Concept explainers
Interpretation:
The electron-dot structure of given reactant and product has to be drawn and using curved arrow notation represent the pair of electron donation from Lewis base to the Lewis acid.
Concept Introduction:
Lewis acid and base:
In Lewis acid-base reactions, the substance donates pair of electron is called Lewis base and the substance accepts the pair of electron from a base called Lewis acid to forms a covalent bond.
Electron-dot structure:
This is only way to show the sharing of electrons between atom in polar covalent bonds or covalent bond. This is often called Lewis structure. This structure denotes valence electrons of an atom by dots and also it shows the way of valence electron distributed within a molecule.
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General Chemistry: Atoms First
- What are the major species in solution after NaHSO4 is dissolved in water? What happens to the pH of the solution as more NaHSO4 is added? Why? Would the results vary if baking soda (NaHCO3) were used instead?arrow_forwardAcids You make a solution by dissolving 0.0010 mol of HCl in enough water to make 1.0 L of solution. a Write the chemical equation for the reaction of HCl(aq) and water. b Without performing calculations, give a rough estimate of the pH of the HCl solution. Justify your answer. c Calculate the H3O+ concentration and the pH of the solution. d Is there any concentration of the base OH present in this solution of HCl(aq)? If so, where did it come from? e If you increase the OH concentration of the solution by adding NaOH, does the H3O+ concentration change? If you think it does, explain why this change occurs and whether the H3O+ concentration increases or decreases. f If you were to measure the pH of 10 drops of the original HCl solution, would you expect it to be different from the pH of the entire sample? Explain. g Explain how two different volumes of your original HCl solution can have the same pH yet contain different moles of H3O+. h If 1.0 L of pure water were added to the HCl solution, would this have any impact on the pH? Explain.arrow_forwardWeak base B has a pKb of 6.78 and weak acid HA has a pKa of 5.12. a Which is the stronger base, B or A? b Which is the stronger acid, HA or BH+? c Consider the following reaction: B(aq)+HA(aq)BH+(aq)+A(aq) Based on the information about the acid/base strengths for the species in this reaction, is this reaction favored to proceed more to the right or more to the left? Why? d An aqueous solution is made in which the concentration of weak base B is one half the concentration of its acidic salt, BHCl, where BH+ is the conjugate weak add of B. Calculate the pH of the solution. e An aqueous solution is made in which the concentration of weak acid HA twice the concentration of the sodium salt of the weak acid, NaA. Calculate the pH of the solution. f Assume the conjugate pairs B/BH+ and HA/A are capable of being used as color-based end point indicators in acidbase titrations, where B is the base form indicator and BH is the acid form indicator, and HA is the acid form indicator and A is the base form indicator. Select the indicator pair that would be best to use in each of the following titrations: (1) Titration of a strong acid with a strong base. (i) B/BH+ (ii) HA/A (2) Titration of a weak base with a strong acid. (i) B/BH+ (ii) HA/Aarrow_forward
- Write chemical equations showing the individual proton-transfer steps that occur in aqueous solution for each of the following acids. a. H2C2O4 (oxalic acid) b. H2C4H4O6 (tartaric acid)arrow_forwardFor conjugate acidbase pairs, how are Ka and Kb related? Consider the reaction of acetic acid in water CH3CO2H(aq)+H2O(l)CH3CO2(aq)+H3O+(aq) where Ka = 1.8 105 a. Which two bases are competing for the proton? b. Which is the stronger base? c. In light of your answer to part b. why do we classify the acetate ion (CH3CO2) as a weak base? Use an appropriate reaction to justify your answer. In general, as base strength increases, conjugate acid strength decreases. Explain why the conjugate acid of the weak base NH3 is a weak acid. To summarize, the conjugate base of a weak acid is a weak base and the conjugate acid of a weak base is a weak acid (weak gives you weak). Assuming Ka for a monoprotic strong acid is 1 106, calculate Kb for the conjugate base of this strong acid. Why do conjugate bases of strong