Chemistry: An Atoms First Approach
2nd Edition
ISBN: 9781305079243
Author: Steven S. Zumdahl, Susan A. Zumdahl
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Textbook Question
Chapter 15, Problem 50E
A solution contains 1.0 × 10−5 M Ag+ and 2.0 × 10−6 M CN−. Will AgCN(s) precipitate? (Ksp for AgCN(s) is 2.2 × 10−12.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
An analytical chemist has been given the task of precipitating lead cation (Pb2+) out of solution that is 0.424 M in Pb2+ . At her disposal is a large bottle of solid sodium iodide (NaI). What must the concentration of iodide be for precipitation to begin? (The Ksp of lead iodide is 9.8 x 10-9).
At what pH will Fe(OH)₃(s) begin to precipitate from 4.45 × 10⁻³ M FeCl₃? Ksp for Fe(OH)₃ is 2.79 × 10⁻³⁹.
#12
Chapter 15 Solutions
Chemistry: An Atoms First Approach
Ch. 15 - To what reaction does the solubility product...Ch. 15 - Prob. 2RQCh. 15 - Prob. 3RQCh. 15 - Prob. 4RQCh. 15 - Prob. 5RQCh. 15 - Prob. 6RQCh. 15 - Prob. 7RQCh. 15 - Prob. 8RQCh. 15 - Prob. 9RQCh. 15 - Prob. 10RQ
Ch. 15 - Prob. 1ALQCh. 15 - Prob. 2ALQCh. 15 - Prob. 3ALQCh. 15 - A friend tells you: The constant Ksp of a salt is...Ch. 15 - Prob. 5ALQCh. 15 - Prob. 6ALQCh. 15 - Prob. 7ALQCh. 15 - For which of the following is the Ksp value of the...Ch. 15 - Ag2S(s) has a larger molar solubility than CuS...Ch. 15 - Prob. 10QCh. 15 - Prob. 11QCh. 15 - When Na3PO4(aq) is added to a solution containing...Ch. 15 - The common ion effect for ionic solids (salts) is...Ch. 15 - Prob. 14QCh. 15 - Prob. 15QCh. 15 - The stepwise formation constants for a complex ion...Ch. 15 - Prob. 17QCh. 15 - Prob. 18QCh. 15 - Write balanced equations for the dissolution...Ch. 15 - Write balanced equations for the dissolution...Ch. 15 - Prob. 21ECh. 15 - Use the following data to calculate the Ksp value...Ch. 15 - Approximately 0.14 g nickel(II) hydroxide,...Ch. 15 - The solubility of the ionic compound M2X3, having...Ch. 15 - Prob. 25ECh. 15 - Prob. 26ECh. 15 - Calculate the solubility of each of the following...Ch. 15 - Prob. 28ECh. 15 - Cream of tartar, a common ingredient in cooking,...Ch. 15 - Prob. 30ECh. 15 - Prob. 31ECh. 15 - Calculate the molar solubility of Cd(OH)2, Ksp =...Ch. 15 - Calculate the molar solubility of Al(OH)3, Ksp = 2...Ch. 15 - Calculate the molar solubility of Co(OH)3, Ksp =...Ch. 15 - Prob. 35ECh. 15 - For each of the following pairs of solids,...Ch. 15 - Calculate the solubility (in moles per liter) of...Ch. 15 - Calculate the solubility of Co(OH)2(s) (Ksp = 2.5 ...Ch. 15 - The Ksp for silver sulfate (Ag2SO4) is 1.2 105....Ch. 15 - Prob. 40ECh. 15 - Prob. 41ECh. 15 - Prob. 42ECh. 15 - Prob. 43ECh. 15 - The solubility of Pb(IO3)(s) in a 0.10-M KIO3...Ch. 15 - Prob. 45ECh. 15 - For which salt in each of the following groups...Ch. 15 - What mass of ZnS (Ksp = 2.5 1022) will dissolve...Ch. 15 - The concentration of Mg2+ in seawater is 0.052 M....Ch. 15 - Will a precipitate form when 100.0 mL of 4.0 104...Ch. 15 - A solution contains 1.0 105 M Ag+ and 2.0 106 M...Ch. 15 - A solution is prepared by mixing 100.0 mL of 1.0 ...Ch. 15 - Prob. 52ECh. 15 - Calculate the final concentrations of K+(aq),...Ch. 15 - Prob. 54ECh. 15 - A 50.0-mL sample