(a) Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn. Concept introduction: Alkanes undergo chlorination when they are treated with Cl 2 in the presence of light or heat. Chlorination takes place at primary, secondary and tertiary carbon atom of alkanes. During free radical mechanism, planner achiral radical is formed. The attack of chlorine atom takes place from above and below the plane.

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Answer 1

Question

Chapter 15, Problem 15.51P

Interpretation Introduction

(a)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo chlorination when they are treated with Cl2 in the presence of light or heat. Chlorination takes place at primary, secondary and tertiary carbon atom of alkanes. During free radical mechanism, planner achiral radical is formed. The attack of chlorine atom takes place from above and below the plane.

Interpretation Introduction

(b)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo chlorination when they are treated with Cl2 in the presence of light or heat. Chlorination takes place at primary, secondary and tertiary carbon atom of alkanes. During free radical mechanism, planner achiral radical is formed. The attack of chlorine atom takes place from above and below the plane.

Interpretation Introduction

(c)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo chlorination when they are treated with Cl2 in the presence of light or heat. Chlorination takes place at primary, secondary and tertiary carbon atom of alkanes. During free radical mechanism, planner achiral radical is formed. The attack of chlorine atom takes place from above and below the plane.

Interpretation Introduction

(d)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo bromination at primary, secondary and tertiary carbon atom when they are treated with Br2 in the presence of light. The attack of bromine radical on achiral planer free radical takes place from above and below the plane.

Interpretation Introduction

(e)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo bromination at primary, secondary and tertiary carbon atom when they are treated with Br2 in the presence of heat. The attack of bromine radical on achiral planer free radical takes place from above and below the plane.

Interpretation Introduction

(f)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo chlorination when they are treated with Cl2 in the presence of light or heat. Chlorination takes place at primary, secondary and tertiary carbon atom of alkanes. During free radical mechanism, planner achiral radical is formed. The attack of chlorine atom takes place from above and below the plane.

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Answer 2

Question

Chapter 15, Problem 15.51P

Interpretation Introduction

(a)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo chlorination when they are treated with Cl2 in the presence of light or heat. Chlorination takes place at primary, secondary and tertiary carbon atom of alkanes. During free radical mechanism, planner achiral radical is formed. The attack of chlorine atom takes place from above and below the plane.

Interpretation Introduction

(b)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo chlorination when they are treated with Cl2 in the presence of light or heat. Chlorination takes place at primary, secondary and tertiary carbon atom of alkanes. During free radical mechanism, planner achiral radical is formed. The attack of chlorine atom takes place from above and below the plane.

Interpretation Introduction

(c)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo chlorination when they are treated with Cl2 in the presence of light or heat. Chlorination takes place at primary, secondary and tertiary carbon atom of alkanes. During free radical mechanism, planner achiral radical is formed. The attack of chlorine atom takes place from above and below the plane.

Interpretation Introduction

(d)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo bromination at primary, secondary and tertiary carbon atom when they are treated with Br2 in the presence of light. The attack of bromine radical on achiral planer free radical takes place from above and below the plane.

Interpretation Introduction

(e)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo bromination at primary, secondary and tertiary carbon atom when they are treated with Br2 in the presence of heat. The attack of bromine radical on achiral planer free radical takes place from above and below the plane.

Interpretation Introduction

(f)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo chlorination when they are treated with Cl2 in the presence of light or heat. Chlorination takes place at primary, secondary and tertiary carbon atom of alkanes. During free radical mechanism, planner achiral radical is formed. The attack of chlorine atom takes place from above and below the plane.

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Answer 3

Question

Chapter 15, Problem 15.51P

Interpretation Introduction

(a)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo chlorination when they are treated with Cl2 in the presence of light or heat. Chlorination takes place at primary, secondary and tertiary carbon atom of alkanes. During free radical mechanism, planner achiral radical is formed. The attack of chlorine atom takes place from above and below the plane.

Interpretation Introduction

(b)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo chlorination when they are treated with Cl2 in the presence of light or heat. Chlorination takes place at primary, secondary and tertiary carbon atom of alkanes. During free radical mechanism, planner achiral radical is formed. The attack of chlorine atom takes place from above and below the plane.

