Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Concept explainers
Textbook Question
Chapter 15.5, Problem 15.10CE
Consider 0.0010-M solutions of these sparingly soluble solutes in equilibrium with their ions. Predict the effect on each equilibrium if a saturated solution of sodium iodide were added. Explain your prediction in each case.
AgI(s) ⇌ Ag+(aq) + I−(aq)
PbI2(s) ⇌ Pb2+(aq) + 2 I−(aq)
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
Predict the effect of adding HCL aqueous to the equilibrium reaction 
A buffer solution is prepared in such a way that the concentration of propanoic acid is
8.0 × 10−1 M and the concentration of sodium propanoate is 8.4 ×10−1 M.
The buffer equilibrium is described by
C2H5COOH(aq)
+
H2O(l)
⇌
H3O+(aq)
+
C2H5COO−(aq)
propanoic acid
proponate ion
with Ka = 1.34 ×10−5
. If the concentration of the sodium propanoate were doubled while the acid concentration remained the same, calculate the pH of the resulting solution.
A 1.034-g sample of impure oxalic acid is dissolved in water and an acid-base indicator added. The sample requires 34.47 mL of 0.485 M NaOH to reach the equivalence point. What is the mass of oxalic acid and what is its mass percent in the sample?H2C2O4(aq) + 2NaOH(aq) ⇌ Na2C2O4(aq) + 2H2O(l)
Chapter 15 Solutions
Chemistry: The Molecular Science
Ch. 15.1 - Predict whether 1.0 L of each solution is a...Ch. 15.1 - Calculate the pH of blood containing 0.0020-M...Ch. 15.1 - Prob. 15.2ECh. 15.1 -
Calculate the ratio of [] to [] in blood at a...Ch. 15.1 - Use the data in Table 15.1 to select a conjugate...Ch. 15.1 -
Calculate the mole ratio of sodium acetate and...Ch. 15.1 - Calculate the pH of these buffers.
Ch. 15.1 - If an abnormally high CO2 concentration is present...Ch. 15.1 - Calculate the minimum mass (g) of KOH that would...Ch. 15.2 - For the titration of 50.0 mL of 0.100-M HCl with...
Ch. 15.2 - Draw the titration curve for the titration of 50.0...Ch. 15.2 - Use the Ka expression and value for acetic acid to...Ch. 15.2 - Explain why the curve for the titration of acetic...Ch. 15.4 - Write the Ksp expression for each of these...Ch. 15.4 - The Ksp of AgBr at 100 C is 5 1010. Calculate the...Ch. 15.4 - A saturated solution of silver oxalate. Ag2C2O4....Ch. 15.4 - Prob. 15.9CECh. 15.5 - Consider 0.0010-M solutions of these sparingly...Ch. 15.5 - Prob. 15.11PSPCh. 15.5 - Calculate the solubility of PbCl2 in (a) pure...Ch. 15.5 - Prob. 15.13PSPCh. 15.6 - (a) Determine whether AgCl precipitates from a...Ch. 15.6 - Prob. 15.15PSPCh. 15 - Prob. 1SPCh. 15 - Choose a weak-acid/weak-base conjugate pair from...Ch. 15 - Prob. 4SPCh. 15 - Define the term buffer capacity.Ch. 15 - What is the difference between the end point and...Ch. 15 - What are the characteristics of a good acid-base...Ch. 15 - A strong acid is titrated with a strong base, such...Ch. 15 - Repeat the description for Question 4, but use a...Ch. 15 - Use Le Chatelier’s principle to explain why PbCl2...Ch. 15 - Describe what a complex ion is and give an...Ch. 15 - Define the term “amphoteric”.
