(a) Interpretation: All resonance structures for the radical that result from the homolysis of OH bond are to be drawn. Concept introduction: The general steps followed by free-radical reaction are stated below: 1. First step is initiation that involves formation of radical. 2. Second step is propagation. 3. Third step is the termination that involves the formation of stable bond.

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Answer 1

Question

Chapter 15, Problem 15.69P

Interpretation Introduction

(a)

Interpretation: All resonance structures for the radical that result from the homolysis of OH bond are to be drawn.

Concept introduction: The general steps followed by free-radical reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

Interpretation Introduction

(b)

Interpretation: An explanation for the given statement that the homolysis of this OH bond is preferred to the homolysis of either OH bond in the other benzene ring is to be stated.

Concept introduction: The general steps followed by free-radical reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

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Explain Huckel's rule.

Answer 2

Question

Chapter 15, Problem 15.69P

Interpretation Introduction

(a)

Interpretation: All resonance structures for the radical that result from the homolysis of OH bond are to be drawn.

Concept introduction: The general steps followed by free-radical reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

Interpretation Introduction

(b)

Interpretation: An explanation for the given statement that the homolysis of this OH bond is preferred to the homolysis of either OH bond in the other benzene ring is to be stated.

Concept introduction: The general steps followed by free-radical reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

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Answer 3

Question

Chapter 15, Problem 15.69P

Interpretation Introduction

(a)

Interpretation: All resonance structures for the radical that result from the homolysis of OH bond are to be drawn.

Concept introduction: The general steps followed by free-radical reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

Interpretation Introduction

(b)

Interpretation: An explanation for the given statement that the homolysis of this OH bond is preferred to the homolysis of either OH bond in the other benzene ring is to be stated.

Concept introduction: The general steps followed by free-radical reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

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Answer 4

Question

Chapter 15, Problem 15.69P

Interpretation Introduction

(a)

Interpretation: All resonance structures for the radical that result from the homolysis of OH bond are to be drawn.

Concept introduction: The general steps followed by free-radical reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

Interpretation Introduction

(b)

Interpretation: An explanation for the given statement that the homolysis of this OH bond is preferred to the homolysis of either OH bond in the other benzene ring is to be stated.

Concept introduction: The general steps followed by free-radical reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

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Answer 5

Chapter 15, Problem 15.69P

Interpretation Introduction

(a)

Interpretation: All resonance structures for the radical that result from the homolysis of OH bond are to be drawn.

Concept introduction: The general steps followed by free-radical reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

Interpretation Introduction

(b)

Interpretation: An explanation for the given statement that the homolysis of this OH bond is preferred to the homolysis of either OH bond in the other benzene ring is to be stated.

Concept introduction: The general steps followed by free-radical reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

Answer 6

Chapter 15, Problem 15.69P

Interpretation Introduction

(a)

Interpretation: All resonance structures for the radical that result from the homolysis of OH bond are to be drawn.

Concept introduction: The general steps followed by free-radical reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

Answer 7

Chapter 15, Problem 15.69P

Interpretation Introduction

(a)

Interpretation: All resonance structures for the radical that result from the homolysis of OH bond are to be drawn.

Concept introduction: The general steps followed by free-radical reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

Answer 8

Interpretation Introduction

(b)

Interpretation: An explanation for the given statement that the homolysis of this OH bond is preferred to the homolysis of either OH bond in the other benzene ring is to be stated.

Concept introduction: The general steps followed by free-radical reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

Answer 9

Interpretation Introduction

(b)

Interpretation: An explanation for the given statement that the homolysis of this OH bond is preferred to the homolysis of either OH bond in the other benzene ring is to be stated.

Concept introduction: The general steps followed by free-radical reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 15 - Prob. 15.1P Ch. 15 - Prob. 15.2P Ch. 15 - Draw the product formed when a chlorine atom (Cl)...Ch. 15 - Prob. 15.4P Ch. 15 - Prob. 15.5P Ch. 15 - Problem 15.6 Using mechanism 15.1 as guide, write...Ch. 15 - Calculate m0 for the two propagation steps in the...Ch. 15 - Prob. 15.8P Ch. 15 - Problem 15.8 Which bond in the each compound is...Ch. 15 - Prob. 15.10P

Solution Summary: The author explains that the radical formed by the homolysis of OH bond is shown in Figure 1.

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