Interpretation Introduction

(c)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo chlorination when they are treated with Cl2 in the presence of light or heat. Chlorination takes place at primary, secondary and tertiary carbon atom of alkanes. During free radical mechanism, planner achiral radical is formed. The attack of chlorine atom takes place from above and below the plane.

Interpretation Introduction

(d)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo bromination at primary, secondary and tertiary carbon atom when they are treated with Br2 in the presence of light. The attack of bromine radical on achiral planer free radical takes place from above and below the plane.

Interpretation Introduction

(e)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo bromination at primary, secondary and tertiary carbon atom when they are treated with Br2 in the presence of heat. The attack of bromine radical on achiral planer free radical takes place from above and below the plane.

Interpretation Introduction

(f)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo chlorination when they are treated with Cl2 in the presence of light or heat. Chlorination takes place at primary, secondary and tertiary carbon atom of alkanes. During free radical mechanism, planner achiral radical is formed. The attack of chlorine atom takes place from above and below the plane.

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Answer 4

Question

Chapter 15, Problem 15.51P

Interpretation Introduction

(a)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo chlorination when they are treated with Cl2 in the presence of light or heat. Chlorination takes place at primary, secondary and tertiary carbon atom of alkanes. During free radical mechanism, planner achiral radical is formed. The attack of chlorine atom takes place from above and below the plane.

Interpretation Introduction

(b)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo chlorination when they are treated with Cl2 in the presence of light or heat. Chlorination takes place at primary, secondary and tertiary carbon atom of alkanes. During free radical mechanism, planner achiral radical is formed. The attack of chlorine atom takes place from above and below the plane.

Interpretation Introduction

(c)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo chlorination when they are treated with Cl2 in the presence of light or heat. Chlorination takes place at primary, secondary and tertiary carbon atom of alkanes. During free radical mechanism, planner achiral radical is formed. The attack of chlorine atom takes place from above and below the plane.

Interpretation Introduction

(d)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo bromination at primary, secondary and tertiary carbon atom when they are treated with Br2 in the presence of light. The attack of bromine radical on achiral planer free radical takes place from above and below the plane.

Interpretation Introduction

(e)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo bromination at primary, secondary and tertiary carbon atom when they are treated with Br2 in the presence of heat. The attack of bromine radical on achiral planer free radical takes place from above and below the plane.

Interpretation Introduction

(f)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo chlorination when they are treated with Cl2 in the presence of light or heat. Chlorination takes place at primary, secondary and tertiary carbon atom of alkanes. During free radical mechanism, planner achiral radical is formed. The attack of chlorine atom takes place from above and below the plane.

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Answer 5

Chapter 15, Problem 15.51P

Interpretation Introduction

(a)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo chlorination when they are treated with Cl2 in the presence of light or heat. Chlorination takes place at primary, secondary and tertiary carbon atom of alkanes. During free radical mechanism, planner achiral radical is formed. The attack of chlorine atom takes place from above and below the plane.

Interpretation Introduction

(b)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo chlorination when they are treated with Cl2 in the presence of light or heat. Chlorination takes place at primary, secondary and tertiary carbon atom of alkanes. During free radical mechanism, planner achiral radical is formed. The attack of chlorine atom takes place from above and below the plane.

Interpretation Introduction

(c)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo chlorination when they are treated with Cl2 in the presence of light or heat. Chlorination takes place at primary, secondary and tertiary carbon atom of alkanes. During free radical mechanism, planner achiral radical is formed. The attack of chlorine atom takes place from above and below the plane.

Interpretation Introduction

(d)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo bromination at primary, secondary and tertiary carbon atom when they are treated with Br2 in the presence of light. The attack of bromine radical on achiral planer free radical takes place from above and below the plane.

Interpretation Introduction

(e)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo bromination at primary, secondary and tertiary carbon atom when they are treated with Br2 in the presence of heat. The attack of bromine radical on achiral planer free radical takes place from above and below the plane.

Interpretation Introduction

(f)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo chlorination when they are treated with Cl2 in the presence of light or heat. Chlorination takes place at primary, secondary and tertiary carbon atom of alkanes. During free radical mechanism, planner achiral radical is formed. The attack of chlorine atom takes place from above and below the plane.

