General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Textbook Question
Chapter 14.8, Problem 14.15P
The pH of 0.10 M HOCl is 4.23. Calculate Ka and pKa for hypochlorous acid, and check your answers against the values given in Table 14.2.
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Consider this molecule:
How many H atoms are in this molecule?
How many different signals could be found in its 1H NMR spectrum?
Note: A multiplet is considered one signal.
For each of the given mass spectrum data, identify whether the compound contains chlorine, bromine, or neither.
Compound
m/z of M* peak
m/z of M
+ 2 peak
ratio of M+ : M
+ 2 peak
Which element is present?
A
122
no M
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not applicable
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B
78
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C
227
229
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Show transformation from reactant to product, step by step. *see image
Chapter 14 Solutions
General Chemistry: Atoms First
Ch. 14.1 - Write a balanced equation for the dissociation of...Ch. 14.1 - What is the conjugate acid of each of the...Ch. 14.1 - Prob. 14.3CPCh. 14.1 - Some of the following ions have been detected...Ch. 14.2 - If you mix equal concentrations of reactants and...Ch. 14.2 - The following pictures represent aqueous solutions...Ch. 14.3 - Prob. 14.7PCh. 14.4 - Prob. 14.8PCh. 14.4 - The concentration of OH in a sample of seawater is...Ch. 14.4 - Prob. 14.10P
Ch. 14.5 - Calculate the pH of each of the following...Ch. 14.5 - Prob. 14.12PCh. 14.7 - Calculate the pH of the following solutions: (a)...Ch. 14.7 - Prob. 14.14PCh. 14.8 - The pH of 0.10 M HOCl is 4.23. Calculate Ka and...Ch. 14.8 - The following pictures represent aqueous solutions...Ch. 14.9 - Acetic acid, CH3CO2H, is the solute that gives...Ch. 14.9 - Prob. 14.18PCh. 14.10 - Prob. 14.19PCh. 14.11 - Calculate the pH and the concentrations of all...Ch. 14.11 - Prob. 14.21PCh. 14.12 - Calculate the pH and the concentrations of all...Ch. 14.12 - Prob. 14.23PCh. 14.13 - (a) Piperidine (C5H11N) is an amine found in black...Ch. 14.14 - Predict whether the following salt solutions are...Ch. 14.14 - Prob. 14.26PCh. 14.14 - Calculate Ka for the cation and Kb for the anion...Ch. 14.14 - Classify each of the following salt solutions as...Ch. 14.15 - For each of the following reactions, identify the...Ch. 14.15 - Prob. 14.30CPCh. 14.15 - Prob. 14.31PCh. 14.15 - Prob. 14.32PCh. 14 - For each of the following reactions, identify the...Ch. 14 - The following pictures represent aqueous solutions...Ch. 14 - Prob. 14.35CPCh. 14 - Which of the following pictures best represents an...Ch. 14 - The following pictures represent aqueous solutions...Ch. 14 - Prob. 14.38CPCh. 14 - The following picture represents the hydrated...Ch. 14 - Prob. 14.40CPCh. 14 - Prob. 14.41CPCh. 14 - Prob. 14.42CPCh. 14 - Prob. 14.43CPCh. 14 - Give three examples of molecules or ions that are...Ch. 14 - Prob. 14.45SPCh. 14 - Prob. 14.46SPCh. 14 - Give the formula for the conjugate acid of each of...Ch. 14 - For each of the following reactions, identify the...Ch. 14 - For each of the following reactions, identify the...Ch. 14 - Which of the following species behave as strong...Ch. 14 - Which acid in each of the following pairs has the...Ch. 14 - Prob. 14.52SPCh. 14 - Prob. 14.53SPCh. 14 - Prob. 14.54SPCh. 14 - Arrange each group of compounds in order of...Ch. 14 - Prob. 14.56SPCh. 14 - Prob. 14.57SPCh. 14 - Prob. 14.58SPCh. 14 - Identify the stronger base in each of the...Ch. 14 - Prob. 14.60SPCh. 14 - For each