To write the mechanism for an uncatalyzed hydrolysis of methyl propionate. Concept introduction: The hydrolysis reaction of etser is the reaction in which the breaking of ester bond is done by using water molecule. The product obtained after the ester hydrolysis is the corresponding carboxylic acid . The hydrolysis reaction can be done in the presence of an acid or base to increase the rate of reaction . When this process occurs in presence of acid it is known as acid hydrolysis of ester and in presence of base it is known as base hydrolysis of ester. The general reaction of an ester to produce in presence of only water is written as,

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Answer 1

Question

Chapter 15.7, Problem 17P

(a)

Interpretation Introduction

Interpretation:

To write the mechanism for an uncatalyzed hydrolysis of methyl propionate.

Concept introduction:

The hydrolysis reaction of etser is the reaction in which the breaking of ester bond is done by using water molecule. The product obtained after the ester hydrolysis is the corresponding carboxylic acid. The hydrolysis reaction can be done in the presence of an acid or base to increase the rate of reaction. When this process occurs in presence of acid it is known as acid hydrolysis of ester and in presence of base it is known as base hydrolysis of ester.

The general reaction of an ester to produce in presence of only water is written as,

(b)

Interpretation Introduction

Interpretation:

To write the mechanism for aminolysis of phenyl formate using methyl amine.

Concept introduction:

The reaction of a carboxylic acid derivative with ammonia, primary and secondary amines gives an amide this reaction is known as aminolysis reaction. This reaction involves two equivalent of ammonia or amine molecule.

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9 7 8 C 9 8 200 190 B 5 A -197.72 9 8 7 15 4 3 0: ང་ 200 190 180 147.52 134.98 170 160 150 140 130 120 110 100 90 90 OH 10 4 3 1 2 -143.04 140. 180 170 160 150 140 130 120 110 100 90 CI 3 5 1 2 141.89 140.07 200 190 180 170 160 150 140 130 120 110 100 ៖- 90 129. 126.25 80 70 60 -60 50 40 10 125.19 -129.21 80 70 3.0 20 20 -8 60 50 10 ppm -20 40 128.31 80 80 70 60 50 40 40 -70.27 3.0 20 10 ppm 00˚0-- 77.17 30 20 20 -45.36 10 ppm -0.00 26.48 22.32 ―30.10 ―-0.00

Assign all the carbons

C 5 4 3 CI 2 the Righ B A 5 4 3 The Lich. OH 10 4 5 3 1 LOOP- -147.52 T 77.17 -45.36 200 190 180 170 160 150 140 130 120 110 100 90 80 70 60 50 40 30 20 10 ppm B -126.25 77.03 200 190 180 170 160 150 140 130 120 110 100 90 80 70 60 50 40 30 20 10 ppm 200 190 180 170 160 150 140 130 120 110 100 90 80 TO LL <-50.00 70 60 50 40 30 20 10 ppm 45.06 30.18 -26.45 22.36 --0.00 45.07 7.5 1.93 2.05 -30.24 -22.36 C A 7 8 5 ° 4 3 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0 ppm 9 8 5 4 3 ཡི་ OH 10 2 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 5 4 3 2 that th 7 I 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 115 2.21 4.00 1.0 ppm 6.96 2.76 5.01 1.0 ppm 6.30 1.00

Answer 2

Question

Chapter 15.7, Problem 17P

(a)

Interpretation Introduction

Interpretation:

To write the mechanism for an uncatalyzed hydrolysis of methyl propionate.

Concept introduction:

The hydrolysis reaction of etser is the reaction in which the breaking of ester bond is done by using water molecule. The product obtained after the ester hydrolysis is the corresponding carboxylic acid. The hydrolysis reaction can be done in the presence of an acid or base to increase the rate of reaction. When this process occurs in presence of acid it is known as acid hydrolysis of ester and in presence of base it is known as base hydrolysis of ester.

The general reaction of an ester to produce in presence of only water is written as,

(b)

Interpretation Introduction

Interpretation:

To write the mechanism for aminolysis of phenyl formate using methyl amine.

Concept introduction:

The reaction of a carboxylic acid derivative with ammonia, primary and secondary amines gives an amide this reaction is known as aminolysis reaction. This reaction involves two equivalent of ammonia or amine molecule.

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Answer 3

Question

Chapter 15.7, Problem 17P

(a)

Interpretation Introduction

Interpretation:

To write the mechanism for an uncatalyzed hydrolysis of methyl propionate.

Concept introduction:

The hydrolysis reaction of etser is the reaction in which the breaking of ester bond is done by using water molecule. The product obtained after the ester hydrolysis is the corresponding carboxylic acid. The hydrolysis reaction can be done in the presence of an acid or base to increase the rate of reaction. When this process occurs in presence of acid it is known as acid hydrolysis of ester and in presence of base it is known as base hydrolysis of ester.

