To identify the functional groups in Warfarin. Concept Introduction: A group of atoms which are responsible for the chemical reactions of a various compounds is known as functional groups. A stereo centre is the centre where all the 4 groups attached to a carbon are different. A keto group stays in the equilibrium with its enol (−OH) form by resonance. NaBH 4 is a reducing agent it reduces ketone or aldehyde to an alcohol.

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Ethyl butyrate, CH3CH2CH2CO2CH2CH3CH3CH2CH2CO2CH2CH3, is an artificial fruit flavor commonly used in the food industry for such flavors as orange and pineapple. Its fragrance and taste are often associated with fresh orange juice, and thus it is most commonly used as orange flavoring. It can be produced by the reaction of butanoic acid with ethanol in the presence of an acid catalyst (H+H+): CH3CH2CH2CO2H(l)+CH2CH3OH(l)H+⟶CH3CH2CH2CO2CH2CH3(l)+H2O(l) Part A Given 7.30 gg of butanoic acid and excess ethanol, how many grams of ethyl butyrate would be synthesized, assuming a complete 100%% yield? Express your answer in grams to three significant figures. Part B A chemist ran the reaction and obtained 5.95 gg of ethyl butyrate. What was the percent yield? Express your answer as a percent to three significant figures. Part C The chemist discovers a more efficient catalyst that can produce ethyl butyrate with a 78.0%% yield. How many grams would be produced from 7.30 gg of…

Answer 1

Question

Chapter 16, Problem 38P

Interpretation Introduction

Interpretation:

To identify the functional groups in Warfarin.

Concept Introduction:

A group of atoms which are responsible for the chemical reactions of a various compounds is known as functional groups.

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

To draw the stereorepresentation of the r enantiomer as s enantiomer is more active than r enantiomer.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

To draw the structural formula of keto form of Warfarin.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

To draw the product formed by treating warfarin with NaBH₄_..

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

The number of molecules of warfarin present in 4 mg tablet should be determined.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

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Ethyl butyrate, CH3CH2CH2CO2CH2CH3CH3CH2CH2CO2CH2CH3, is an artificial fruit flavor commonly used in the food industry for such flavors as orange and pineapple. Its fragrance and taste are often associated with fresh orange juice, and thus it is most commonly used as orange flavoring. It can be produced by the reaction of butanoic acid with ethanol in the presence of an acid catalyst (H+H+): CH3CH2CH2CO2H(l)+CH2CH3OH(l)H+⟶CH3CH2CH2CO2CH2CH3(l)+H2O(l) Part A Given 7.30 gg of butanoic acid and excess ethanol, how many grams of ethyl butyrate would be synthesized, assuming a complete 100%% yield? Express your answer in grams to three significant figures. Part B A chemist ran the reaction and obtained 5.95 gg of ethyl butyrate. What was the percent yield? Express your answer as a percent to three significant figures. Part C The chemist discovers a more efficient catalyst that can produce ethyl butyrate with a 78.0%% yield. How many grams would be produced from 7.30 gg of…

Ethyl butyrate, CH3CH2CH2CO2CH2CH3CH3CH2CH2CO2CH2CH3, is an artificial fruit flavor commonly used in the food industry for such flavors as orange and pineapple. Its fragrance and taste are often associated with fresh orange juice, and thus it is most commonly used as orange flavoring. It can be produced by the reaction of butanoic acid with ethanol in the presence of an acid catalyst (H+H+): CH3CH2CH2CO2H(l)+CH2CH3OH(l)H+⟶CH3CH2CH2CO2CH2CH3(l)+H2O(l) Given 8.45 gg of butanoic acid and excess ethanol, how many grams of ethyl butyrate would be synthesized, assuming a complete 100%% yield? Express your answer in grams to three significant figures. A chemist ran the reaction and obtained 5.50 gg of ethyl butyrate. What was the percent yield? Express your answer as a percent to three significant figures. The chemist discovers a more efficient catalyst that can produce ethyl butyrate with a 78.0%% yield. How many grams would be produced from 8.45 gg of butanoic acid and excess…

(a) Label the acetal in salicin, a naturally occurring pain reliever isolated from the bark of the willow tree. (b) How many 1° OH groups does salicin contain?

Answer 2

Question

Chapter 16, Problem 38P

Interpretation Introduction

Interpretation:

To identify the functional groups in Warfarin.

Concept Introduction:

A group of atoms which are responsible for the chemical reactions of a various compounds is known as functional groups.

