Biochemistry
9th Edition
ISBN: 9781305961135
Author: Mary K. Campbell, Shawn O. Farrell, Owen M. McDougal
Publisher: Cengage Learning
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Textbook Question
Chapter 16, Problem 35RE
REFLECT AND APPLY All naturally occurring polysaccharides have one terminal residue, which contains a free anomeric carbon. Why do these polysaccharides not give a positive chemical test for a reducing sugar?
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Chapter 16 Solutions
Biochemistry
Ch. 16 - RECALL Define the following terms: polysaccharide,...Ch. 16 - RECALL Name which, if any, of the following are...Ch. 16 - RECALL Name which, if any, of the following groups...Ch. 16 - RECALL What is the difference between an...Ch. 16 - RECALL How many possible epimers of D-glucose...Ch. 16 - RECALL Why are furanoses and pyranoses the most...Ch. 16 - RECALL How many chiral centers are there in the...Ch. 16 - REFLECT AND APPLY Following are Fischer...Ch. 16 - REFLECT AND APPLY The sugar alcohol often used in...Ch. 16 - REFLECT AND APPLY Consider the structures of...
Ch. 16 - REFLECT AND APPLY Two sugars are epimers of each...Ch. 16 - REFLECT AND APPLY How does the cyclization of...Ch. 16 - REFLECT AND APPLY Convert the following Haworth...Ch. 16 - REFLECT AND APPLY Convert each of the following...Ch. 16 - REFLECT AND APPLY Starting with a Fischer...Ch. 16 - REFLECT AND APPLY Starting with the open-chain...Ch. 16 - RECALL What is unusual about the structure of...Ch. 16 - RECALL What is the chemical difference between a...Ch. 16 - RECALL Define the term reducing sugar.Ch. 16 - BIOCHEMICAL CONNECTIONS What are the structural...Ch. 16 - RECALL Name two differences between sucrose and...Ch. 16 - REFLECT AND APPLY Draw a Haworth projection for...Ch. 16 - BIOCHEMICAL CONNECTIONS What is the metabolic...Ch. 16 - REFLECT AND APPLY Draw Haworth projection formulas...Ch. 16 - BIOCHEMICAL CONNECTIONS A friend asks you why some...Ch. 16 - RECALL What are some of the main differences...Ch. 16 - RECALL How does chitin differ from cellulose in...Ch. 16 - RECALL How does glycogen differ from starch in...Ch. 16 - RECALL What is the main structural difference...Ch. 16 - RECALL What is the main structural difference...Ch. 16 - RECALL How do the cell walls of bacteria differ...Ch. 16 - REFLECT AND APPLY Pectin, which occurs in plant...Ch. 16 - REFLECT AND APPLY Advertisements for a food...Ch. 16 - REFLECT AND APPLY Explain how the minor structural...Ch. 16 - REFLECT AND APPLY All naturally occurring...Ch. 16 - REFLECT AND APPLY An amylose chain is 5000 glucose...Ch. 16 - REFLECT AND APPLY Suppose that a polymer of...Ch. 16 - REFLECT AND APPLY Glycogen is highly branched....Ch. 16 - REFLECT AND APPLY No animal can digest cellulose....Ch. 16 - REFLECT AND APPLY How does the presence of -bonds...Ch. 16 - REFLECT AND APPLY How do the sites of cleavage of...Ch. 16 - BIOCHEMICAL CONNECTIONS What is the benefit of...Ch. 16 - REFLECT AND APPLY How would you expect the active...Ch. 16 - REFLECT AND APPLY Would you expect cross-linking...Ch. 16 - REFLECT AND APPLY Compare the information in the...Ch. 16 - REFLECT AND APPLY Why is it advantageous that...Ch. 16 - REFLECT AND APPLY Why is the polysaccharide chitin...Ch. 16 - REFLECT AND APPLY Could bacterial cell walls...Ch. 16 - REFLECT AND APPLY Some athletes eat diets high in...Ch. 16 - Prob. 50RECh. 16 - REFLECT AND APPLY Blood samples for research or...Ch. 16 - REFLECT AND APPLY Based on what you know about...Ch. 16 - RECALL What are glycoproteins? What are some of...Ch. 16 - BIOCHEMICAL CONNECTIONS Briefly indicate the role...
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- REFLECT AND APPLY Compare the information in the sequence of monomers in a polysaccharide with that in the sequence of amino acid residues in a protein.arrow_forwardREFLECT AND APPLY Many properties of acetic acid can be rationalized in terms of a hydrogen-bonded dimer. Propose a structure for such a dimer.arrow_forwardREFLECT AND APPLY Why is it advantageous that polysaccharides can have branched chains? How do they achieve this structural feature?arrow_forward
- REFLECT AND APPLY Would you expect cross-linking to play a role in the structure of polysaccharides? If so, how would the cross-links be formed?arrow_forwardREFLECT AND APPLY Convert each of the following chair conformations to an open-chain from and to a Fischer projection. Name the monosaccharides you have drawn.arrow_forwardREFLECT AND APPLY Starting with a Fischer projection of D-fructose, write equations showing the formation of -D-fructopyranose, -D-fructofuranose, -D-fructopyranose, and -D-fructofuranose.arrow_forward
- REFLECT AND APPLY Following are Fischer projections for a group of five-carbon sugars, all of which are aldopentoses. Identify the pairs that are enantiomers and the pairs that are epimers. (The sugars shown here are not all of the possible five-carbon sugars.)arrow_forwardREFLECT AND APPLY Convert the following Haworth projections to a Fischer projection. Name the monosaccharides you have drawn.arrow_forwardREFLECT AND APPLY Explain how the minor structural difference between - and -glucose is related to the differences in structure and function in the polymers formed from these two monomers.arrow_forward
- REFLECT AND APPLY Based on what you know about glycosidic bonds, propose a scheme for formation of covalent bonds between the carbohydrate and protein portions of glycoproteins.arrow_forwardREFLECT AND APPLY Pectin, which occurs in plant cell walls, exists in nature as a polymer of D-galacturonic acid methylated at car- bon 6 of the monomer. Draw a Haworth projection for a repeating disaccharide unit of pectin with one methylated and one unmeth- ylated monomer unit in (14) linkage.arrow_forwardREFLECT AND APPLY Nucleic acids are polymers of just four different monomers in a linear arrangement. How many different sequences are available if one makes a polymer with only 40 monomers? How does this number compare with Avogadros number?arrow_forward
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