of 0.00200 M AgNO3 is added to...Ch. 15 - Prob. 56ECh. 15 - A solution contains 1.0 105 M Na3PO4. What is the...Ch. 15 - The Ksp of Al(OH)3 is 2 1032. At what pH will a...Ch. 15 - A solution is 1 104 M in NaF, Na2S, and Na3PO4....Ch. 15 - A solution contains 0.25 M Ni(NO3)2 and 0.25 M...Ch. 15 - Write equations for the stepwise formation of each...Ch. 15 - Write equations for the stepwise formation of each...Ch. 15 - In the presence of CN, Fe3+ forms the complex ion...Ch. 15 - In the presence of NH3, Cu2+ forms the complex ion...Ch. 15 - Prob. 65ECh. 15 - Prob. 66ECh. 15 - The overall formation constant for HgI42 is 1.0 ...Ch. 15 - Prob. 68ECh. 15 - A solution is formed by mixing 50.0 mL of 10.0 M...Ch. 15 - A solution is prepared by mixing 100.0 mL of 1.0 ...Ch. 15 - a. Calculate the molar solubility of AgI in pure...Ch. 15 - Solutions of sodium thiosulfate are used to...Ch. 15 - Kf for the complex ion Ag(NH3)2+ is 1.7 107. Ksp...Ch. 15 - Prob. 74ECh. 15 - Prob. 75ECh. 15 - The solubility of copper(II) hydroxide in water...Ch. 15 - A solution contains 0.018 mole each of I, Br, and...Ch. 15 - Prob. 78AECh. 15 - Tooth enamel is composed of the mineral...Ch. 15 - Prob. 80AECh. 15 - What mass of Ca(NO3)2 must be added to 1.0 L of a...Ch. 15 - Calculate the mass of manganese hydroxide present...Ch. 15 - Prob. 83AECh. 15 - The active ingredient of Pepto-Bismol is the...Ch. 15 - Prob. 85AECh. 15 - The equilibrium constant for the following...Ch. 15 - Calculate the concentration of Pb2+ in each of the...Ch. 15 - Will a precipitate of Cd(OH)2 form if 1.0 mL of...Ch. 15 - Prob. 89AECh. 15 - Describe how you could separate the ions in each...Ch. 15 - Prob. 91AECh. 15 - Prob. 92AECh. 15 - Prob. 93CWPCh. 15 - Prob. 94CWPCh. 15 - Prob. 95CWPCh. 15 - The solubility of Pb(IO3)2(s) in a 7.2 102-M KIO3...Ch. 15 - A 50.0-mL sample of 0.0413 M AgNO3(aq) is added to...Ch. 15 - Prob. 98CWPCh. 15 - Prob. 99CPCh. 15 - Consider a solution made by mixing 500.0 mL of 4.0...Ch. 15 - a. Calculate the molar solubility of AgBr in pure...Ch. 15 - Prob. 102CPCh. 15 - Prob. 103CPCh. 15 - Calcium oxalate (CaC2O4) is relatively insoluble...Ch. 15 - What is the maximum possible concentration of Ni2+...Ch. 15 - A mixture contains 1.0 103 M Cu2+ and 1.0 103 M...Ch. 15 - Sodium tripolyphosphate (Na5P3O10) is used in many...Ch. 15 - You add an excess of solid MX in 250g water. You...Ch. 15 - a. Calculate the molar solubility of SrF2 in...Ch. 15 - Prob. 110IPCh. 15 - Prob. 111IPCh. 15 - Prob. 112IPCh. 15 - Aluminum ions react with the hydroxide ion to form...
Additional Science Textbook Solutions
Find more solutions based on key concepts
16.43 The following pictures represent solutions at various stages in thetitration of a weak diprotic acid with...
Chemistry (7th Edition)
Consider a sample of ideal gas initially in a volume V at temperature T and pressure P. Does the entropy of thi...
General Chemistry: Principles and Modern Applications (11th Edition)
The method to determine the volume of a powered solid, liquid and a rock needs to be determined. Concept introd...
Living by Chemistry
The method to determine the volume of a powered solid, liquid and a rock needs to be determined. Concept introd...
