EBK ORGANIC AND BIOLOGICAL CHEMISTRY
7th Edition
ISBN: 9780100547742
Author: STOKER
Publisher: YUZU
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Chapter 15.8, Problem 3QQ
Interpretation Introduction
Interpretation: To determine the reactant in the first step of the sulfate assimilation process.
Concept introduction: Sulfate assimilation is the process used for the production of hydrogen sulfide. The starting material for sulfate assimilation is sulfate ion. It is an oxidation-reduction process as the sulfur in sulfate ion is in oxidized form and in hydrogen sulfide it is present in the reduced form.
The conversion of sulfate ion to sulfide ion via sulfate assimilation occurs in 4 steps. These steps are as follows:
Step 1:
Step 2:
Step 3:
Step 4:
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Consider this step in a radical reaction:
Y
What type of step is this? Check all that apply.
Draw the products of the step on the right-hand side of the drawing area
below. If more than one set of products is possible, draw any set.
Also, draw the mechanism arrows on the left-hand side of the drawing
area to show how this happens.
ionization
propagation
initialization
passivation
none of the above
22.16 The following groups are ortho-para directors.
(a)
-C=CH₂
H
(d)
-Br
(b)
-NH2
(c)
-OCHS
Draw a contributing structure for the resonance-stabilized cation formed during elec-
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intermediate by further delocalizing its positive charge.
22.17 Predict the major product or products from treatment of each compound with
Cl₁/FeCl₂-
OH
(b)
NO2
CHO
22.18 How do you account for the fact that phenyl acetate is less reactive toward electro-
philic aromatic substitution than anisole?
Phenyl acetate
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CH
(d)
Chapter 15 Solutions
EBK ORGANIC AND BIOLOGICAL CHEMISTRY
Ch. 15.1 - Which of the following statements about dietary...Ch. 15.1 - Dietary protein materials as they leave the...Ch. 15.1 - Prob. 3QQCh. 15.1 - Which of the following is not a proteolytic...Ch. 15.2 - The dominant use for the amino acids of the amino...Ch. 15.2 - The most abundant amino acid in the amino acid...Ch. 15.2 - Prob. 3QQCh. 15.3 - The reactants in a transamination reaction are a....Ch. 15.3 - Prob. 2QQCh. 15.3 - Prob. 3QQ
Ch. 15.3 - Prob. 4QQCh. 15.3 - Prob. 5QQCh. 15.3 - Prob. 6QQCh. 15.4 - Prob. 1QQCh. 15.4 - Prob. 2QQCh. 15.4 - Prob. 3QQCh. 15.4 - Prob. 4QQCh. 15.4 - Prob. 5QQCh. 15.4 - In the urea cycle, the urea-producing step...Ch. 15.5 - Which of the following statements concerning the...Ch. 15.5 - Prob. 2QQCh. 15.5 - Which of the following statements concerning the...Ch. 15.5 - Prob. 4QQCh. 15.6 - Prob. 1QQCh. 15.6 - Prob. 2QQCh. 15.6 - Prob. 3QQCh. 15.7 - Prob. 1QQCh. 15.7 - Prob. 2QQCh. 15.7 - In the degradation of heme, which of the following...Ch. 15.7 - In the degradation of heme, the iron atom present...Ch. 15.8 - In degradation of the sulfur-containing amino acid...Ch. 15.8 - Prob. 2QQCh. 15.8 - Prob. 3QQCh. 15.8 - Prob. 4QQCh. 15.9 - Prob. 1QQCh. 15.9 - Prob. 2QQCh. 15.9 - Prob. 