environment is contaminated by a toxic or...Ch. 16 - Entropy has been described as times arrow....Ch. 16 - Prob. 14QCh. 16 - A mixture of hydrogen gas and chlorine gas remains...Ch. 16 - Consider the following potential energy plots: a....Ch. 16 - Prob. 17QCh. 16 - Given the following illustration, what can be said...Ch. 16 - The third law of thermodynamics states that the...Ch. 16 - Prob. 20QCh. 16 - Prob. 21QCh. 16 - Prob. 22QCh. 16 - Monochloroethane (C2H5Cl) can be produced by the...Ch. 16 - Prob. 24QCh. 16 - Which of the following processes are spontaneous?...Ch. 16 - Which of the following processes are spontaneous?...Ch. 16 - Prob. 27ECh. 16 - Consider the following illustration of six...Ch. 16 - Consider the following energy levels, each capable...Ch. 16 - Prob. 30ECh. 16 - Choose the substance with the larger positional...Ch. 16 - Which of the following involve an increase in the...Ch. 16 - Predict the sign of Ssurr for the following...Ch. 16 - Prob. 34ECh. 16 - Given the values of H and S, which of the...Ch. 16 - At what temperatures will the following processes...Ch. 16 - Ethanethiol (C2H5SH; also called ethyl mercaptan)...Ch. 16 - For mercury, the enthalpy of vaporization is 58.51...Ch. 16 - For ammonia (NH3), the enthalpy of fusion is 5.65...Ch. 16 - The enthalpy of vaporization of ethanol is 38.7...Ch. 16 - Predict the sign of S for each of the following...Ch. 16 - Prob. 42ECh. 16 - Prob. 43ECh. 16 - For each of the following pairs, which substance...Ch. 16 - Predict the sign of S and then calculate S for...Ch. 16 - Predict the sign of S and then calculate S for...Ch. 16 - Prob. 47ECh. 16 - Prob. 48ECh. 16 - Prob. 49ECh. 16 - Two crystalline forms of white phosphorus are...Ch. 16 - Consider the reaction 2O(g)O2(g) a. Predict the...Ch. 16 - Prob. 52ECh. 16 - Prob. 53ECh. 16 - The major industrial use of hydrogen is in the...Ch. 16 - Prob. 55ECh. 16 - At 100C and 1.00 atm, H = 40.6 kJ/mol for the...Ch. 16 - Prob. 57ECh. 16 - Prob. 58ECh. 16 - Prob. 59ECh. 16 - Prob. 60ECh. 16 - Consider the reaction...Ch. 16 - Consider the reaction 2POCl3(g)2PCl3(g)+O2(g) a....Ch. 16 - Prob. 63ECh. 16 - Consider two reactions for the production of...Ch. 16 - Prob. 65ECh. 16 - Prob. 66ECh. 16 - Consider the reaction 2NO2(g)N2O4(g) For each of...Ch. 16 - Prob. 68ECh. 16 - One of the reactions that destroys ozone in the...Ch. 16 - Hydrogen sulfide can be removed from natural gas...Ch. 16 - Consider the following reaction at 25.0C:...Ch. 16 - The standard free energies of formation and the...Ch. 16 - Calculate G forH2O(g)+12O2(g)H2O2(g) at 600. K,...Ch. 16 - The Ostwald process for the commercial production...Ch. 16 - Cells use the hydrolysis of adenosine...Ch. 16 - One reaction that occurs in human metabolism is...Ch. 16 - Prob. 77ECh. 16 - Consider the following reaction at 298 K:...Ch. 16 - Prob. 79ECh. 16 - The equilibrium constant K for the reaction...Ch. 16 - Prob. 81AECh. 16 - Some water is placed in a coffee-cup calorimeter....Ch. 16 - Consider the following system at equilibrium at...Ch. 16 - Calculate the entropy change for the vaporization...Ch. 16 - As O2(l) is cooled at 1 atm, it freezes at 54.5 K...Ch. 16 - Prob. 86AECh. 16 - Using the following data, calculate the value of...Ch. 16 - Prob. 88AECh. 16 - Carbon monoxide is toxic because it bonds much...Ch. 16 - Prob. 90AECh. 16 - Prob. 91AECh. 16 - Use the equation in Exercise 79 to determine H and...Ch. 16 - Consider the reaction...Ch. 16 - Consider the following diagram of free energy (G)...Ch. 16 - Prob. 95CWPCh. 