The general reaction of an ester to produce in presence of only water is written as,

(b)

Interpretation Introduction

Interpretation:

To write the mechanism for aminolysis of phenyl formate using methyl amine.

Concept introduction:

The reaction of a carboxylic acid derivative with ammonia, primary and secondary amines gives an amide this reaction is known as aminolysis reaction. This reaction involves two equivalent of ammonia or amine molecule.

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Answer 4

Question

Chapter 15.7, Problem 17P

(a)

Interpretation Introduction

Interpretation:

To write the mechanism for an uncatalyzed hydrolysis of methyl propionate.

Concept introduction:

The hydrolysis reaction of etser is the reaction in which the breaking of ester bond is done by using water molecule. The product obtained after the ester hydrolysis is the corresponding carboxylic acid. The hydrolysis reaction can be done in the presence of an acid or base to increase the rate of reaction. When this process occurs in presence of acid it is known as acid hydrolysis of ester and in presence of base it is known as base hydrolysis of ester.

The general reaction of an ester to produce in presence of only water is written as,

(b)

Interpretation Introduction

Interpretation:

To write the mechanism for aminolysis of phenyl formate using methyl amine.

Concept introduction:

The reaction of a carboxylic acid derivative with ammonia, primary and secondary amines gives an amide this reaction is known as aminolysis reaction. This reaction involves two equivalent of ammonia or amine molecule.

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Answer 5

Chapter 15.7, Problem 17P

(a)

Interpretation Introduction

Interpretation:

To write the mechanism for an uncatalyzed hydrolysis of methyl propionate.

Concept introduction:

The hydrolysis reaction of etser is the reaction in which the breaking of ester bond is done by using water molecule. The product obtained after the ester hydrolysis is the corresponding carboxylic acid. The hydrolysis reaction can be done in the presence of an acid or base to increase the rate of reaction. When this process occurs in presence of acid it is known as acid hydrolysis of ester and in presence of base it is known as base hydrolysis of ester.

The general reaction of an ester to produce in presence of only water is written as,

(b)

Interpretation Introduction

Interpretation:

To write the mechanism for aminolysis of phenyl formate using methyl amine.

Concept introduction:

The reaction of a carboxylic acid derivative with ammonia, primary and secondary amines gives an amide this reaction is known as aminolysis reaction. This reaction involves two equivalent of ammonia or amine molecule.

Answer 6

Chapter 15.7, Problem 17P

(a)

Interpretation Introduction

Interpretation:

To write the mechanism for an uncatalyzed hydrolysis of methyl propionate.

Concept introduction:

The hydrolysis reaction of etser is the reaction in which the breaking of ester bond is done by using water molecule. The product obtained after the ester hydrolysis is the corresponding carboxylic acid. The hydrolysis reaction can be done in the presence of an acid or base to increase the rate of reaction. When this process occurs in presence of acid it is known as acid hydrolysis of ester and in presence of base it is known as base hydrolysis of ester.

The general reaction of an ester to produce in presence of only water is written as,

Answer 7

Chapter 15.7, Problem 17P

(a)

Interpretation Introduction

Interpretation:

To write the mechanism for an uncatalyzed hydrolysis of methyl propionate.

Concept introduction:

The hydrolysis reaction of etser is the reaction in which the breaking of ester bond is done by using water molecule. The product obtained after the ester hydrolysis is the corresponding carboxylic acid. The hydrolysis reaction can be done in the presence of an acid or base to increase the rate of reaction. When this process occurs in presence of acid it is known as acid hydrolysis of ester and in presence of base it is known as base hydrolysis of ester.

The general reaction of an ester to produce in presence of only water is written as,

Answer 8

(b)

Interpretation Introduction

Interpretation:

To write the mechanism for aminolysis of phenyl formate using methyl amine.

Concept introduction:

The reaction of a carboxylic acid derivative with ammonia, primary and secondary amines gives an amide this reaction is known as aminolysis reaction. This reaction involves two equivalent of ammonia or amine molecule.

Answer 9

(b)

Interpretation Introduction

Interpretation:

To write the mechanism for aminolysis of phenyl formate using methyl amine.

Concept introduction:

The reaction of a carboxylic acid derivative with ammonia, primary and secondary amines gives an amide this reaction is known as aminolysis reaction. This reaction involves two equivalent of ammonia or amine molecule.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 15.1 - The aromas of many flowers and fruits are due to...Ch. 15.1 - Name the following:Ch. 15.1 - Prob. 3P Ch. 15.2 - Which is longer, the carbon-oxygen single bond in...Ch. 15.2 - There are three carbon-oxygen bonds in methyl...Ch. 15.2 - Prob. 6P Ch. 15.4 - a. What is the product of the reaction of acetyl...Ch. 15.4 - What is the product of an acyl substitution...Ch. 15.5 - a. Which compound has the stretching vibration for...Ch. 15.5 - Using the pKa values listed in Table 15.1, predict...

Solution Summary: The author explains the mechanism for an uncatalyzed hydrolysis of methyl propionate.

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