The structural formula for the product of hydrolysis of given acetal in aqueous HCl has to be drawn. Concept Introduction: The structural formula of a compound shows how the atoms are arranged in a molecule and, in particular, shows which functional groups are present. Hydrocarbon compound which contain a hydroxyl group and an alkoxy group is known as Hemiacetals. Hemiacetal can be prepared by the addition of alcohol to an aldehyde or ketone in the presence of an acid catalyst. Hemiacetals react with a second alcohol molecule to produce an acetal, which contains a carbon with two alkoxy groups –OR. The process of hydrolysis of acetal exactly the reverse of acetal formation and in this reaction hemiacetal acts as the intermediate. The reaction is shown below,

Question

Indicate how to obtain 2-metilbencimidazol from 1,2-diaminobenzene.

Answer 1

Question

Chapter 16, Problem 16.31P

(a)

Interpretation Introduction

Interpretation:

The structural formula for the product of hydrolysis of given acetal in aqueous HCl has to be drawn.

Concept Introduction:

The structural formula of a compound shows how the atoms are arranged in a molecule and, in particular, shows which functional groups are present.

Hydrocarbon compound which contain a hydroxyl group and an alkoxy group is known as Hemiacetals. Hemiacetal can be prepared by the addition of alcohol to an aldehyde or ketone in the presence of an acid catalyst. Hemiacetals react with a second alcohol molecule to produce an acetal, which contains a carbon with two alkoxy groups –OR.

The process of hydrolysis of acetal exactly the reverse of acetal formation and in this reaction hemiacetal acts as the intermediate. The reaction is shown below,

(b)

Interpretation Introduction

Interpretation:

The structural formula for the product of hydrolysis of given acetal in aqueous HCl has to be drawn.

Concept Introduction:

The structural formula of a compound shows how the atoms are arranged in a molecule and, in particular, shows which functional groups are present.

Hydrocarbon compound which contain a hydroxyl group and an alkoxy group is known as Hemiacetals. Hemiacetal can be prepared by the addition of alcohol to an aldehyde or ketone in the presence of an acid catalyst. Hemiacetals react with a second alcohol molecule to produce an acetal, which contains a carbon with two alkoxy groups –OR.

The process of hydrolysis of acetal exactly the reverse of acetal formation and in this reaction hemiacetal acts as the intermediate. The reaction is shown below,

(c)

Interpretation Introduction

Interpretation:

The structural formula for the product of hydrolysis of given acetal in aqueous HCl has to be drawn.

Concept Introduction:

The structural formula of a compound shows how the atoms are arranged in a molecule and, in particular, shows which functional groups are present.

Hydrocarbon compound which contain a hydroxyl group and an alkoxy group is known as Hemiacetals. Hemiacetal can be prepared by the addition of alcohol to an aldehyde or ketone in the presence of an acid catalyst. Hemiacetals react with a second alcohol molecule to produce an acetal, which contains a carbon with two alkoxy groups –OR.

The process of hydrolysis of acetal exactly the reverse of acetal formation and in this reaction hemiacetal acts as the intermediate. The reaction is shown below,

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Indicate how to obtain 2-metilbencimidazol from 1,2-diaminobenzene.

break down both reactions shown and explain it correctly using the bromonium ion mechanism, instead of the (disproven) carbocation-based mechanism.

Indicate how from 1,2-diaminobenzene to obtain 1-metilbenzotriazol.

Answer 2

Question

Chapter 16, Problem 16.31P

(a)

Interpretation Introduction

Interpretation:

The structural formula for the product of hydrolysis of given acetal in aqueous HCl has to be drawn.

Concept Introduction:

The structural formula of a compound shows how the atoms are arranged in a molecule and, in particular, shows which functional groups are present.

Hydrocarbon compound which contain a hydroxyl group and an alkoxy group is known as Hemiacetals. Hemiacetal can be prepared by the addition of alcohol to an aldehyde or ketone in the presence of an acid catalyst. Hemiacetals react with a second alcohol molecule to produce an acetal, which contains a carbon with two alkoxy groups –OR.

The process of hydrolysis of acetal exactly the reverse of acetal formation and in this reaction hemiacetal acts as the intermediate. The reaction is shown below,

(b)

Interpretation Introduction

Interpretation:

The structural formula for the product of hydrolysis of given acetal in aqueous HCl has to be drawn.

Concept Introduction:

The structural formula of a compound shows how the atoms are arranged in a molecule and, in particular, shows which functional groups are present.

