Strongest acid in given set of the molecules has to be identified. Concept Introduction: For binary acids, the element present in the same group of periodic table, strength of H-A bond is important to determine an acidity. H-A bond strength decreases down a group because of overlapping between 1s orbital of the Hydrogen atom and more diffusion, larger p orbital of A atom increases the strength of an acid and so decreases with increasing size of the element.
Strongest acid in given set of the molecules has to be identified. Concept Introduction: For binary acids, the element present in the same group of periodic table, strength of H-A bond is important to determine an acidity. H-A bond strength decreases down a group because of overlapping between 1s orbital of the Hydrogen atom and more diffusion, larger p orbital of A atom increases the strength of an acid and so decreases with increasing size of the element.
Solution Summary: The author explains that strength of H-A bond is important to determine an acidity for binary acids.
Strongest acid in given set of the molecules has to be identified.
Concept Introduction:
For binary acids, the element present in the same group of periodic table, strength of H-A bond is important to determine an acidity. H-A bond strength decreases down a group because of overlapping between 1s orbital of the Hydrogen atom and more diffusion, larger p orbital of A atom increases the strength of an acid and so decreases with increasing size of the element.
(b)
Interpretation Introduction
Interpretation:
Stronger acid in given set of the molecules has to be identified.
Concept Introduction:
Oxoacids have general formula is HnYOm, where Y is non-metallic atom (C,N,S and Cl) and n, m are integers. Y is always bonded to one or more OH group. Strength of an acid increases with increasing electronegativity of Y and sometimes strength of an acid increases with increasing number of Oxygen atoms.
(c)
Interpretation Introduction
Interpretation:
Stronger acid in given set of the molecule has to be identified.
Concept Introduction:
For binary acids, the element present in the same group of periodic table, strength of H-A bond is important to determine an acidity. H-A bond strength decreases down a group because of overlapping between 1s orbital of the Hydrogen atom and more diffusion, larger p orbital of A atom increases the strength of an acid and so decreases with increasing size of the element.
3. Name this ether correctly.
H₁C
H3C
CH3
CH3
4. Show the best way to make the ether in #3 by a
Williamson Ether Synthesis.
Start from an alcohol or phenol.
5. Draw the structure of an example of a sulfide.
1. Which one(s) of these can be oxidized with CrO3 ?
(could be more than one)
a) triphenylmethanol
b) 2-pentanol
c) Ethyl alcohol
d)
CH3
2. Write in all the product(s) of this reaction. Label them
as "major" or "minor".
2-methyl-2-hexanol
H2SO4, heat
3) Determine if the pairs are constitutional isomers, enantiomers, diastereomers, or mesocompounds.
(4 points)
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