The order for the given reaction should be determined using the given set of data. Concept introduction: Rate law: It is generally the rate equation that consists of the reaction rate with the concentration or the pressures of the reactants and constant parameters. Rate constant: The rate constant for a chemical reaction is the proportionality term in the chemical reaction rate law which gives the relationship between the rate and the concentration of the reactant present in the chemical reaction. Rate order: The order of each reactant in a reaction is represented by the exponential term of the respective reactant present in the rate law and the overall order of the reaction is the sum of all the exponents of all reactants present in the chemical reaction. The order of the reaction is directly proportional to the concentration of the reactants.

Question

1. (a) Show that decomposition of the organic compound 1,3-pentadiene is a second-order reaction and determine the rate constant. The concentration of 1,3-pentadiene was measured as a function of time. The data are as follows: (b) What is the value of the rate constant for the decomposition of 1,3-pentadiene.(c) What is the initial concentration for the reaction? Report to 3 significant figures.(d) What is the concentration of 1,3-pentadiene after 3.750 x10^3 s? Time(s) [1,3-pentadiene] (M) 0 .480 1000 .179 2000 .110 3000 .0795 4000 .0622 5000 .0510

Answer 1

Question

Chapter 14, Problem 36PS

(a)

Interpretation Introduction

Interpretation:

The order for the given reaction should be determined using the given set of data.

Concept introduction:

Rate law: It is generally the rate equation that consists of the reaction rate with the concentration or the pressures of the reactants and constant parameters.

Rate constant: The rate constant for a chemical reaction is the proportionality term in the chemical reaction rate law which gives the relationship between the rate and the concentration of the reactant present in the chemical reaction.

Rate order: The order of each reactant in a reaction is represented by the exponential term of the respective reactant present in the rate law and the overall order of the reaction is the sum of all the exponents of all reactants present in the chemical reaction. The order of the reaction is directly proportional to the concentration of the reactants.

(b)

Interpretation Introduction

Interpretation:

The rate constant for the given reaction should be determined using the given set of data.

Concept introduction:

Rate law: It is generally the rate equation that consists of the reaction rate with the concentration or the pressures of the reactants and constant parameters.

Rate constant: The rate constant for a chemical reaction is the proportionality term in the chemical reaction rate law which gives the relationship between the rate and the concentration of the reactant present in the chemical reaction.

Rate order: The order of each reactant in a reaction is represented by the exponential term of the respective reactant present in the rate law and the overall order of the reaction is the sum of all the exponents of all reactants present in the chemical reaction. The order of the reaction is directly proportional to the concentration of the reactants.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Students have asked these similar questions

1. (a) Show that decomposition of the organic compound 1,3-pentadiene is a second-order reaction and determine the rate constant. The concentration of 1,3-pentadiene was measured as a function of time. The data are as follows: (b) What is the value of the rate constant for the decomposition of 1,3-pentadiene.(c) What is the initial concentration for the reaction? Report to 3 significant figures.(d) What is the concentration of 1,3-pentadiene after 3.750 x10^3 s? Time(s) [1,3-pentadiene] (M) 0 .480 1000 .179 2000 .110 3000 .0795 4000 .0622 5000 .0510

! (plz give proper explanation)

The radioactive isotope 28Mg has a half-life of 20.9 hours. (a) What is the rate constant for this first-order reaction? (b) What fraction of the isotope remains after 24 hours? Assume 3 significant figures in your calculations.