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

To draw the stereorepresentation of the r enantiomer as s enantiomer is more active than r enantiomer.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

To draw the structural formula of keto form of Warfarin.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

To draw the product formed by treating warfarin with NaBH₄_..

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

The number of molecules of warfarin present in 4 mg tablet should be determined.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

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Answer 3

Question

Chapter 16, Problem 38P

Interpretation Introduction

Interpretation:

To identify the functional groups in Warfarin.

Concept Introduction:

A group of atoms which are responsible for the chemical reactions of a various compounds is known as functional groups.

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

To draw the stereorepresentation of the r enantiomer as s enantiomer is more active than r enantiomer.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

To draw the structural formula of keto form of Warfarin.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

To draw the product formed by treating warfarin with NaBH₄_..

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

The number of molecules of warfarin present in 4 mg tablet should be determined.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

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Answer 4

Question

Chapter 16, Problem 38P

Interpretation Introduction

Interpretation:

To identify the functional groups in Warfarin.

Concept Introduction:

A group of atoms which are responsible for the chemical reactions of a various compounds is known as functional groups.

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

To draw the stereorepresentation of the r enantiomer as s enantiomer is more active than r enantiomer.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

To draw the structural formula of keto form of Warfarin.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

To draw the product formed by treating warfarin with NaBH₄_..

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

The number of molecules of warfarin present in 4 mg tablet should be determined.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Expert Solution & Answer

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Answer 5

Chapter 16, Problem 38P

Interpretation Introduction

Interpretation:

To identify the functional groups in Warfarin.

Concept Introduction:

A group of atoms which are responsible for the chemical reactions of a various compounds is known as functional groups.

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

To draw the stereorepresentation of the r enantiomer as s enantiomer is more active than r enantiomer.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

To draw the structural formula of keto form of Warfarin.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

To draw the product formed by treating warfarin with NaBH₄_..

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Interpretation Introduction

Interpretation:

The number of molecules of warfarin present in 4 mg tablet should be determined.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Answer 6

Chapter 16, Problem 38P

Interpretation Introduction

Interpretation:

To identify the functional groups in Warfarin.

Concept Introduction:

A group of atoms which are responsible for the chemical reactions of a various compounds is known as functional groups.

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Answer 7

Chapter 16, Problem 38P

Interpretation Introduction

Interpretation:

To identify the functional groups in Warfarin.

Concept Introduction:

A group of atoms which are responsible for the chemical reactions of a various compounds is known as functional groups.

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Answer 8

Interpretation Introduction

Interpretation:

To draw the stereorepresentation of the r enantiomer as s enantiomer is more active than r enantiomer.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Answer 9

Interpretation Introduction

Interpretation:

To draw the stereorepresentation of the r enantiomer as s enantiomer is more active than r enantiomer.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Answer 10

Interpretation Introduction

Interpretation:

To draw the structural formula of keto form of Warfarin.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Answer 11

Interpretation Introduction

Interpretation:

To draw the structural formula of keto form of Warfarin.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Answer 12

Interpretation Introduction

Interpretation:

To draw the product formed by treating warfarin with NaBH₄_..

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Answer 13

Interpretation Introduction

Interpretation:

To draw the product formed by treating warfarin with NaBH₄_..

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Answer 14

Interpretation Introduction

Interpretation:

The number of molecules of warfarin present in 4 mg tablet should be determined.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Answer 15

Interpretation Introduction

Interpretation:

The number of molecules of warfarin present in 4 mg tablet should be determined.

Concept Introduction:

A stereo centre is the centre where all the 4 groups attached to a carbon are different.

A keto group stays in the equilibrium with its enol (−OH) form by resonance.

NaBH₄ is a reducing agent it reduces ketone or aldehyde to an alcohol.

Answer 16

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Ch. 16.2 - Problem 17-1 Wrtie the IUPAC name for each...Ch. 16.2 - Prob. 16.2QC Ch. 16.2 - Prob. 16.3QC Ch. 16.4 - Prob. 16.4QC Ch. 16.4 - Prob. 16.5QC Ch. 16.4 - Problem 17-6 Show the reaction of benzaldehyde...Ch. 16.4 - Problem 17-7 Identify all hemiacetals and acetals...Ch. 16.5 - Prob. 16.8QC Ch. 16 - 17-9 Answer true or false. (a) The one aldehyde...Ch. 16 - Prob. 2P

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