Hydrocarbon compound which contain a hydroxyl group and an alkoxy group is known as Hemiacetals. Hemiacetal can be prepared by the addition of alcohol to an aldehyde or ketone in the presence of an acid catalyst. Hemiacetals react with a second alcohol molecule to produce an acetal, which contains a carbon with two alkoxy groups –OR.

The process of hydrolysis of acetal exactly the reverse of acetal formation and in this reaction hemiacetal acts as the intermediate. The reaction is shown below,

(c)

Interpretation Introduction

Interpretation:

The structural formula for the product of hydrolysis of given acetal in aqueous HCl has to be drawn.

Concept Introduction:

The structural formula of a compound shows how the atoms are arranged in a molecule and, in particular, shows which functional groups are present.

Hydrocarbon compound which contain a hydroxyl group and an alkoxy group is known as Hemiacetals. Hemiacetal can be prepared by the addition of alcohol to an aldehyde or ketone in the presence of an acid catalyst. Hemiacetals react with a second alcohol molecule to produce an acetal, which contains a carbon with two alkoxy groups –OR.

The process of hydrolysis of acetal exactly the reverse of acetal formation and in this reaction hemiacetal acts as the intermediate. The reaction is shown below,

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Answer 3

Question

Chapter 16, Problem 16.31P

(a)

Interpretation Introduction

Interpretation:

The structural formula for the product of hydrolysis of given acetal in aqueous HCl has to be drawn.

Concept Introduction:

The structural formula of a compound shows how the atoms are arranged in a molecule and, in particular, shows which functional groups are present.

Hydrocarbon compound which contain a hydroxyl group and an alkoxy group is known as Hemiacetals. Hemiacetal can be prepared by the addition of alcohol to an aldehyde or ketone in the presence of an acid catalyst. Hemiacetals react with a second alcohol molecule to produce an acetal, which contains a carbon with two alkoxy groups –OR.

The process of hydrolysis of acetal exactly the reverse of acetal formation and in this reaction hemiacetal acts as the intermediate. The reaction is shown below,

(b)

Interpretation Introduction

Interpretation:

The structural formula for the product of hydrolysis of given acetal in aqueous HCl has to be drawn.

Concept Introduction:

The structural formula of a compound shows how the atoms are arranged in a molecule and, in particular, shows which functional groups are present.

Hydrocarbon compound which contain a hydroxyl group and an alkoxy group is known as Hemiacetals. Hemiacetal can be prepared by the addition of alcohol to an aldehyde or ketone in the presence of an acid catalyst. Hemiacetals react with a second alcohol molecule to produce an acetal, which contains a carbon with two alkoxy groups –OR.

The process of hydrolysis of acetal exactly the reverse of acetal formation and in this reaction hemiacetal acts as the intermediate. The reaction is shown below,

(c)

Interpretation Introduction

Interpretation:

The structural formula for the product of hydrolysis of given acetal in aqueous HCl has to be drawn.

Concept Introduction:

The structural formula of a compound shows how the atoms are arranged in a molecule and, in particular, shows which functional groups are present.

Hydrocarbon compound which contain a hydroxyl group and an alkoxy group is known as Hemiacetals. Hemiacetal can be prepared by the addition of alcohol to an aldehyde or ketone in the presence of an acid catalyst. Hemiacetals react with a second alcohol molecule to produce an acetal, which contains a carbon with two alkoxy groups –OR.

The process of hydrolysis of acetal exactly the reverse of acetal formation and in this reaction hemiacetal acts as the intermediate. The reaction is shown below,

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Answer 4

Question

Chapter 16, Problem 16.31P

(a)

Interpretation Introduction

Interpretation:

The structural formula for the product of hydrolysis of given acetal in aqueous HCl has to be drawn.

Concept Introduction:

The structural formula of a compound shows how the atoms are arranged in a molecule and, in particular, shows which functional groups are present.

Hydrocarbon compound which contain a hydroxyl group and an alkoxy group is known as Hemiacetals. Hemiacetal can be prepared by the addition of alcohol to an aldehyde or ketone in the presence of an acid catalyst. Hemiacetals react with a second alcohol molecule to produce an acetal, which contains a carbon with two alkoxy groups –OR.

The process of hydrolysis of acetal exactly the reverse of acetal formation and in this reaction hemiacetal acts as the intermediate. The reaction is shown below,

(b)

Interpretation Introduction

Interpretation:

The structural formula for the product of hydrolysis of given acetal in aqueous HCl has to be drawn.