acids have no basic properties in water? List the conjugate bases of the six common strong acids. To tie it all together, some instructors have students think of Li+, K+, Rb+, Cs+, Ca2+, Sr2+, and Ba2+ as the conjugate acids of the strong bases LiOH, KOH. RbOH, CsOH, Ca(OH)2, Sr(OH)2, and Ba(OH)2. Although not technically correct, the conjugate acid strength of these cations is similar to the conjugate base strength of the strong acids. That is, these cations have no acidic properties in water; similarly, the conjugate bases of strong acids have no basic properties (strong gives you worthless). Fill in the blanks with the correct response. The conjugate base of a weak acid is a_____base. The conjugate acid of a weak base is a_____acid. The conjugate base of a strong acid is a_____base. The conjugate acid of a strong base is a_____ acid. (Hint: Weak gives you weak and strong gives you worthless.)arrow_forwardHydrazine, N2H4 (having the structure H2NNH2), and its derivatives have been used as rocket fuels. Draw the Lewis electron-dot formula for the hydrazine molecule. Describe the geometries expected about the nitrogen atoms in this molecule. Why would you expect hydrazine to be basic? Which substance, NH3 or N2H4, would you expect to be more basic? Why? Write the chemical equation in which hydrazine reacts with hydrochloric acids to form the salt N2H5Cl. Consider the positive ion of this salt. How does its basic character compare with that of NH3 and N2H4? Explain.arrow_forward
- Write a balanced molecular equation for the preparation of each of the following salts, using an acidbase neutralization reaction. a. LiNO3 (lithium nitrate) b. BaCl2 (barium chloride) c. K3PO4 (potassium phosphate) d. Na2SO4 (sodium sulfate)arrow_forwardBoron trifluoride, BF3, and ammonia, NH3, react to produce BF3: NH3. A coordinate covalent bond is formed between the boron atom on BF3 and the nitrogen atom on NH3. Write the equation for this reaction, using Lewis electron-dot formulas. Label the Lewis acid and the Lewis base. Determine how many grams of BF3: NH3 are formed when 10.0 g BF3 and 10.0 g NH3 are placed in a reaction vessel, assuming that the reaction goes to completion.arrow_forwardLeucine is an amino acid with this Lewis structure: Write the Lewis structure for the zwitterion form of leucine.arrow_forward
- Two strategies are also followed when solving for the pH of a base in water. What is the strategy for calculating the pH of a strong base in water? List the strong bases mentioned in the text that should be committed to memory. Why is calculating the pH of Ca(OH)2 solutions a little more difficult than calculating the pH of NaOH solutions? Most bases are weak bases. The presence of what element most commonly results in basic properties for an organic compound? What is present on this element in compounds that allows it to accept a proton? Table 13-3 and Appendix 5 of the text list Kb values for some weak bases. What strategy is used to solve for the pH of a weak base in water? What assumptions are made when solving for the pH of weak base solutions? If the 5% rule fails, how do you calculate the pH of a weak base in water?arrow_forward3. What is the pH of a 0.0075 mol L·' HCl solution? What is [OH]in this solution? 4. Each of the following salts were dissolved in water to give a 0.10 mol.L·' solution. Rank the solutions from lowest to highest pH. Their respective pKb values are indicated in brackets. Na2S (-5), Na3PO4 (1.68), NaF (10.86), NaCH3CO0 (9.26), AIC13arrow_forwardCalculate the pH and pOH of the following solutions (see Appendix 11 of your textbook for pKa values): 1. 0.01 M HBr 2. 0.00005 M HBr 3. 0.00002 МКОН 4. 0.01 M CH,COOH 5. 0.00001 M CH,COOH 6. 0.01 M HIO, 7. 0.01 M pyridine Calculate the pH of the following solutions: 1. 0.01 M NAHS 2. 0.005 M NaН.РО, 3. 0.005 M Na,HPO, 4. 0.005 M Na PO, 5. 0.1 ΜΝΗ,CN Calculate the pH of the following buffer solutions: 1. 1.7 g/L of NH, and 5.35 g/L of NH,Cl. 2. 50 mL of 1 M CH,COONA and 1 L 0.1 M CH,COOH. 3. 50 mL of 1 M NaOH and 1 L 0.1 M CH,COOH. 4. 10 mL 0.1 H,PO, + 25 mL 0.1 NaOH 5. 10 mL 0.1 H,PO, + 25 mL 0.1 Na,PO, 6. A buffer solution pH=5.00 contains 0.01 M CH,COOH. Calculate the concentration of sodium acetate it contains. 7. What weight of NH,Cl should be added to 1 L of 0.1 M NH, solution to get pH=9.00?arrow_forward
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