Ch. 15 - Distinguish between the ion product (Q) expression...Ch. 15 - Describe at least two ways that the solubility of...Ch. 15 - Briefly describe how a buffer solution can control...Ch. 15 - Identify each pair that could form a buffer. (a)...Ch. 15 - Identify each pair that could form a buffer. (a)...Ch. 15 - Many natural processes can be studied in the...Ch. 15 - Which of these combinations is the best to buffer...Ch. 15 - Without doing calculations, determine the pH of a...Ch. 15 - Without doing calculations, determine the pH of a...Ch. 15 - Select from Table 15.1 a conjugate acid-base pair...Ch. 15 - Select from Table 15.1 a conjugate acid-base pair...Ch. 15 - Calculate the mass of sodium acetate, NaCH3COO,...Ch. 15 - Calculate the mass in grams of ammonium chloride,...Ch. 15 - A buffer solution can be made from benzoic acid,...Ch. 15 - A buffer solution is prepared from 5.15 g NH4NO3...Ch. 15 - You dissolve 0.425 g NaOH in 2.00 L of a solution...Ch. 15 - A buffer solution is prepared by adding 0.125 mol...Ch. 15 - If added to 1 L of 0.20-M acetic acid, CH3COOH,...Ch. 15 - If added to 1 L of 0.20-M NaOH, which of these...Ch. 15 - Calculate the pH change when 10.0 mL of 0.100-M...Ch. 15 - Prob. 29QRTCh. 15 - Prob. 30QRTCh. 15 - Prob. 31QRTCh. 15 - The titration curves for two acids with the same...Ch. 15 - Explain why it is that the weaker the acid being...Ch. 15 - Prob. 34QRTCh. 15 - Consider all acid-base indicators discussed in...Ch. 15 - Which of the acid-base indicators discussed in...Ch. 15 - It required 22.6 mL of 0.0140-M Ba(OH)2 solution...Ch. 15 - It took 12.4 mL of 0.205-M H2SO4 solution to...Ch. 15 - Vitamin C is a monoprotic acid. To analyze a...Ch. 15 - An acid-base titration was used to find the...Ch. 15 - Calculate the volume of 0.150-M HCl required to...Ch. 15 - Calculate the volume of 0.225-M NaOH required to...Ch. 15 - Prob. 43QRTCh. 15 - Prob. 44QRTCh. 15 - Prob. 45QRTCh. 15 - Explain why rain with a pH of 6.7 is not...Ch. 15 - Identify two oxides that are key producers of acid...Ch. 15 - Prob. 48QRTCh. 15 - Prob. 49QRTCh. 15 - Prob. 50QRTCh. 15 - Prob. 51QRTCh. 15 - A saturated solution of silver arsenate, Ag3AsO4,...Ch. 15 - Prob. 53QRTCh. 15 - Prob. 54QRTCh. 15 - Prob. 55QRTCh. 15 - Prob. 56QRTCh. 15 - Prob. 57QRTCh. 15 - Prob. 58QRTCh. 15 - Prob. 59QRTCh. 15 - Prob. 60QRTCh. 15 - Prob. 61QRTCh. 15 - Prob. 62QRTCh. 15 - Prob. 63QRTCh. 15 - Prob. 64QRTCh. 15 - Predict what effect each would have on this...Ch. 15 - Prob. 66QRTCh. 15 - Prob. 67QRTCh. 15 - The solubility of Mg(OH)2 in water is...Ch. 15 - Prob. 69QRTCh. 15 - Prob. 70QRTCh. 15 - Prob. 71QRTCh. 15 - Prob. 72QRTCh. 15 - Write the chemical equation for the formation of...Ch. 15 - Prob. 74QRTCh. 15 - Prob. 75QRTCh. 15 - Prob. 76QRTCh. 15 - Prob. 77QRTCh. 15 - Prob. 78QRTCh. 15 - Prob. 79QRTCh. 15 - Prob. 80QRTCh. 15 - Prob. 81QRTCh. 15 - Solid sodium fluoride is slowly added to an...Ch. 15 - Prob. 83QRTCh. 15 - Prob. 84QRTCh. 15 - A buffer solution was prepared by adding 4.95 g...Ch. 15 - Prob. 86QRTCh. 15 - Prob. 87QRTCh. 15 - Prob. 88QRTCh. 15 - Prob. 89QRTCh. 15 - Which of these buffers involving a weak acid HA...Ch. 15 - Prob. 91QRTCh. 15 - Prob. 92QRTCh. 15 - When 40.00 mL of a weak monoprotic acid solution...Ch. 15 - Each of the solutions in the table has the same...Ch. 15 - Prob. 95QRTCh. 15 - Prob. 97QRTCh. 15 - The average normal concentration of Ca2+ in urine...Ch. 15 - Explain why even though an aqueous acetic acid...Ch. 15 - Prob. 100QRTCh. 15 - Prob. 101QRTCh. 15 - Prob. 102QRTCh. 15 - Prob. 103QRTCh. 15 - Prob. 104QRTCh. 15 - Apatite, Ca5(PO4)3OH, is the mineral in teeth.
