Chemistry for Today: General, Organic, and Biochemistry
Chemistry for Today: General, Organic, and Biochemistry
9th Edition
ISBN: 9781305960060
Author: Spencer L. Seager, Michael R. Slabaugh, Maren S. Hansen
Publisher: Cengage Learning
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Chapter 14, Problem 14.4E

Identify each of the following compounds as an aldehyde, a ketone, or neither:

a.Chapter 14, Problem 14.4E, Identify each of the following compounds as an aldehyde, a ketone, or neither: a.d. b.e. c.f. , example  1 d.Chapter 14, Problem 14.4E, Identify each of the following compounds as an aldehyde, a ketone, or neither: a.d. b.e. c.f. , example  2

b.Chapter 14, Problem 14.4E, Identify each of the following compounds as an aldehyde, a ketone, or neither: a.d. b.e. c.f. , example  3 e.Chapter 14, Problem 14.4E, Identify each of the following compounds as an aldehyde, a ketone, or neither: a.d. b.e. c.f. , example  4

c.Chapter 14, Problem 14.4E, Identify each of the following compounds as an aldehyde, a ketone, or neither: a.d. b.e. c.f. , example  5 f.Chapter 14, Problem 14.4E, Identify each of the following compounds as an aldehyde, a ketone, or neither: a.d. b.e. c.f. , example  6

Expert Solution
Check Mark
Interpretation Introduction

(a)

Interpretation:

The given compound is to be identified as an aldehyde, a ketone, or neither.

Concept introduction:

An aldehyde consists of a carbonyl group that is single bonded to minimum one hydrogen atom, whereas a ketone consists of a carbonyl group that is single bonded to two carbon atoms. The structural formula of an aldehyde is RCOH and the structural formula of a ketone is RCOR.

Answer to Problem 14.4E

The given compound is an aldehyde.

Explanation of Solution

The given compound is shown below.

Chemistry for Today: General, Organic, and Biochemistry, Chapter 14, Problem 14.4E , additional homework tip  1

Figure 1

The given compound contains carbonyl group that is connected to one carbon atom and one hydrogen atom. Hence, it is an aldehyde.

Conclusion

The given compound is an aldehyde.

Expert Solution
Check Mark
Interpretation Introduction

(b)

Interpretation:

The given compound is to be identified as an aldehyde, a ketone, or neither.

Concept introduction:

An aldehyde consists of a carbonyl group that is single bonded to minimum one hydrogen atom, whereas a ketone consists of a carbonyl group that is single bonded to two carbon atoms. The structural formula of an aldehyde is RCOH and the structural formula of a ketone is RCOR.

Answer to Problem 14.4E

The given compound is neither aldehyde nor ketone.

Explanation of Solution

The given compound is shown below.

Chemistry for Today: General, Organic, and Biochemistry, Chapter 14, Problem 14.4E , additional homework tip  2

Figure 2

In the given compound, the carbonyl group is not attached with two carbon atoms. Therefore, it is not a ketone. Also, the carbonyl group is not attached with at least one hydrogen atom. Thus, it is not an aldehyde. Hence, it is neither aldehyde nor ketone.

Conclusion

The given compound is neither aldehyde nor ketone.

Expert Solution
Check Mark
Interpretation Introduction

(c)

Interpretation:

The given compound is to be identified as an aldehyde, a ketone, or neither.

Concept introduction:

An aldehyde consists of a carbonyl group that is single bonded to minimum one hydrogen atom, whereas a ketone consists of a carbonyl group that is single bonded to two carbon atoms. The structural formula of an aldehyde is RCOH and the structural formula of a ketone is RCOR.

Answer to Problem 14.4E

The given compound is a ketone.

Explanation of Solution

The given compound is shown below.

Chemistry for Today: General, Organic, and Biochemistry, Chapter 14, Problem 14.4E , additional homework tip  3

Figure 3

The given compound contains carbonyl group that is connected to two carbon atoms in the ring. Hence, it is a ketone.

Conclusion

The given compound is a ketone.

Expert Solution
Check Mark
Interpretation Introduction

(d)

Interpretation:

The given compound is to be identified as an aldehyde, a ketone, or neither.

Concept introduction:

An aldehyde consists of a carbonyl group that is single bonded to minimum one hydrogen atom, whereas a ketone consists of a carbonyl group that is single bonded to two carbon atoms. The structural formula of an aldehyde is RCOH and the structural formula of a ketone is RCOR.

Answer to Problem 14.4E

The given compound is neither aldehyde nor ketone.

Explanation of Solution

The given compound is shown below.

Chemistry for Today: General, Organic, and Biochemistry, Chapter 14, Problem 14.4E , additional homework tip  4

Figure 4

In the given compound, the carbonyl group is not attached with two carbon atoms. Therefore, it is not a ketone. Also, the carbonyl group is not attached with at least one hydrogen atom. Thus, it is not an aldehyde. Hence, it is neither aldehyde nor ketone.

Conclusion

The given compound is neither aldehyde nor ketone.