Concept Introduction:

The structural formula of a compound shows how the atoms are arranged in a molecule and, in particular, shows which functional groups are present.

Hydrocarbon compound which contain a hydroxyl group and an alkoxy group is known as Hemiacetals. Hemiacetal can be prepared by the addition of alcohol to an aldehyde or ketone in the presence of an acid catalyst. Hemiacetals react with a second alcohol molecule to produce an acetal, which contains a carbon with two alkoxy groups –OR.

The process of hydrolysis of acetal exactly the reverse of acetal formation and in this reaction hemiacetal acts as the intermediate. The reaction is shown below,

(c)

Interpretation Introduction

Interpretation:

The structural formula for the product of hydrolysis of given acetal in aqueous HCl has to be drawn.

Concept Introduction:

The structural formula of a compound shows how the atoms are arranged in a molecule and, in particular, shows which functional groups are present.

Hydrocarbon compound which contain a hydroxyl group and an alkoxy group is known as Hemiacetals. Hemiacetal can be prepared by the addition of alcohol to an aldehyde or ketone in the presence of an acid catalyst. Hemiacetals react with a second alcohol molecule to produce an acetal, which contains a carbon with two alkoxy groups –OR.

The process of hydrolysis of acetal exactly the reverse of acetal formation and in this reaction hemiacetal acts as the intermediate. The reaction is shown below,

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Answer 5

Chapter 16, Problem 16.31P

(a)

Interpretation Introduction

Interpretation:

The structural formula for the product of hydrolysis of given acetal in aqueous HCl has to be drawn.

Concept Introduction:

The structural formula of a compound shows how the atoms are arranged in a molecule and, in particular, shows which functional groups are present.

Hydrocarbon compound which contain a hydroxyl group and an alkoxy group is known as Hemiacetals. Hemiacetal can be prepared by the addition of alcohol to an aldehyde or ketone in the presence of an acid catalyst. Hemiacetals react with a second alcohol molecule to produce an acetal, which contains a carbon with two alkoxy groups –OR.

The process of hydrolysis of acetal exactly the reverse of acetal formation and in this reaction hemiacetal acts as the intermediate. The reaction is shown below,

(b)

Interpretation Introduction

Interpretation:

The structural formula for the product of hydrolysis of given acetal in aqueous HCl has to be drawn.

Concept Introduction:

The structural formula of a compound shows how the atoms are arranged in a molecule and, in particular, shows which functional groups are present.

Hydrocarbon compound which contain a hydroxyl group and an alkoxy group is known as Hemiacetals. Hemiacetal can be prepared by the addition of alcohol to an aldehyde or ketone in the presence of an acid catalyst. Hemiacetals react with a second alcohol molecule to produce an acetal, which contains a carbon with two alkoxy groups –OR.

The process of hydrolysis of acetal exactly the reverse of acetal formation and in this reaction hemiacetal acts as the intermediate. The reaction is shown below,

(c)

Interpretation Introduction

Interpretation:

The structural formula for the product of hydrolysis of given acetal in aqueous HCl has to be drawn.

Concept Introduction:

The structural formula of a compound shows how the atoms are arranged in a molecule and, in particular, shows which functional groups are present.

Hydrocarbon compound which contain a hydroxyl group and an alkoxy group is known as Hemiacetals. Hemiacetal can be prepared by the addition of alcohol to an aldehyde or ketone in the presence of an acid catalyst. Hemiacetals react with a second alcohol molecule to produce an acetal, which contains a carbon with two alkoxy groups –OR.

The process of hydrolysis of acetal exactly the reverse of acetal formation and in this reaction hemiacetal acts as the intermediate. The reaction is shown below,

Answer 6

Chapter 16, Problem 16.31P

(a)

Interpretation Introduction

Interpretation:

The structural formula for the product of hydrolysis of given acetal in aqueous HCl has to be drawn.

Concept Introduction:

The structural formula of a compound shows how the atoms are arranged in a molecule and, in particular, shows which functional groups are present.

Hydrocarbon compound which contain a hydroxyl group and an alkoxy group is known as Hemiacetals. Hemiacetal can be prepared by the addition of alcohol to an aldehyde or ketone in the presence of an acid catalyst. Hemiacetals react with a second alcohol molecule to produce an acetal, which contains a carbon with two alkoxy groups –OR.

The process of hydrolysis of acetal exactly the reverse of acetal formation and in this reaction hemiacetal acts as the intermediate. The reaction is shown below,

Answer 7

Chapter 16, Problem 16.31P

(a)

Interpretation Introduction

Interpretation:

The structural formula for the product of hydrolysis of given acetal in aqueous HCl has to be drawn.