On...Ch. 15 - Calculate the maximum concentration of Mg2+...Ch. 15 - Prob. 107QRTCh. 15 - Prob. 108QRTCh. 15 - The grid has six lettered boxes, each of which...Ch. 15 - Consider the nanoscale-level representations for...Ch. 15 - Consider the nanoscale-level representations for...Ch. 15 - Prob. 112QRTCh. 15 - Prob. 113QRTCh. 15 - Prob. 114QRTCh. 15 - Prob. 115QRTCh. 15 - You want to prepare a pH 4.50 buffer using sodium...Ch. 15 - Prob. 117QRTCh. 15 - Prob. 118QRTCh. 15 - Prob. 119QRTCh. 15 - Prob. 120QRTCh. 15 - Prob. 121QRTCh. 15 - Prob. 122QRTCh. 15 - You are given four different aqueous solutions and...Ch. 15 - Prob. 124QRTCh. 15 - Prob. 126QRTCh. 15 - Prob. 15.ACPCh. 15 - Prob. 15.BCP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Phosphate ions are abundant in cells, both as the ions themselves and as important substituents on organic molecules. Most importantly, the pKa for the H2PO4 ion is 7.20, which is very close to the normal pH in the body. H2PO4(aq) + H2O() H3O+(aq) + HPO42(aq) 1. What should the ratio [HPO42]/[H2PO4] be to control the pH at 7.40?arrow_forwardThe simplest amino acid is glycine, H2NCH2CO2H. The common feature of amino acids is that they contain the functional groups: an amine group, -NH2, and a carboxylic acid group, -CO2H. An amino acid can function as either an acid or a base. For glycine, the acid strength of the carboxyl group is about the same as that of acetic acid. CH3CO2H, and the base strength of the amino group is slightly greater than that of ammonia, NH3. (a) Write the Lewis structures of the ions that form when glycine is dissolved in 1 M HCl and in 1 M KOH. (b) Write the Lewis structure of glycine when this amino acid is dissolved in water. (Hint: Consider the relative base strengths of the -NH2 and -CO2- groups.)arrow_forwardCalculate the molar solubility of the sparingly soluble salt AB for which Ksp = 5.16 × 10–10. Provide your answer to seven decimal places and without units. Note the following: AB(s) ⇌ A+(aq) + B−(aq)arrow_forward
- Can you solve the question in the picture shown?arrow_forwardEqual quantities of 0.010M solutions of an acid HA and a base B are mixed. The pH of the resulting solution is 9.4 Part A:Write the equilibrium equation for the reaction between HA and B. Express your answer as a chemical equation. Identify all of the phases in your answer. Part B: Write equilibrium-constant expression for the reaction between HA and B. Part C: If Ka for HA is 8.0×10−5, what is the value of the equilibrium constant for the reaction between HA and B? Express your answer using one significant figure. Part D: What is the value of Kb for B? Express your answer using one significant figure.arrow_forward1) Write the equilibrium constant expression for the dissociation of acetic acid 2) Vinegar sold commercially is typically 0.8−1.0 M acetic acid. A 1.00 M solution of acetic acid is measured by its pH to have an equilibrium concentration of 4.19×10−3 M for both acetate ions and hydronium ions at room temperature. Assuming [HOAc]0 = 1.00 M, what is the equilibrium concentration of undissociated acetic acid [HOAc]eq to the correct number of significant figures? 3) What is the value of the equilibrium constant Keq for the dissociation according to the concentrations from number 2?arrow_forward
- Write the equilibrium expression for the reaction Zn2+(aq) + 2 NH3(aq) <--> Zn(NH3)2+(aq)arrow_forwardThe equilibrium constant for the reaction Hg2+(aq) + 2Cl−(aq) ⇌ HgCl2(aq) is 1.6 × 1013. Is HgCl2 a strong electrolyte or a weak electrolyte? What are the concentrations of Hg2+ and Cl– in a 0.015-M solution of HgCl2?arrow_forwardCu2+(aq) + H2O(l) ⇌ CuOH+(aq) + H+(aq) Keq = 1.2 x 10−8 A 1.00 M solution of copper(II) nitrate is created and the system shown above reaches equilibrium. What happens to the pH of the system if more CuOH+ is added after reaching equilibrium? The pH of the system will not change because of the small size of K. The pH of the system will increase because of the increased concentration of CuOH+. The pH of the system will increase as the reverse reaction proceeds at a faster rate to reestablish equilibrium. The pH of the system will decrease as the forward reaction proceeds at a faster rate to reestablish equilibrium.arrow_forward
- B represents an acid-base indicator and behaves like a base. Its dissociation equilibrium in an aqueous solution can be written as: B(ac) + H2O(l) <-> +BH(ac) + OH(ac) If B (ac) is yellow +BH is red. Using Le Châtelier's principle, predict the color of the indicator by adding a few drops of the indicator to an aqueous solution of HCl and an aqueous solution of NaOH. Write the corresponding chemical reactions.arrow_forwardBromothymol blue is yellow in acid solutions. HBB is acidic form of the indicator . The indicator is blue in basic solutions. BB- is basic form of the indicator. HBB + H2O H3O+ + BB- In this case, HBB is an acidic form of the indicator. BB- is the basic form of the indicator. The acidic form is yellow in color and the basic form is the blue color. (a) Predict what will happen if NaOH is added to the reaction system. explain why ? make sure to explain why?arrow_forward1) Write the equilibrium constant expression for the following reaction. CaO(S) + 2HCl (aq) <=>CaCl2 (aq) + H2O(l) 2) At 90 C , Kw is about 10-13, what is the pH under these conditions? 3. Will an aqueous solution of NaCl be acidic, neutral or basic?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStaxChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:OpenStax
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
General Chemistry | Acids & Bases; Author: Ninja Nerd;https://www.youtube.com/watch?v=AOr_5tbgfQ0;License: Standard YouTube License, CC-BY