of the following solutions, calculate...Ch. 14 - Prob. 14.62SPCh. 14 - Prob. 14.63SPCh. 14 - Calculate the pH to the correct number of...Ch. 14 - Prob. 14.65SPCh. 14 - Calculate the H3O+ concentration to the correct...Ch. 14 - Prob. 14.67SPCh. 14 - Prob. 14.68SPCh. 14 - Prob. 14.69SPCh. 14 - Prob. 14.70SPCh. 14 - A solution of KOH has a pH of 10.00. How many...Ch. 14 - Prob. 14.72SPCh. 14 - Calculate the pH of solutions prepared by: (a)...Ch. 14 - Prob. 14.74SPCh. 14 - Look up the values of Ka in Appendix C for HCO2H,...Ch. 14 - The pH of 0.040 M hypobromous acid (HOBr) is 5.05....Ch. 14 - Prob. 14.77SPCh. 14 - Acrylic acid (C3H4O2) is used in the manufacture...Ch. 14 - Prob. 14.79SPCh. 14 - Prob. 14.80SPCh. 14 - Prob. 14.81SPCh. 14 - Write balanced net ionic equations and the...Ch. 14 - Prob. 14.83SPCh. 14 - Calculate the pH and the concentrations of all...Ch. 14 - Prob. 14.85SPCh. 14 - Oxalic acid (H2C2O4) is a diprotic acid that...Ch. 14 - Prob. 14.87SPCh. 14 - Write a balanced net ionic equation and the...Ch. 14 - Write a balanced net ionic equation and the...Ch. 14 - Prob. 14.90SPCh. 14 - Prob. 14.91SPCh. 14 - Oxycodone (C18H21NO4), a narcotic analgesic, is a...Ch. 14 - Prob. 14.93SPCh. 14 - Using values of Kb, in Appendix C, calculate...Ch. 14 - Prob. 14.95SPCh. 14 - Prob. 14.96SPCh. 14 - Write a balanced net ionic equation for the...Ch. 14 - Prob. 14.98SPCh. 14 - Classify each of the following salt solutions as...Ch. 14 - Calculate the concentrations of all species...Ch. 14 - Prob. 14.101SPCh. 14 - For each of the following reactions, identify the...Ch. 14 - For each of the following reactions, identify the...Ch. 14 - Prob. 14.104SPCh. 14 - For each of the Lewis acid-base reactions in...Ch. 14 - Classify each of the following as a Lewis acid or...Ch. 14 - Which would you expect to be the stronger Lewis...Ch. 14 - Prob. 14.108CHPCh. 14 - Prob. 14.109CHPCh. 14 - Prob. 14.110CHPCh. 14 - Prob. 14.111CHPCh. 14 - Prob. 14.112CHPCh. 14 - Use the conjugate acidbase pair HCN and CN to...Ch. 14 - Prob. 14.114CHPCh. 14 - Prob. 14.115CHPCh. 14 - Nicotine (C10H14N2) can accept two protons because...Ch. 14 - Prob. 14.117CHPCh. 14 - The hydrated cation M(H2O)63+ has Ka = 104, and...Ch. 14 - Calculate the pH and the concentrations of all...Ch. 14 - Prob. 14.120CHPCh. 14 - Prob. 14.121CHPCh. 14 - Prob. 14.122CHPCh. 14 - Prob. 14.123CHPCh. 14 - Prob. 14.124CHPCh. 14 - Prob. 14.125CHPCh. 14 - Prob. 14.126CHPCh. 14 - Prob. 14.127CHPCh. 14 - Prob. 14.128CHPCh. 14 - What is the pH and the principal source of H3O+...Ch. 14 - Prob. 14.130CHPCh. 14 - Prob. 14.131CHPCh. 14 - Prob. 14.132MPCh. 14 - Prob. 14.133MPCh. 14 - In aqueous solution, sodium acetate behaves as a...Ch. 14 - During a certain time period, 4.0 million tons of...Ch. 14 - Prob. 14.136MPCh. 14 - Prob. 14.137MPCh. 14 - Prob. 14.138MPCh. 14 - Prob. 14.139MP
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- 2' P17E.6 The oxidation of NO to NO 2 2 NO(g) + O2(g) → 2NO2(g), proceeds by the following mechanism: NO + NO → N₂O₂ k₁ N2O2 NO NO K = N2O2 + O2 → NO2 + NO₂ Ко Verify that application of the steady-state approximation to the intermediate N2O2 results in the rate law d[NO₂] _ 2kk₁[NO][O₂] = dt k+k₁₂[O₂]arrow_forwardPLEASE ANSWER BOTH i) and ii) !!!!arrow_forwardE17E.2(a) The following mechanism has been proposed for the decomposition of ozone in the atmosphere: 03 → 0₂+0 k₁ O₁₂+0 → 03 K →> 2 k₁ Show that if the third step is rate limiting, then the rate law for the decomposition of O3 is second-order in O3 and of order −1 in O̟.arrow_forward
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