Concept Introduction:

The structural formula of a compound shows how the atoms are arranged in a molecule and, in particular, shows which functional groups are present.

Hydrocarbon compound which contain a hydroxyl group and an alkoxy group is known as Hemiacetals. Hemiacetal can be prepared by the addition of alcohol to an aldehyde or ketone in the presence of an acid catalyst. Hemiacetals react with a second alcohol molecule to produce an acetal, which contains a carbon with two alkoxy groups –OR.

The process of hydrolysis of acetal exactly the reverse of acetal formation and in this reaction hemiacetal acts as the intermediate. The reaction is shown below,

Answer 8

(b)

Interpretation Introduction

Interpretation:

The structural formula for the product of hydrolysis of given acetal in aqueous HCl has to be drawn.

Concept Introduction:

The structural formula of a compound shows how the atoms are arranged in a molecule and, in particular, shows which functional groups are present.

Hydrocarbon compound which contain a hydroxyl group and an alkoxy group is known as Hemiacetals. Hemiacetal can be prepared by the addition of alcohol to an aldehyde or ketone in the presence of an acid catalyst. Hemiacetals react with a second alcohol molecule to produce an acetal, which contains a carbon with two alkoxy groups –OR.

The process of hydrolysis of acetal exactly the reverse of acetal formation and in this reaction hemiacetal acts as the intermediate. The reaction is shown below,

Answer 9

(b)

Interpretation Introduction

Interpretation:

The structural formula for the product of hydrolysis of given acetal in aqueous HCl has to be drawn.

Concept Introduction:

The structural formula of a compound shows how the atoms are arranged in a molecule and, in particular, shows which functional groups are present.

Hydrocarbon compound which contain a hydroxyl group and an alkoxy group is known as Hemiacetals. Hemiacetal can be prepared by the addition of alcohol to an aldehyde or ketone in the presence of an acid catalyst. Hemiacetals react with a second alcohol molecule to produce an acetal, which contains a carbon with two alkoxy groups –OR.

The process of hydrolysis of acetal exactly the reverse of acetal formation and in this reaction hemiacetal acts as the intermediate. The reaction is shown below,

Answer 10

(c)

Interpretation Introduction

Interpretation:

The structural formula for the product of hydrolysis of given acetal in aqueous HCl has to be drawn.

Concept Introduction:

The structural formula of a compound shows how the atoms are arranged in a molecule and, in particular, shows which functional groups are present.

Hydrocarbon compound which contain a hydroxyl group and an alkoxy group is known as Hemiacetals. Hemiacetal can be prepared by the addition of alcohol to an aldehyde or ketone in the presence of an acid catalyst. Hemiacetals react with a second alcohol molecule to produce an acetal, which contains a carbon with two alkoxy groups –OR.

The process of hydrolysis of acetal exactly the reverse of acetal formation and in this reaction hemiacetal acts as the intermediate. The reaction is shown below,

Answer 11

(c)

Interpretation Introduction

Interpretation:

The structural formula for the product of hydrolysis of given acetal in aqueous HCl has to be drawn.

Concept Introduction:

The structural formula of a compound shows how the atoms are arranged in a molecule and, in particular, shows which functional groups are present.

Hydrocarbon compound which contain a hydroxyl group and an alkoxy group is known as Hemiacetals. Hemiacetal can be prepared by the addition of alcohol to an aldehyde or ketone in the presence of an acid catalyst. Hemiacetals react with a second alcohol molecule to produce an acetal, which contains a carbon with two alkoxy groups –OR.

The process of hydrolysis of acetal exactly the reverse of acetal formation and in this reaction hemiacetal acts as the intermediate. The reaction is shown below,

Answer 12

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Answer 23

Ch. 16.1 - Write the IUPAC name for each compound. Specify...Ch. 16.1 - Write structural formulas for all aldehydes with...Ch. 16.1 - Write the IUPAC name for each compound.Ch. 16.5 - Prob. 16.4P Ch. 16.6 - Prob. 16.5P Ch. 16.7 - Prob. 16.6P Ch. 16.7 - Write a mechanism for the acid-catalyzed...Ch. 16.8 - Prob. 16.8P Ch. 16.8 - The given mechanism of transamination reaction is...Ch. 16.8 - The given mechanism of transamination reaction is...

Solution Summary: The author explains how the structural formula for the product of hydrolysis of given acetal in aqueous HCl has to be drawn.

Chapter 16 Solutions