Expert Solution
Check Mark
Interpretation Introduction

(e)

Interpretation:

The given compound is to be identified as an aldehyde, a ketone, or neither.

Concept introduction:

An aldehyde consists of a carbonyl group that is single bonded to at least one hydrogen atom, whereas a ketone consists of a carbonyl group that is single bonded to two carbon atoms. The structural formula of an aldehyde is RCOH and the structural formula of a ketone is RCOR.

Answer to Problem 14.4E

The given compound is a ketone.

Explanation of Solution

The given compound is shown below.

Chemistry for Today: General, Organic, and Biochemistry, Chapter 14, Problem 14.4E , additional homework tip  5

Figure 5

The given compound contains carbonyl group that is connected to two carbon atoms. Hence, it is a ketone.

Conclusion

The given compound is a ketone.

Expert Solution
Check Mark
Interpretation Introduction

(f)

Interpretation:

The given compound is to be identified as an aldehyde, a ketone, or neither.

Concept introduction:

An aldehyde consists of a carbonyl group that is single bonded to minimum one hydrogen atom, whereas a ketone consists of a carbonyl group that is single bonded to two carbon atoms. The structural formula of an aldehyde is RCOH and the structural formula of a ketone is RCOR.

Answer to Problem 14.4E

The given compound is neither aldehyde nor ketone.

Explanation of Solution

The given compound is shown below.

Chemistry for Today: General, Organic, and Biochemistry, Chapter 14, Problem 14.4E , additional homework tip  6

Figure 6

In the given compound, the carbonyl group is not attached with two carbon atoms. Therefore, it is not a ketone. Also, the carbonyl group is not attached with at least one hydrogen atom. Thus, it is not an aldehyde. The carbonyl group is attached to one nitrogen atom and one carbon atom. Hence, it is neither aldehyde nor ketone.

Conclusion

The given compound is neither aldehyde nor ketone.

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Chapter 14 Solutions

Chemistry for Today: General, Organic, and Biochemistry

Ch. 14 - Each of the following names is wrong. Give the...Ch. 14 - Each of the following names is wrong. Give the...Ch. 14 - Prob. 14.13ECh. 14 - Prob. 14.14ECh. 14 - Prob. 14.15ECh. 14 - Explain why propane boils at 42C, whereas ethanal,...Ch. 14 - Use a dotted line to show hydrogen bonding between...Ch. 14 - Use a dotted line to show hydrogen bonding between...Ch. 14 - Prob. 14.19ECh. 14 - Prob. 14.20ECh. 14 - Prob. 14.21ECh. 14 - Prob. 14.22ECh. 14 - Prob. 14.23ECh. 14 - Prob. 14.24ECh. 14 - Label each of the following as acetals, ketals, or...Ch. 14 - Label each of the following as acetals, ketals, or...Ch. 14 - Label each of the following structures as a cyclic...Ch. 14 - Label each of the following structures as a...Ch. 14 - What two functional groups react to form the...Ch. 14 - Hemiacetals are sometimes referred to as potential...Ch. 14 - Complete the following statements: a. Oxidation of...Ch. 14 - Prob. 14.32ECh. 14 - Prob. 14.33ECh. 14 - Prob. 14.34ECh. 14 - Prob. 14.35ECh. 14 - Not all aldehyde give a positve Bendicts test....Ch. 14 - A stockroom assistant prepares three bottles, each...Ch. 14 - Glucose, the sugar present within the blood, gives...Ch. 14 - Fructose, present with glucose in honey, reacts...Ch. 14 - Prob. 14.40ECh. 14 - Prob. 14.41ECh. 14 - Complete the following equations. If no reaction...Ch. 14 - Complete the following equations. If no reaction...Ch. 14 - Describe the products that result when hydrogen...Ch. 14 - Prob. 14.45ECh. 14 - Draw structural formulas for the products of the...Ch. 14 - The following compounds are cyclic acetals or...Ch. 14 - The following compounds are cyclic acetals or...Ch. 14 - Write equations to show how the following...Ch. 14 - Prob. 14.50ECh. 14 - Identify the most important aldehyde and ketone...Ch. 14 - Using Table 14.3, name an aldehyde or ketone used...Ch. 14 - Prob. 14.53ECh. 14 - CH3COH(O)CH3COOHacetaldehydeaceticacid You need to...Ch. 14 - The addition of water to aldehydes and ketones...Ch. 14 - Prob. 14.56ECh. 14 - Formaldehyde levels above 0.10mg/1000L of ambient...Ch. 14 - In the IUPAC name for the following ketone, it is...Ch. 14 - Why can formaldehyde (CH2O) be prepared in the...Ch. 14 - Other addition reactions of aldehydes occur....Ch. 14 - Prob. 14.61ECh. 14 - Prob. 14.62ECh. 14 - Vanilla flavoring is either extracted from a...Ch. 14 - Prob. 14.64ECh. 14 - The use of acetone in laboratory experiments must...Ch. 14 - Prob. 14.66ECh. 14 - Prob. 14.67ECh. 14 - Which of the following would be classified as a...
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