Living By Chemistry: First Edition Textbook
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Lead(II) chromate, PbCrO4, was used as a yellow paint pigment (chrome yellow). When a solution is prepared that is 5.0 104 M in lead ion, Pb2, and 5.0 105 M in chromate ion, CrO42, would you expect some of the lead(II) chromate to precipitate?arrow_forwardAn analytical chemist has a solution containing chloride ion, Cl. She decides to determine the amount of chloride ion in the solution by titrating 50.0 mL of this solution by 0.100 M AgNO3. As a way to indicate the endpoint of the titration, she added 1.00 g of potassium chromate, K2CrO4 (see Figure 17.5). As she slowly added the silver nitrate to the solution, a white precipitate formed. She continued the titration, with more white precipitate forming. Finally, the solution turned red, from another precipitate. The volume of the solution at this point was 60.3 mL. How many moles of chloride ion were there in the original solution? How many moles of chloride ion were there in the final solution? You may make any reasonable approximations.arrow_forwardHow do the concentrations of Ag+ and CrO42- in a saturated solution above 1.0 g of solid Ag2CrO4 Change when 100 g of solid Ag2CrO4 is added to the system? Explain.arrow_forward
- Marble is almost pure CaCO3. Acid rain has a devastating effect on marble statuary left outdoors. Assume that the reaction which occurs is CoCO3(s)+ H+(aq)Ca2+(aq)+HCO3(aq) Neglecting all other competing equilibria and using Tables 15.1 and 13.2, calculate (a) K for the reaction. (b) the molar solubility of CaCO3 in pure water. (c) the molar solubility of CaCO3 in acid rainwater with a pH of 4.00.arrow_forwardA 1.0-L solution that is 4.2 M in ammonia is mixed with 26.7 g of ammonium chloride. a What is the hydroxide-ion concentration of this solution? b 0.075 mol of MgCl2 is added to the above solution. Assume that there is no volume change. After Mg(OH)2 has precipitated, what is the molar concentration of magnesium ion? What percent of the Mg2+ is removed from solution?arrow_forwardA solution is 0.047 M in both NaF and Na2CO3. Solid strontium nitrate, Sr(NO3)2, is added without changing the volume of the solution. (a) Which salt, SrCO3 or SrF2(Ksp=4.3109), will precipitate first? (b) What is [Sr2+] when the salt in (a) first begins to precipitate?arrow_forward
- A solution is made up by adding 0.632 g of barium nitrate and 0.920 g of lanthanum nitrate, to La(NO3)3 enough water to make 0.500 L of solution. Solid sodium iodate, NalO3, is added (without volume change) to the solution. (a) Which salt will precipitate first? La(IO3)3 (Ksp=7.501012) or BAIO3 (Ksp=4.0109)? (b) What is [IO3-] when the salt in (a) first begins to precipitate?arrow_forwardA saturated solution of copper(II) iodate in pure water has a copper-ion concentration of 2.7 103 M. a What is the molar solubility of copper iodate in a 0.35 M potassium iodate solution? b What is the molar solubility of copper iodate in a 0.35 M copper nitrate solution? c Should there be a difference in the answers to parts a and b? Why?arrow_forwardA 3.20-L solution of 1.25 103 M Pb(NO3)2 is mixed with a 0.80-L solution of 5.0 101 M NaCl. Calculate Q for the dissolution of PbCl2. No precipitate has formed. Is the solution supersaturated, saturated, or unsaturated?arrow_forward
- How would the solubility of calcium fluoride be affected by the presence of fluoride ion from another source? What is the solubility of calcium fluoride in a saturated solution of barium fluoride? How does this compare with the value of the solubility of calcium fluoride found in Example 17.4? Is this what you expect?arrow_forwardSolid sodium fluoride is slowly added to an aqueous solution that contains 0.0100-M Pb2+ and 0.0100-M Ca2+. (a) Determine which precipitates first, calcium fluoride or lead(II) fluoride. (b) Calculate the percentage of Ca2+ or Pb2+ that has precipitated just prior to the precipitation of the compound that precipitates second.arrow_forwardWrite the chemical equation for the formation of each complex ion and write its formation constant expression, (a) [Ag(CN)2] (b) [Cd(NH3)4]2+arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStax
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:OpenStax
General Chemistry | Acids & Bases; Author: Ninja Nerd;https://www.youtube.com/watch?v=AOr_5tbgfQ0;License: Standard YouTube License, CC-BY