Organic Chemistry
Organic Chemistry
12th Edition
ISBN: 9781118875766
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Chapter 14, Problem 33P

Give a structure for compound F that is consistent with the 1 H NMR spectrum in Fig. 14.28 and IR absorptions at 3020, 2965, 2940, 2870, 1517, 1463, and 818 c m 1 .

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Following is the 1H-NMR spectrum of compound O, molecular formula C7H12. Compound O reacts with bromine in carbon tetrachloride to give a compound with the molecular formula C7H12Br2. The 13C-NMR spectrum of compound O shows signals at d 150.12, 106.43, 35.44, 28.36, and 26.36. Deduce the structural formula of compound O.
Give the structure that corresponds to the following molecular formula and H1 NMR spectrum:: C7H16O4: δ 1.93 (triplet); δ 3.35 (s); δ 4.49 (triplet); relative integral 1:6:1.
Indicate two basic differences that exist between the spectra of 1H y 13C in NMR.

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