(a) Interpretation: The monochlorination product formed when given compound is heated with Cl 2 is to be drawn. Concept introduction: Halogens react with alkanes in the presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from C − H sigma bond of the alkane.

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Answer 1

Question

Chapter 15, Problem 15.15P

Interpretation Introduction

(a)

Interpretation:

The monochlorination product formed when given compound is heated with Cl2 is to be drawn.

Concept introduction:

Halogens react with alkanes in the presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(b)

Interpretation:

The monochlorination product formed when given compound is heated with Cl2 is to be drawn.

Concept introduction:

Halogens react with alkanes in the presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation:

The monochlorination product formed when given compound is heated with Cl2 is to be drawn.

Concept introduction:

Halogens react with alkanes in the presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(d)

Interpretation:

The monochlorination product formed when given compound is heated with Cl2 is to be drawn.

Concept introduction:

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

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Draw the eight constitutional isomers having the molecular formula C5H11Cl.a. Give the IUPAC name for each compound (ignoring R and S designations).b. Classify each alkyl halide as 1°, 2°, or 3°.c. Label any stereogenic centers.d. For each constitutional isomer that contains a stereogenic center, draw all possible stereoisomers, and label each stereogenic center as R or S.

Draw the eight constitutional isomers having the molecular formula C5H11Cl. a.Give the IUPAC name for each compound (ignoring R and S designations). b.Classify each alkyl halide as 1°, 2°, or 3°. c.Label any stereogenic centers. d.For each constitutional isomer that contains a stereogenic center, draw all possible stereoisomers, and label each stereogenic center as R or S.

Draw a structural formula for the major product of the reaction shown. -CH₂CH3 Br₂ H₂O • Show product stereochemistry IF the reactant alkene has both carbons of the double bond within a ring. • Do not show stereochemistry in other cases. • If the reaction produces a racemic mixture, just draw one stereoisomer.

Answer 2

Question

Chapter 15, Problem 15.15P

Interpretation Introduction

(a)

Interpretation:

The monochlorination product formed when given compound is heated with Cl2 is to be drawn.

Concept introduction:

Halogens react with alkanes in the presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(b)

Interpretation:

The monochlorination product formed when given compound is heated with Cl2 is to be drawn.

Concept introduction:

Halogens react with alkanes in the presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation:

The monochlorination product formed when given compound is heated with Cl2 is to be drawn.

Concept introduction:

Halogens react with alkanes in the presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(d)

Interpretation:

The monochlorination product formed when given compound is heated with Cl2 is to be drawn.

Concept introduction:

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

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Answer 3

Question

Chapter 15, Problem 15.15P

Interpretation Introduction

(a)

Interpretation:

The monochlorination product formed when given compound is heated with Cl2 is to be drawn.

Concept introduction:

Halogens react with alkanes in the presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(b)

Interpretation:

The monochlorination product formed when given compound is heated with Cl2 is to be drawn.

Concept introduction:

Halogens react with alkanes in the presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation:

The monochlorination product formed when given compound is heated with Cl2 is to be drawn.

Concept introduction:

Halogens react with alkanes in the presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(d)

Interpretation:

The monochlorination product formed when given compound is heated with Cl2 is to be drawn.

Concept introduction:

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

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Answer 4

Question

Chapter 15, Problem 15.15P

Interpretation Introduction

(a)

Interpretation:

The monochlorination product formed when given compound is heated with Cl2 is to be drawn.

Concept introduction:

Halogens react with alkanes in the presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(b)

Interpretation:

The monochlorination product formed when given compound is heated with Cl2 is to be drawn.

Concept introduction:

Halogens react with alkanes in the presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation:

The monochlorination product formed when given compound is heated with Cl2 is to be drawn.

Concept introduction:

Halogens react with alkanes in the presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(d)

Interpretation:

The monochlorination product formed when given compound is heated with Cl2 is to be drawn.

Concept introduction:

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

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Answer 5

Chapter 15, Problem 15.15P

Interpretation Introduction

(a)

Interpretation:

The monochlorination product formed when given compound is heated with Cl2 is to be drawn.

Concept introduction:

Halogens react with alkanes in the presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(b)

Interpretation:

The monochlorination product formed when given compound is heated with Cl2 is to be drawn.

Concept introduction:

Halogens react with alkanes in the presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(c)

Interpretation:

The monochlorination product formed when given compound is heated with Cl2 is to be drawn.

Concept introduction:

Halogens react with alkanes in the presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Interpretation Introduction

(d)

Interpretation:

The monochlorination product formed when given compound is heated with Cl2 is to be drawn.

Concept introduction:

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 6

Chapter 15, Problem 15.15P

Interpretation Introduction

(a)

Interpretation:

The monochlorination product formed when given compound is heated with Cl2 is to be drawn.

Concept introduction:

Halogens react with alkanes in the presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 7

Chapter 15, Problem 15.15P

Interpretation Introduction

(a)

Interpretation:

The monochlorination product formed when given compound is heated with Cl2 is to be drawn.

Concept introduction:

Halogens react with alkanes in the presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The monochlorination product formed when given compound is heated with Cl2 is to be drawn.

Concept introduction:

Halogens react with alkanes in the presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The monochlorination product formed when given compound is heated with Cl2 is to be drawn.

Concept introduction:

Halogens react with alkanes in the presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The monochlorination product formed when given compound is heated with Cl2 is to be drawn.

Concept introduction:

Halogens react with alkanes in the presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The monochlorination product formed when given compound is heated with Cl2 is to be drawn.

Concept introduction:

Halogens react with alkanes in the presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this reaction, the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The monochlorination product formed when given compound is heated with Cl2 is to be drawn.

Concept introduction:

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The monochlorination product formed when given compound is heated with Cl2 is to be drawn.

Concept introduction:

Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from C−H sigma bond of the alkane.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 15 - Prob. 15.1P Ch. 15 - Prob. 15.2P Ch. 15 - Draw the product formed when a chlorine atom (Cl)...Ch. 15 - Prob. 15.4P Ch. 15 - Prob. 15.5P Ch. 15 - Problem 15.6 Using mechanism 15.1 as guide, write...Ch. 15 - Calculate m0 for the two propagation steps in the...Ch. 15 - Prob. 15.8P Ch. 15 - Problem 15.8 Which bond in the each compound is...Ch. 15 - Prob. 15.10P

Solution Summary: The author explains that halogens react with alkanes in the presence of heat or light to form alkyl.

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Chapter 15 Solutions