(a) Interpretation: The products formed by the treatment of given alkene with NBS + h v are to be drawn. Concept introduction: The general steps followed by free-radical addition reaction are stated below: 1. First step is initiation that involves formation of radical. 2. Second step is propagation. 3. Third step is the termination that involves the formation of stable bond.

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Answer 1

Question

Chapter 15, Problem 15.45P

Interpretation Introduction

(a)

Interpretation: The products formed by the treatment of given alkene with NBS+hv are to be drawn.

Concept introduction: The general steps followed by free-radical addition reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

Interpretation Introduction

(b)

Interpretation: The products formed by the treatment of given alkene with NBS+hv are to be drawn.

Concept introduction: The general steps followed by free-radical addition reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

Interpretation Introduction

(c)

Interpretation: The products formed by the treatment of given alkene with NBS+hv are to be drawn.

Concept introduction: The general steps followed by free-radical addition reaction are stated below:

4. First step is initiation that involves formation of radical.

5. Second step is propagation.

6. Third step is the termination that involves the formation of stable bond.

Interpretation Introduction

(d)

Interpretation: The products formed by the treatment of given alkene with NBS+hv are to be drawn.

Concept introduction: The general steps followed by free-radical addition reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

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Answer 2

Question

Chapter 15, Problem 15.45P

Interpretation Introduction

(a)

Interpretation: The products formed by the treatment of given alkene with NBS+hv are to be drawn.

Concept introduction: The general steps followed by free-radical addition reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

Interpretation Introduction

(b)

Interpretation: The products formed by the treatment of given alkene with NBS+hv are to be drawn.

Concept introduction: The general steps followed by free-radical addition reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

Interpretation Introduction

(c)

Interpretation: The products formed by the treatment of given alkene with NBS+hv are to be drawn.

Concept introduction: The general steps followed by free-radical addition reaction are stated below:

4. First step is initiation that involves formation of radical.

5. Second step is propagation.

6. Third step is the termination that involves the formation of stable bond.

Interpretation Introduction

(d)

Interpretation: The products formed by the treatment of given alkene with NBS+hv are to be drawn.

Concept introduction: The general steps followed by free-radical addition reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

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Answer 3

Question

Chapter 15, Problem 15.45P

Interpretation Introduction

(a)

Interpretation: The products formed by the treatment of given alkene with NBS+hv are to be drawn.

Concept introduction: The general steps followed by free-radical addition reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

Interpretation Introduction

(b)

Interpretation: The products formed by the treatment of given alkene with NBS+hv are to be drawn.

Concept introduction: The general steps followed by free-radical addition reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

Interpretation Introduction

(c)

Interpretation: The products formed by the treatment of given alkene with NBS+hv are to be drawn.

Concept introduction: The general steps followed by free-radical addition reaction are stated below:

4. First step is initiation that involves formation of radical.

5. Second step is propagation.

6. Third step is the termination that involves the formation of stable bond.

Interpretation Introduction

(d)

Interpretation: The products formed by the treatment of given alkene with NBS+hv are to be drawn.

Concept introduction: The general steps followed by free-radical addition reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

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Answer 4

Question

Chapter 15, Problem 15.45P

Interpretation Introduction

(a)

Interpretation: The products formed by the treatment of given alkene with NBS+hv are to be drawn.

Concept introduction: The general steps followed by free-radical addition reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

Interpretation Introduction

(b)

Interpretation: The products formed by the treatment of given alkene with NBS+hv are to be drawn.

Concept introduction: The general steps followed by free-radical addition reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

Interpretation Introduction

(c)

Interpretation: The products formed by the treatment of given alkene with NBS+hv are to be drawn.

Concept introduction: The general steps followed by free-radical addition reaction are stated below:

4. First step is initiation that involves formation of radical.

5. Second step is propagation.

6. Third step is the termination that involves the formation of stable bond.

Interpretation Introduction

(d)

Interpretation: The products formed by the treatment of given alkene with NBS+hv are to be drawn.

Concept introduction: The general steps followed by free-radical addition reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

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Answer 5

Chapter 15, Problem 15.45P

Interpretation Introduction

(a)

Interpretation: The products formed by the treatment of given alkene with NBS+hv are to be drawn.

Concept introduction: The general steps followed by free-radical addition reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

Interpretation Introduction

(b)

Interpretation: The products formed by the treatment of given alkene with NBS+hv are to be drawn.

Concept introduction: The general steps followed by free-radical addition reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

Interpretation Introduction

(c)

Interpretation: The products formed by the treatment of given alkene with NBS+hv are to be drawn.

Concept introduction: The general steps followed by free-radical addition reaction are stated below:

4. First step is initiation that involves formation of radical.

5. Second step is propagation.

6. Third step is the termination that involves the formation of stable bond.

Interpretation Introduction

(d)

Interpretation: The products formed by the treatment of given alkene with NBS+hv are to be drawn.

Concept introduction: The general steps followed by free-radical addition reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

Answer 6

Chapter 15, Problem 15.45P

Interpretation Introduction

(a)

Interpretation: The products formed by the treatment of given alkene with NBS+hv are to be drawn.

Concept introduction: The general steps followed by free-radical addition reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

Answer 7

Chapter 15, Problem 15.45P

Interpretation Introduction

(a)

Interpretation: The products formed by the treatment of given alkene with NBS+hv are to be drawn.

Concept introduction: The general steps followed by free-radical addition reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

Answer 8

Interpretation Introduction

(b)

Interpretation: The products formed by the treatment of given alkene with NBS+hv are to be drawn.

Concept introduction: The general steps followed by free-radical addition reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

Answer 9

Interpretation Introduction

(b)

Interpretation: The products formed by the treatment of given alkene with NBS+hv are to be drawn.

Concept introduction: The general steps followed by free-radical addition reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

Answer 10

Interpretation Introduction

(c)

Interpretation: The products formed by the treatment of given alkene with NBS+hv are to be drawn.

Concept introduction: The general steps followed by free-radical addition reaction are stated below:

4. First step is initiation that involves formation of radical.

5. Second step is propagation.

6. Third step is the termination that involves the formation of stable bond.

Answer 11

Interpretation Introduction

(c)

Interpretation: The products formed by the treatment of given alkene with NBS+hv are to be drawn.

Concept introduction: The general steps followed by free-radical addition reaction are stated below:

4. First step is initiation that involves formation of radical.

5. Second step is propagation.

6. Third step is the termination that involves the formation of stable bond.

Answer 12

Interpretation Introduction

(d)

Interpretation: The products formed by the treatment of given alkene with NBS+hv are to be drawn.

Concept introduction: The general steps followed by free-radical addition reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

Answer 13

Interpretation Introduction

(d)

Interpretation: The products formed by the treatment of given alkene with NBS+hv are to be drawn.

Concept introduction: The general steps followed by free-radical addition reaction are stated below:

1. First step is initiation that involves formation of radical.

2. Second step is propagation.

3. Third step is the termination that involves the formation of stable bond.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 15 - Prob. 15.1P Ch. 15 - Prob. 15.2P Ch. 15 - Draw the product formed when a chlorine atom (Cl)...Ch. 15 - Prob. 15.4P Ch. 15 - Prob. 15.5P Ch. 15 - Problem 15.6 Using mechanism 15.1 as guide, write...Ch. 15 - Calculate m0 for the two propagation steps in the...Ch. 15 - Prob. 15.8P Ch. 15 - Problem 15.8 Which bond in the each compound is...Ch. 15 - Prob. 15.10P

Solution Summary: The author explains the steps followed by free-radical addition reaction: initiation, propagation, termination, and stable bond formation.

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Chapter 15 Solutions