Answer 6

Chapter 15, Problem 15.51P

Interpretation Introduction

(a)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo chlorination when they are treated with Cl2 in the presence of light or heat. Chlorination takes place at primary, secondary and tertiary carbon atom of alkanes. During free radical mechanism, planner achiral radical is formed. The attack of chlorine atom takes place from above and below the plane.

Answer 7

Chapter 15, Problem 15.51P

Interpretation Introduction

(a)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo chlorination when they are treated with Cl2 in the presence of light or heat. Chlorination takes place at primary, secondary and tertiary carbon atom of alkanes. During free radical mechanism, planner achiral radical is formed. The attack of chlorine atom takes place from above and below the plane.

Answer 8

Interpretation Introduction

(b)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo chlorination when they are treated with Cl2 in the presence of light or heat. Chlorination takes place at primary, secondary and tertiary carbon atom of alkanes. During free radical mechanism, planner achiral radical is formed. The attack of chlorine atom takes place from above and below the plane.

Answer 9

Interpretation Introduction

(b)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo chlorination when they are treated with Cl2 in the presence of light or heat. Chlorination takes place at primary, secondary and tertiary carbon atom of alkanes. During free radical mechanism, planner achiral radical is formed. The attack of chlorine atom takes place from above and below the plane.

Answer 10

Interpretation Introduction

(c)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo chlorination when they are treated with Cl2 in the presence of light or heat. Chlorination takes place at primary, secondary and tertiary carbon atom of alkanes. During free radical mechanism, planner achiral radical is formed. The attack of chlorine atom takes place from above and below the plane.

Answer 11

Interpretation Introduction

(c)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo chlorination when they are treated with Cl2 in the presence of light or heat. Chlorination takes place at primary, secondary and tertiary carbon atom of alkanes. During free radical mechanism, planner achiral radical is formed. The attack of chlorine atom takes place from above and below the plane.

Answer 12

Interpretation Introduction

(d)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo bromination at primary, secondary and tertiary carbon atom when they are treated with Br2 in the presence of light. The attack of bromine radical on achiral planer free radical takes place from above and below the plane.

Answer 13

Interpretation Introduction

(d)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo bromination at primary, secondary and tertiary carbon atom when they are treated with Br2 in the presence of light. The attack of bromine radical on achiral planer free radical takes place from above and below the plane.

Answer 14

Interpretation Introduction

(e)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo bromination at primary, secondary and tertiary carbon atom when they are treated with Br2 in the presence of heat. The attack of bromine radical on achiral planer free radical takes place from above and below the plane.

Answer 15

Interpretation Introduction

(e)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo bromination at primary, secondary and tertiary carbon atom when they are treated with Br2 in the presence of heat. The attack of bromine radical on achiral planer free radical takes place from above and below the plane.

Answer 16

Interpretation Introduction

(f)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo chlorination when they are treated with Cl2 in the presence of light or heat. Chlorination takes place at primary, secondary and tertiary carbon atom of alkanes. During free radical mechanism, planner achiral radical is formed. The attack of chlorine atom takes place from above and below the plane.

Answer 17

Interpretation Introduction

(f)

Interpretation: The products formed in the given reaction along with the stereochemistry around any stereogenic center are to be drawn.

Concept introduction: Alkanes undergo chlorination when they are treated with Cl2 in the presence of light or heat. Chlorination takes place at primary, secondary and tertiary carbon atom of alkanes. During free radical mechanism, planner achiral radical is formed. The attack of chlorine atom takes place from above and below the plane.

Answer 18

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Answer 19

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Answer 20

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Answer 21

Ch. 15 - Prob. 15.1P Ch. 15 - Prob. 15.2P Ch. 15 - Draw the product formed when a chlorine atom (Cl)...Ch. 15 - Prob. 15.4P Ch. 15 - Prob. 15.5P Ch. 15 - Problem 15.6 Using mechanism 15.1 as guide, write...Ch. 15 - Calculate m0 for the two propagation steps in the...Ch. 15 - Prob. 15.8P Ch. 15 - Problem 15.8 Which bond in the each compound is...Ch. 15 - Prob. 15.10P

Solution Summary: The author explains that the products formed in the given reaction along with the stereochemistry around any stereogenic center are shown in Figure 1.

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Chapter 15 Solutions