Organic Chemistry
Organic Chemistry
12th Edition
ISBN: 9781118875766
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Chapter 14, Problem 9PP

Practice Problem 14.9

In 1967 R. Breslow (of Columbia University) and co-workers showed that adding S b C l 5 to a solution of 3-chlorocyclopropene in C H 2 C l 2 caused the precipitation of a white solid with the composition C 3 H 3 + S b C l 6 . NMR spectroscopy of a solution of this salt showed that all of its hydrogen atoms were equivalent.

(a) What new aromatic ion had these researchers prepared?

(b) How many 13 C NMR signals would you predict for this ion?

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The following is a two groups (Regular tomato sauce & Salt Reduced Tomato Sauce) of data recorded by a team analysising salt content in tomato sauce using the MOHR titration method: Regular Tomato Sauce Salt Reduced Tomato Sauce 340.0 262.7 QUESTION: For both groups of data provide answers to the calculations attached in the image
7. Concentration and uncertainty in the estimate of concentration (class data) Class mean for sample (Regular) |[Cl-] (mmol/L) class mean Sn za/2 95% Confidence Interval (mmol/L) [Na+] (mg/100 mL) 95% Confidence Interval (mg/100 mL)
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Chapter 14 Solutions

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