16 - For rubidium Hvapo=69.0KJ/mol at 686C, its boiling...Ch. 16 - Given the thermodynamic data below, calculate S...Ch. 16 - Prob. 98CWPCh. 16 - Prob. 99CWPCh. 16 - Consider the dissociation of a weak acid HA (Ka =...Ch. 16 - Prob. 101CWPCh. 16 - The equilibrium constant for a certain reaction...Ch. 16 - For the following reactions at constant pressure,...Ch. 16 - The standard enthalpy of formation of H2O(l) at...Ch. 16 - Prob. 105CPCh. 16 - Liquid water at 25C is introduced into an...Ch. 16 - Using data from Appendix 4, calculate H, G, and K...Ch. 16 - Prob. 108CPCh. 16 - Prob. 109CPCh. 16 - Prob. 110CPCh. 16 - Prob. 111CPCh. 16 - Prob. 112CPCh. 16 - If wet silver carbonate is dried in a stream of...Ch. 16 - Carbon tetrachloride (CCl4) and benzene (C6H6)...Ch. 16 - Sodium chloride is added to water (at 25C) until...Ch. 16 - Prob. 116CPCh. 16 - Prob. 117CPCh. 16 - Prob. 118IPCh. 16 - Prob. 119IPCh. 16 - Prob. 120IPCh. 16 - Consider a sample containing 5.00 moles of a...Ch. 16 - Impure nickel, refined by smelting sulfide ores in...
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- 1. Sodium azide (NaN3) is the primary chemical substance used in automobile air bags. Upon impact, the decomposition of sodium azide is initiated to produce sodium metal and nitrogen gas which then inflates the bag. How many liters of nitrogen gas are produced at 1.15 atm and 30.0°C when 145.0 grams of sodium azide decomposes? 2. Calcium carbonate (such as that in limestone) reacts with aqueous hydrochloric acid to produce carbon dioxide, aqueous calcium chloride and water. How many liters of carbon dioxide are produced at 20°C and 745 torr when 3.583 grams of calcium carbonate is dissolved in solution containing 1.550 grams of hydrochloric acid?arrow_forwardShow all work (where appropriate) for full credit. 1. Describe (steps, equipment and quantities) how to accurately prepare 250.0 mL of a 0.0075 M solution of NaCl (aq) from a 500 mL, 0.0500 M stock solution. 2. Describe (steps, equipment and quantities) how to accurately prepare 250.0 mL of a 0.0075 M solution of NaCl (aq) from 100 g of solid NaCl.arrow_forward5. An unlabeled gas cylinder was recently found in the laboratory. A sample of the gas was removed and analyzed. A 500.0 mL sample of the gas at 15°C and a pressure of 736 mmHg was found to weigh 2.688 g. Determine the molar mass of the gas. What element is the gas?arrow_forward
- 4. Nitrogen gas is commonly sold in 49.0 L steal cylinders at a pressure of 150 atm. (a) How many moles of nitrogen are in the container if the temperature of the cylinder is 21°C. (b) How many moles of nitrogen will there be if the container above is heated to 100°C? (careful here) (c) What is the mass of nitrogen gas in the cylinder in part (a)? (d) What volume would the nitrogen occupy at 21°C, if the pressure was reduced to 1.02 atm? (e) What would be the pressure of the nitrogen gas in the cylinder when the temperature is raised to 39°C?arrow_forward6. A 0.4550 g sample of an unknown organic compound with the empirical formula CH2O was placed into a 150.0 ml vessel and was vaporized into a gas. At 175.0°C, the pressure of the vaporized compound was measured at 941.1 torr. (a) Determine the molar mass of the compound (b) Determine the molecular formula of the compound.arrow_forwardDon't used Ai solutionarrow_forward
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