3QQCh. 15.10 - Transamination reactions require the cofactor PLP...Ch. 15.10 - Prob. 2QQCh. 15.10 - Prob. 3QQCh. 15 - Prob. 15.1EPCh. 15 - Indicate whether each of the following aspects of...Ch. 15 - Prob. 15.3EPCh. 15 - Prob. 15.4EPCh. 15 - Prob. 15.5EPCh. 15 - Prob. 15.6EPCh. 15 - Prob. 15.7EPCh. 15 - Prob. 15.8EPCh. 15 - Prob. 15.9EPCh. 15 - Prob. 15.10EPCh. 15 - Prob. 15.11EPCh. 15 - Prob. 15.12EPCh. 15 - Prob. 15.13EPCh. 15 - Indicate whether each of the following statements...Ch. 15 - Prob. 15.15EPCh. 15 - Prob. 15.16EPCh. 15 - Prob. 15.17EPCh. 15 - What are the four major uses for amino acids...Ch. 15 - With the help of Table 26-1, classify each of the...Ch. 15 - Prob. 15.20EPCh. 15 - Prob. 15.21EPCh. 15 - Prob. 15.22EPCh. 15 - Prob. 15.23EPCh. 15 - Prob. 15.24EPCh. 15 - Prob. 15.25EPCh. 15 - Prob. 15.26EPCh. 15 - Prob. 15.27EPCh. 15 - Prob. 15.28EPCh. 15 - Prob. 15.29EPCh. 15 - Prob. 15.30EPCh. 15 - Prob. 15.31EPCh. 15 - Prob. 15.32EPCh. 15 - Prob. 15.33EPCh. 15 - Prob. 15.34EPCh. 15 - Prob. 15.35EPCh. 15 - Prob. 15.36EPCh. 15 - Prob. 15.37EPCh. 15 - Prob. 15.38EPCh. 15 - Prob. 15.39EPCh. 15 - Prob. 15.40EPCh. 15 - Prob. 15.41EPCh. 15 - Prob. 15.42EPCh. 15 - Draw the structure of the -keto acid produced from...Ch. 15 - Draw the structure of the -keto acid produced from...Ch. 15 - Prob. 15.45EPCh. 15 - Prob. 15.46EPCh. 15 - Prob. 15.47EPCh. 15 - Prob. 15.48EPCh. 15 - Prob. 15.49EPCh. 15 - Prob. 15.50EPCh. 15 - Prob. 15.51EPCh. 15 - Prob. 15.52EPCh. 15 - Prob. 15.53EPCh. 15 - Prob. 15.54EPCh. 15 - What is a carbamoyl group?Ch. 15 - Prob. 15.56EPCh. 15 - Prob. 15.57EPCh. 15 - Prob. 15.58EPCh. 15 - Prob. 15.59EPCh. 15 - Prob. 15.60EPCh. 15 - Prob. 15.61EPCh. 15 - Prob. 15.62EPCh. 15 - Prob. 15.63EPCh. 15 - Prob. 15.64EPCh. 15 - Prob. 15.65EPCh. 15 - Prob. 15.66EPCh. 15 - Prob. 15.67EPCh. 15 - Prob. 15.68EPCh. 15 - Prob. 15.69EPCh. 15 - Prob. 15.70EPCh. 15 - Prob. 15.71EPCh. 15 - Prob. 15.72EPCh. 15 - Prob. 15.73EPCh. 15 - Prob. 15.74EPCh. 15 - Prob. 15.75EPCh. 15 - Prob. 15.76EPCh. 15 - Prob. 15.77EPCh. 15 - Prob. 15.78EPCh. 15 - Prob. 15.79EPCh. 15 - Prob. 15.80EPCh. 15 - Prob. 15.81EPCh. 15 - Prob. 15.82EPCh. 15 - Prob. 15.83EPCh. 15 - Prob. 15.84EPCh. 15 - Prob. 15.85EPCh. 15 - Prob. 15.86EPCh. 15 - Prob. 15.87EPCh. 15 - What is the starting material for the biosynthesis...Ch. 15 - Prob. 15.89EPCh. 15 - Prob. 15.90EPCh. 15 - Prob. 15.91EPCh. 15 - Prob. 15.92EPCh. 15 - Prob. 15.93EPCh. 15 - What are the structural differences between...Ch. 15 - Prob. 15.95EPCh. 15 - Prob. 15.96EPCh. 15 - Which bile pigment is responsible for the yellow...Ch. 15 - Prob. 15.98EPCh. 15 - Prob. 15.99EPCh. 15 - Prob. 15.100EPCh. 15 - Prob. 15.101EPCh. 15 - Prob. 15.102EPCh. 15 - Prob. 15.103EPCh. 15 - Prob. 15.104EPCh. 15 - Prob. 15.105EPCh. 15 - Indicate whether each of the following statements...Ch. 15 - Prob. 15.107EPCh. 15 - Prob. 15.108EPCh. 15 - Prob. 15.109EPCh. 15 - Prob. 15.110EPCh. 15 - Prob. 15.111EPCh. 15 - Prob. 15.112EPCh. 15 - Prob. 15.113EPCh. 15 - Prob. 15.114EPCh. 15 - Prob. 15.115EPCh. 15 - Prob. 15.116EP
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